Isoxazoles . Part one / / Paolo Grunanger, Paola Vita-Finzi

• Record Nr.: UNINA9910877238203321
• Autore: Grunanger Paolo
• Pubbl/distr/stampa: New York, : John Wiley & Sons, 1991
• ISBN: 1-282-30723-1; 9786612307232; 0-470-18735-2; 0-470-18887-1
• Descrizione fisica: 1 online resource (904 p.)
• Collana: Chemistry of heterocyclic compounds, , 0069-3154 ; ; v. 49
• Altri autori (Persone): Vita-FinziPaola; DowlingJames Edward <1966->
• Disciplina: 547.592; 547/.59/05; 547/.592
• Soggetti: Oxazoles; Chemistry
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and indexes.
• Nota di contenuto: ISOXAZOLES; The Chemistry of Heterocyclic Compounds Introduction to the Series; Preface; Contents; CHAPTER 1; 1. Isoxazoles; 1.1 Introduction; 1.2 Physicochemical Properties; 1.2.1 Infrared Spectra; 1.2.2 Ultraviolet Spectra; 1.2.3 Nuclear Magnetic Resonance Spectra; 1.2.3.1 PMR Spectra; 1.2.3.2 I3C-NMR Spectra; 1.2.3.3 I4N- and ""N-NMR Spectra; 1.2.3.4 Other Nuclei NMR Spectra; 1.2.4 Mass Spectra; 1.2.5 Other Spectra; 1.2.5.1 Microwave Spectra; 1.2.5.2 Photoelectron Spectra; 1.2.5.3 Electron Paramagnetic Resonance Spectra; 1.2.5.4 Electron Spin Resonance Spectra; 1.2.5.5 Nuclear Quadrupole Resonance Spectra1.2.5.6 Other Spectra; 1.2.6 Crystal and Molecular Structure; 1.2.7 Dipole Moments; 1.2.8 Theoretical Calculations; 1.2.8.1 Reactivity, Aromaticity, and Electron Density; 1.2.8.2 Molecular Geometry; 1.2.8.3 Basicity and Dipole Moments; 1.2.8.4 Ionization Potentials; 1.2.8.5 Molecular Core Binding Energy; 1.2.8.6 Spectroscopic Data and Conformational Analysis; 1.2.9 Basicity; 1.2.10 Miscellaneous Data; 1.2.11 Analytical Methods; 1.3 Methods of Preparation; 1.3.1 [CCC + NO] Processes; 1.3.1.1 ; Oximation of 1, 3-Dicarbonyl (and Related) Compounds; 1.3.1.2 Oximation of a-Acetylenic Carbonyl (and Related) Compounds1.3.1.3 Oximation of a-Dihalocarbonyl (and Related) Compounds; 1.3.1.4 Oximation of z, 8-Ethylenic Carbonyl (and Related) Compounds 8-Substituted with Electron-Withdrawing Groups; 1.3.1.5 Oximation of a, b-Ethylenic Carbonyl (and Related) Compounds; 1.3.1.6 Other Oximation Reactions; 1.3.1.7 Synthesis from Unsaturated Compounds and Nitric (Nitrous) Acid; 1.3.1.8 Nitrosation of Ketodicarboxylic Esters; 1.3.2 [CNO + CC] Processes; 1.3.2.1 Cycloaddition of Nitrile Oxides (or Their Precursors) to Acetylenic Compounds; 1.3.2.2 Cycloaddition of Nitrile Oxides (or Their Precursors) to Ethylenic Compounds1.3.2.3 Cycloaddition of Nitrile Oxides (or Their Precursors) with Active Methylene Compounds; 1.3.2.4 Cycloaddition of Nitrile Oxides (or Their Precursors) with Sodium Acetylides or Acetylenic Grignard Reagents; 1.3.2.5 Other [CNO + CC] Processes; 1.3.3 [CNO + 2C] Processes: Syntheses from Nitro Derivatives; 1.3.4 [CCNO + C] Processes; 1.3.4.1 Synthesis from Oxime Dilithium Salts and Carboxylic Acid Derivatives; 1.3.4.2 Reaction of a-Chloroketoximes with Ylides; 1.3.5 [CCCN + O] Process; 1.3.6 Cyclization Processes1.3.6.1 [OCCCN] Processes; 1.3.6.2 [CCCON] Processes; 1.3.6.3 [CCNOC] Processes; 1.3.6.4 [CCCNO] Processes; 1.3.7 From Heterocyclic Compounds; 1.3.7.1 From Other 1, 2-Oxazole Derivatives; 1.3.7.2 From Other Heterocycles; 1.4 Chemical Properties; 1.4.1 Protonation and Quaternization; 1.4.2 Complexation; 1.4.2.1 Metallic Complexes; 1.4.2.2 Molecular Complexes; 1.4.3 Reduction Reactions; 1.4.3.1 Hydrogenolytic Ring Cleavage; 1.4.3.2 Reductions without Ring Cleavage; 1.4.4 Oxidation Reactions; 1.4.5 Thermolysis and Photolysis; 1.4.6 Reactions with Nucleophiles; 1.4.6.1 Reactions with Ring Cleavage
• Sommario/riassunto: Isoxazoles. Isoxazolines (Dihydroisoxazoles). Isoxazolidines (Tetrahydroisoxazoles). References. Index.