1.

Record Nr.

UNINA9910877320303321

Titolo

Organoiron polymers / / edited by Alaa S. Abd-El-Aziz ... [et al.]

Pubbl/distr/stampa

Hoboken, N.J., : Wiley-Interscience, c2004

ISBN

1-280-34385-0

9786610343850

0-470-24444-5

0-471-46656-5

0-471-46657-3

Descrizione fisica

1 online resource (305 p.)

Collana

Macromolecules containing metal and metal-like elements, , 1545-438X ; ; v. 2

Altri autori (Persone)

Abd-El-AzizAlaa S

Disciplina

547/.05621

Soggetti

Ferrocene

Organometallic polymers

Organoiron compounds

Macromolecules

Metal complexes

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Macromolecules Containing Metal and Metal-Like Elements Volume 2; Contributors; Contents; Preface; Series Preface; 1. Overview of Organoiron Polymers; I. Introduction; II. Ferrocene-Based Polymers; III. Polymers Containing Cyclopentadienyliron-Complexed Arenes; IV. Polymers Containing Iron Carbonyl Complexes; V. Iron Polyynes; VI. Polymers with Iron-Iron Bonds; VII. Outlook; VIII. References; 2. Synthesis and Properties of Hyperbranched Polyferrocenylenesilynes; I. Introduction; II. Polymer Synthesis; III. Structural Characterization; IV. Electronic and Thermal Transitions

V. Pyrolytic CeramizationVI. Ceramic Composition; VII. Magnetic Susceptibility; VIII. Summary and Perspectives; IX. Experimentation; A. Materials; B. Instrumentation; C. Polymerization; D. Ceramization; X. Acknowledgments; XI. References and Notes; 3. Ring-Opened Polyferrocenes: Metal-Containing Polymers for Materials Science, Self-Assembly, and Nanostructure Applications; I. Introduction; II. Properties



of Polyferrocenylsilanes; III. Water-Soluble PFS Derivatives for Layer-by-Layer Self-Assembly Applications

IV. Metal-Containing Block Copolymers: Formation of Self-Assembled, Supramolecular Materials and Nanoscopic Ceramic PatternsV. Summary; VI. Acknowledgments; VII. References; 4. Synthesis and Solution Self-Assembly of Polyferrocene-Based AB Diblock and ABC Triblock Copolymers; I. Introduction; II. Results and Discussion; A. Synthesis and Aqueous Micellization of PFS-PDMAEMA; B. Synthesis and Micellization of PFP-PFS-PDMS; III. Summary and Outlook; IV. References

5. Synthesis and Self-Assembly of Polyisoprene-block-Polyferrocenyldimethylsilane Diblock Copolymers: Fabrication of Ceramic Nanolines on Semiconducting SubstratesI. Introduction; II. Experimental; III. Results and Discussion; A. Block Copolymer Synthesis; B. PI-b-PFDMS Micelles; C. Fabrication of Ceramic Nanolines; IV. Conclusions; V. Acknowledgments; VI. References; 6. Water-Soluble Polyferrocenylsilanes for Supramolecular Assemblies by Layer-by-Layer Deposition; I. Introduction; II. Synthesis of Polyferrocenylsilane Polyions; III. Polymer Characterization; IV. Multilayer Characterization

V. Patterned Polyferrocenylsilane Multilayer Thin FilmsVI. Summary; VII. Experimentation; VIII. Acknowledgment; IX. References; 7. Metal-Containing Polymers for High-Performance Resist Applications; I. Introduction; II. Organic Resists; A. Chemical Amplification; III. Inorganic Resists; IV. Organic-Inorganic Composite Resists; V. Organometallic Polymers; A. Polyferrocenyldimethylsilane as Reactive Ion Etch Barrier; B. Printing of Organometallic Polymers by Soft Lithography; 1. Directed Dewetting; VI. Organic-Organometallic Block Copolymers

A. Structure Formation via Block Copolymer Self-Assembly

Sommario/riassunto

Metal- and metalloid-containing macromolecules are defined as large molecules (i.e., polymers, DNA, proteins) that contain a metal or metalloid group affiliated with the molecule.  Compiled by an all-star cast of macromolecular experts, Macromolecules Containing Metal and Metal-Like Elements, Volume 2, Organoiron-Containing Polymers:Provides useful descriptions of applications for the reader to apply in his/her research into materials, polymers, and medicine/drug development.Covers non-linear optical materials, speciality magnetic materials, liquid crystals, anticance