Transition metal-containing polymers / / edited by Alaa S. Abd-El-Aziz ... [et al.]

• Record Nr.: UNINA9910877467303321
• Pubbl/distr/stampa: Hoboken, NJ, : Wiley, c2006
• ISBN: 1-280-23565-9; 9786610235650; 0-470-29481-7; 0-471-74731-9; 0-471-74730-0
• Descrizione fisica: 1 online resource (235 p.)
• Collana: Macromolecules containing metal and metal-like elements ; ; v. 6
• Altri autori (Persone): Abd-El-AzizAlaa S
• Disciplina: 546.6; 547.7
• Soggetti: Transition metal compounds; Metal complexes; Organometallic polymers; Macromolecules
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Macromolecules Containing Metal and Metal-Like Elements Volume 6; Contributors; Contents; Preface; Series Preface; 1. Introduction; I. Coverage; II. General Concepts; III. Historical; IV. Polymers Containing Bis(Cyclopentadienyl) Metal Complexes; A. Polymerization of Olefin-Functionalized Metallocenes; B. Alkyne Metathesis Polymerization of Substituted Metallocenes; C. Polycondensation of Metallocenes; D. Ring-Opening Polymerization; E. Coordination of Metals to Cyclopentadienyl Rings; F. Introduction of Metallocenes into Preformed Polymers; V. Arene-Transition Metal Polymers; A. Polymerization of Olefin-Containing ArenesB. Ring-Opening Metathesis Polymerization of Substituted Norbornenes; C. Nucleophilic Aromatic Substitution Polymerization of Chloroarene Complexes; D. Polycondensation of Arene Complexes; E. Coordination of Organometallic Moieties to Arenes; F. Supramolecular Assembly of Polymers; VI. Polymers with Metal-Coordinated Cyclobutadienes; VII. ; Polymers Containing Metal Carbonyl Complexes; VIII. Polymers with Metal-Carbon s-Bonds; A. Transition Metal Polyynes; B. Metal-Aryl and Metal-Alkyl Systems; IX. Metal-Metal Bonded Systems; X. Conclusion; XI. References2. Lithographic Applications of Highly Metallized Polyferrocenylsilanes; I. Introduction; II. Polyferrocenylsilanes as Electron Beam Lithography Resists; III. Polyferrocenylsilanes as Reactive Ion Etch Resists; IV. Polyferrocenylsilanes as UV Photoresists; V. Conclusions; VI. Acknowledgments; VII. References; 3. Polymers Possessing Reactive Metallacycles in the Mainchain; I. Introduction; II. Synthesis and Reactions of Organometallic Polymers Possessing Metallacycles in the Mainchain; A. Cobaltacyclopentadiene-Containing Polymers; B. Conversion of Cobaltacyclopentadiene-Containing Polymers into Polymers Possessing Various Mainchain Structuresi. Conversion into Other Organometallic Polymers; ii. Conversion into Organic Polymers with Various Functional Groups in the Mainchain; C. Synthesis and Reactions of Titanacycle-Containing Polymers; i. Polymers Containing Titanacyclopentadiene Unit in the Mainchain; ii. Polymers Possessing Other Titanacycle Units; III. Summary; IV. References; 4. Mechanistic Aspects of the Photodegradation of Polymers Containing Metal-Metal Bonds Along Their Backbones; I. Introduction; II. General Overview of Polymer PhotodegradationA. The Auto-Oxidation Mechanism; B. Reactions of Hydroperoxide Species That Lead to Backbone Degradation; C. Other Photochemical Degradation Mechanisms; D. Methods for Intentionally Making Polymers Photodegradable; III. Metal-Metal Bond-Containing Polymers; A. Synthesis and Characterization; B. Synthesis of the Difunctional Dimers; C. Synthesis of the Polymers; D. Characterization of the Polymers; E. Photochemical Reactions in Solution; F. Photochemistry in the Solid State; IV. Factors Controlling the Rate of Photochemical Degradation; A. Cage Effects
• Sommario/riassunto: This series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. The sixth volume in this series provides useful descriptions of the transition metals and their applications, edited by high-quality team of macromolecular experts from around the world.