Synthesis of naturally occurring nitrogen heterocycles from carbohydrates / / El Sayed H. El Ashry, Ahmed El Nemr

• Record Nr.: UNINA9910877986903321
• Autore: El Ashry El Sayed H. <1942->
• Pubbl/distr/stampa: Oxford, UK ; ; Ames, Iowa, : Blackwell Pub., 2005
• ISBN: 1-280-19704-8; 9786610197040; 0-470-98861-4; 1-4051-4479-3
• Descrizione fisica: 1 online resource (466 p.)
• Altri autori (Persone): El-NemrAhmed <1962->
• Disciplina: 547/.590459
• Soggetti: Heterocyclic compounds - Synthesis; Carbohydrates
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and indexes.
• Nota di contenuto: Synthesis of Naturally Occurring Nitrogen Heterocycles from Carbohydrates; Contents; Preface; Author details; List of abbreviations and acronyms used in this book; Introduction; 1. Five-membered nitrogen heterocycles; 1.1 Hydroxymethylpyrrolidines; 1.1.1 2-Hydroxymethylpyrrolidines; 1.1.1.1 Synthesis from D-glucose; 1.1.1.2 Synthesis from D-mannose; 1.1.1.3 Synthesis from L-arabinose; 1.1.1.4 Synthesis from D-xylose; 1.1.1.5 Synthesis from D-threose; 1.1.1.6 Synthesis from D-lyxonolactone; 1.1.1.7 Synthesis from D-gulonolactone; 1.1.2 Dihydro-2-hydroxymethylpyrrole (nectrisine); 1.1.2.1 Synthesis from D-glucose1.1.2.2 Synthesis from D-arabinose; 1.1.2.3 Synthesis from D-glyceraldehyde; 1.1.2.4 Synthesis from L-threitol; 1.1.3 2,5-Dihydroxymethylpyrrolidines; 1.1.3.1 Synthesis from D-glucose; 1.1.3.2 Synthesis from D-glucosamine; 1.1.3.3 Synthesis from D-fructose; 1.1.3.4 Synthesis from L-sorbose; 1.1.3.5 Synthesis from D-arabinose; 1.1.3.6 Synthesis from L-xylose; 1.1.3.7 Synthesis from D-iditol; 1.1.3.8 Synthesis from D-mannitol; 1.1.3.9 Synthesis from D-glucosamic acid; 1.1.3.10 Synthesis from D-glyconolactone; 1.2 2-Carboxypyrrolidines; 1.2.1 Hydroxyprolines; 1.2.1.1 Synthesis from D-glucose1.2.1.2 Synthesis from D-mannitol; ; 1.2.1.3 Synthesis from L-arabinono- and L-lyxono-lactones; 1.2.1.4 Synthesis from D-ribonolactone; 1.2.1.5 Synthesis from D-gulonolactones; 1.2.1.6 Synthesis from D-gluconolactone; 1.2.1.7 Synthesis from D-glucoronolactone; 1.2.1.8 Synthesis from D-xylonolactone; 1.2.2 Bulgecins; 1.2.2.1 Synthesis from D-glucose; 1.2.2.2 Synthesis from D-glucuronolactone; 1.3 2-Aralkyl pyrrolidines; 1.3.1 (-)-Anisomycin; 1.3.1.1 Synthesis from D-galactose; 1.3.1.2 Synthesis from L-arabinose; 1.3.1.3 Synthesis from D-ribose; 1.3.1.4 Synthesis from L-threose1.3.1.5 Synthesis from L-threitol; 1.3.1.6 Synthesis from D-mannitol; 1.3.2 (+)-Preussin; 1.3.2.1 Synthesis from D-glucose; 1.3.2.2 Synthesis from D-mannose; 1.3.2.3 Synthesis from D-arabinose; 1.4 2-Aryl pyrrolidines; 1.4.1 Codonopsinine and codonopsine; 1.5 Miscellaneous; 1.5.1 Detoxins; 1.5.1.1 Synthesis from D-glucose; 1.5.1.2 Synthesis from L-ascorbic acid; 1.5.2 Gualamycin; 1.5.3 Lactacystin; 2. Five-membered heterocycles with two heteroatoms; 2.1 (+)-Hydantocidin; 2.1.1 Synthesis from D-fructose; 2.1.2 Synthesis from D-ribose; 2.1.3 Synthesis from D-threose2.1.4 Synthesis from D-ribonolactone; 2.2 Bleomycin; 2.2.1 Synthesis from D-glucosamine; 2.2.2 Synthesis from L-rhamnose; 2.2.3 Total synthesis of bleomycin A2; 2.3 Calyculins; 2.3.1 Synthesis from D-lyxose; 2.3.2 Synthesis from D-gulonolactone; 2.3.3 Synthesis from L-idonolactone; 2.3.4 Synthesis from D-ribonolactone; 2.3.5 Synthesis from D-erythronolactone; 2.4 Acivicin; 2.5 Bengazole; 3. Six-membered nitrogen heterocycles; 3.1 Hydroxymethylpiperidines; 3.1.1 Nojirimycin; 3.1.1.1 Synthesis from D-glucose; 3.1.1.2 Synthesis from L-sorbose; 3.1.1.3 Synthesis from L-threose
• Sommario/riassunto: Carbohydrates are widely distributed in nature and widely available, and so are considered as a promising feedstock for the preparation of many organic chemical compounds. They are particularly useful in the preparation of nitrogen heterocycles because of their related structural characteristics and easy availability. Synthesis of Naturally Occurring Nitrogen Heterocycles from Carbohydrates will review the recent literature dealing with use of carbohydrates as raw materials in the synthesis of these materials. The text contains six chapters arranged according to the comple