1.

Record Nr.

UNINA9910877523303321

Titolo

Seven-membered heterocyclic compounds containing oxygen and sulfur / / edited by Andre Rosowsky

Pubbl/distr/stampa

New York, : Wiley-Interscience, 1972

ISBN

1-282-30171-3

9786612301711

0-470-18696-8

0-470-18845-6

Edizione

[99th ed.]

Descrizione fisica

1 online resource (982 p.)

Collana

Chemistry of heterocyclic compounds ; ; v. 26

Altri autori (Persone)

RosowskyAndre

Disciplina

547.592

547/.59/05

547/.592

Soggetti

Oxepins

Thiepins

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references.

Nota di contenuto

THE CHEMISTRY OF HETEROCYCLIC COMPOUNDS A SERIES OF MONOGRAPHS; Preface; Contents; Tables; I. Oxepins and Reduced Oxepins; A. OXEPINS; 1. Theoretical Interest; 2. Preparation; 3. Physical Properties; a. Infrared Absorption; b. Ultraviolet Absorption; c. Nuclear Magnetic Resonance; d. Thermodynamic Properties; 4. Chemical Reactions; a. Addendum; B. DIHYDROOXEPINS; 1. Introduction; 2. Preparation; 3. Physical Properties; a. Infrared Absorption; b. Ultraviolet Absorption; c. Nuclear Magnetic Resonance; 4. Chemical Reactions; C. TETRAHYDROOXEPINS; 1. Introduction; 2. Preparation

3. Physical Propertiesa. Infrared Absorption; b. Nuclear Magnetic Resonance; 4. Chemical Reactions; D. HEXAHYDROOXEPINS (OXEPANS); 1. Preparation; a. Hexamethylene Oxide; b. Substituted Oxepans; (1) Ring Closure Reactions; (2) Ring Expansion Reactions; (3) Two-Component Reactions; 2. Physical Properties of Hexamethylene Oxide; 3. Chemical Reactions of Hexamethylene Oxide; 4. Preparation and Reactions of Cyclic Acetals, Ketals, and Related Compounds; E. TABLES; I-1. Oxepins and Reduced Oxepins; F. REFERENCES; II. Oxepin Ring



Systems Containing Two Rings; A. FUSED RINGS SYSTEMS

1. 2-Oxabicyclo[5.1.0]octanes2. 2-Oxabicyclo[5.2.0]nonanes; 3. 2H-Cyclopent[b]oxepins; 4. 2H-Cyclopent[d]oxepins; 5. Furo[3,4-b]oxepins; 6. Furo[3,4-d]oxepins; 7. 2H-Oxepino[2,3-b]pyrroles; 8. Thieno[3,4-d]oxepins; 9.1-Benzoxepins; a. Synthesis, Chemical Reactions, and Physical Properties of the Parent Compound; b. Synthesis and Chemical Reactions of Dihydro-l-benzoxepins; c. Synthesis and Chemical Reactions of Tetrahydro-l- benzoxepins; d. Synthesis and Chemical Reactions of Other Reduced 1-Benzoxepins; e. Physicochemical Properties of 2,3,4,5-Tetrahydro-1- benzoxepins; 10.2-Benzoxepins

11. 3-BenzoxepinsB. SPIRANS; 1. 1,7-Dioxaspiro[5.6]dodecanes; 2. 1,4,6-Trioxaspiro[4.6]undecanes; C. BRIDGED SYSTEMS; 1. 2-Oxabicyclo[3.2.2]nonanes; 2. 3-Oxabicyclo[3.2.2]nonanes; 3. 9-Oxabicyclo[3.3.2]decanes; 4. 11-Oxabicyclo[4.4.1]undecanes; a. Partly or Fully Saturated Derivatives; b. 1,6-Oxido[10]annulenes; 5. 3-Oxa-6,7-dithiabicyclo[3.2.2]nonanes; D. TABLES; II-1. Uv Data and Bromination Rate of 2,3,4,5-Tetrahydro-l-benzoxepins and Lower Ring Homologs; II-2. Solvolysis Kinetics of 7-Chloromethyl-2,3,4,5-tetrahydro-l- benzoxepin and Lower Ring Homologs

II-3. Uv Data and Bromination Rate of 2,3,4,5-Tetrahydro-l- benzoxepin-2-carboxylic Acid and Lower Ring HomologsII-4. Uv Data and Molecular Geometry of 2,3,4,5-Tetrahydro-2-(N,N-dimethylamino)methyl-1-benzoxepin Methobromide and Lower Ring Homologs; II-5. l-Benzoxepins; II-6. 2-Benzoxepins; II-7. 3-Benzoxepins; E. REFERENCES; III. Oxepin Ring Systems Containing Three Rings; A. FUSED RING SYSTEMS; 1. Cyclopenta[5.6]pyrano[4,3-b]oxepins; 2. 8H-1,3-Dioxolo[4,5-h][3]benzoxepins; 3. Dibenz[b,d]oxepins; 4. Dibenz[b,e]oxepins; 5. Dibenz[b,f]oxepins; 6. Dibenz[c,e]oxepins

a. Dibenz[c,e]oxepin-5,7-diones (Diphenic Anhydrides)

Sommario/riassunto

Chemistry of Heterocyclic Compounds publishes articles, letters to the Editor, reviews, and minireviews on the synthesis, structure, reactivity, and biological activity of heterocyclic compounds including natural products. The journal covers investigations in heterocyclic chemistry taking place in scientific centers of all over the world, including extensively the scientific institutions in Russia, Ukraine, Latvia, Lithuania and Belarus.