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Record Nr. |
UNINA9910877331303321 |
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Titolo |
Reactions catalyzed by inorganic compounds / / founding editor J.J. Zuckerman; editor, Arlan D. Norman |
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Pubbl/distr/stampa |
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ISBN |
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1-282-30826-2 |
9786612308260 |
0-470-14531-5 |
0-470-14552-8 |
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Descrizione fisica |
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1 online resource (686 p.) |
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Collana |
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Inorganic reactions and methods ; ; v. 16 |
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Altri autori (Persone) |
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ZuckermanJ. J <1936-1987.> (Jerold J.) |
NormanArlen D |
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Disciplina |
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Soggetti |
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Catalysis |
Chemical reactions |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and indexes. |
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Nota di contenuto |
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Inorganic Reactions and Methods; Contents; How to Use this book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 16; Reactions Catalyzed by Inorganic Compounds; Introduction: Principles of Catalysis; Catalysis as a Kinetic Phenomenon; Basic Processes in Molecular Catalysis; Electron Transfer; Ligand Dissociation and Association Processes; Heterolytic Ligand Dissociation.; Homolytic Ligand Dissociation.; Promotion of Nucleophilic Reactions by Electron Withdrawal from Reactants; Catalysis of Electrophilic Reactions by Proton Loss from a Coordinated Ligand |
Oxidative Addition/Reductive Elimination ReactionsOne-Electron Oxidative Addition.; Two-Electron Oxidative Addition.; Free Radical Chain Mechanism of Oxidative Addition.; Insertion Reactions; Types of Catalysts; Introduction; Solid Catalysts; Metallic Catalysts; Metal Crystals and Films.; Supported Metal Catalysts.; Metal Oxide and Metal Sulfide Catalysts; Soluble Catalysts; Selectivity Advantages; Process Engineering and Product Recovery Problems; Supported Metal Complexes; Polymeric Supports; Metal Oxide Supports; Phase Transfer |
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Catalysis; Catalysis in Microscopic Phases |
Production of Catalysts and SupportsGeneral Principles; Methods of Production of Nonmetal Catalysts and Supports; Precipitation and Gel Formation.; Impregnation.; Natural Materials, Leaching, Carbon supports.; Methods of Production of Supported Metal Catalysts; Relationships between Catalyst Production and Performance; Hydrogenation Reactions; Introduction; Dihydrogen Activation; Homolytic Cleavage to Give Metal-Hydrides; Heterolytic Cleavage to Give Metal-Hydrides; Molecular Hydrogen Complexes; Classes of Soluble Catalysts; Rhodium(I) Catalysts; Cobalt Cyanide Systems |
Cobalt Carbonyl CatalystsChromium(0) Carbonyl Catalysts; Ziegler Catalysts; Ruthenium(lI) Catalysts; Hydrogenation of Aliphatic C-C Functions; In Simple Olefins; Isolated Double Bonds.; Olefins Conjugated to Carbonyl, Nitrile, Nitro.; Vinyl Functions.; In Conjugated Dienes; In Unconjugated Dienes; In Acetylenes and Cumulenes; In Triple Bonds.; In Allenes and Cumulenes.; By Asymmetric Hydrogenation; Hydrogenation of Arenes; By Cobalt Catalysts; By Ruthenium Catalysts; by Rhodium Catalysts; By Palladium and Platinum Catalysts; By Miscellaneous Catalysts; Hydrogenation of C=O Functions |
In AldehydesSaturated Aliphatic Aldehydes.; Aromatic Aldehydes.; Selectivity.; In Ketones; Hydrogenation to the Carbinol.; Hydrogenolysis and Miscellaneous Reactions.; Selectivity.; Stereochemistry and Asymmetric Hydrogenation.; In Carboxyl Derivatives; By Transfer Hydrogenation; Hydrogenation of Other Functional Groups; Nitrites; Hydrogenation to Primary Amines.; Coupling Reactions.; Reductive Hydrolysis.; Hydrogenolysis and Cyclizations.; Nitro Compounds; Hydrogenation to the Amine.; Selective and Partial Reductions.; Side Reactions in Polyfunctional Molecules.; Miscellaneous |
Addition Reactions |
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Sommario/riassunto |
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For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson).Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research.The work is indexed in a unique way by a structured system which maximizes its use |
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