Electron-transfer and electrochemical reactions : photochemical and other energized reactions / / editor, J.J. Zuckerman; subject index editor, A.P. Hagen

• Record Nr.: UNINA9910877143303321
• Pubbl/distr/stampa: [Deerfield Beach, FL], : VCH, c1986
• ISBN: 1-282-30827-0; 9786612308277; 0-470-14530-7; 0-470-14551-X
• Descrizione fisica: 1 online resource (426 p.)
• Collana: Inorganic reactions and methods ; ; v. 15
• Altri autori (Persone): ZuckermanJ. J <1936-1987.> (Jerold J.)
• Disciplina: 541.3/9; 541.39
• Soggetti: Photochemistry; Charge transfer
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references.
• Nota di contenuto: Inorganic Reactions and Methods; Contents; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 15; Electron-Transfer and Electrochemical Reactions; Introduction; Electron Transfer; Introduction; Classification of Electron-Transfer Reactions; Outer-Sphere Reactions; Examples of Outer-Sphere Reactions; Outer-Sphere Transition States; Inner-Sphere Reactions; Inner-Sphere Reactions: Scheme I; Inner-Sphere Reactions: Scheme II; Inner-Sphere Reactions: Scheme Ill; Double-Ligand Bridging; Other Reaction Classes; Mixed Outer- and Innersphere ReactionsIntramolecular Electron Transfer; Two-Electron Transfers; Theory of Electron-Transfer Reactions; The Stability of the Precursor Complex; Potential-Energy Surfaces; of Zero Order.; of First Order.; The Electronic Factor; Electron-Exchange Reactions; The Reorganization Energy; Nuclear Tunneling in Electron Exchange; Quantum-Mechanical Treatment; Comparison of Observed and Calculated Parameters for Electron Exchange; Electron Transfer Accompanied by a Net Chemical Change; Semiclassical ; Treatment; Cross Reactions and Electron-Exchange Rates; Quantum-Mechanical TreatmentConclusions; General Reactivity Patterns in Electron Transfer; The Inner-Shell Reorganization Energy: Exchange Rates of Aquo Ions; Variations with Ligand: The Outer-Shell Reorganization Energy; Electronic Factors: Nonadiabaticity; Free-Energy Relations; Inner-Sphere Versus Outer-Sphere Electron Transfer; Rate Saturation in Electron Transfer; Specific Reactivity Patterns in Electron-Transfer Reactions; Variation with the Reductant; One-Electron Reductants; Two-Electron Reductants; Variation with the Oxidant; One-Electron Oxidants; Multiple-Electron Oxidants; Oxidation and Reduction of Coordinated LigandsCatalysis in Electron-Transfer Reactions; Catalyzed Electron Transfer; Catalyzed Ligand Substitution; Induced Electron-Transfer Reactions; Photoinduced Electron-Transfer Reactions; Electrochemical Reactions; Introduction; The Electrode Process; Reversibility; Electrochemical Reversibility; Chemical Reversibility; Complex Electrode Mechanisms; Diagnostic Electrochemical Measurements; Voltammetric Methods; Direct-Current Polarography; Pulse-Polarographic Methods; Alternating-Current Polarography; Cyclic Voltammetry; Evaluation of Formal Potentials; Involving Stable Reactants and Products.Involving Unstable Electrode Products.; Involving Reactants Undergoing Multiple- Electrode Reactions.; Chemical Reactions Accompanying Electrode Reactions; Reactions Preceding Electron Transfer (CE); Slow-Reaction (1 >a) Limit; Intermediate-Reaction Kinetics; Reactions Following Electron Transfer (EC); Giving Electroinactive Products.; Giving Electroactive Products (ECE).; Other Coupled Chemical Reactions; Electrochemical Synthesis; by Controlled-Potential Electrolysis.; Involving Bulk Preparations.; Conclusions; Thermodynamics of Simple Electrochemical Reactions
• Sommario/riassunto: How to Use this Book. Preface to the Series. Editorial Consultants to the Series. Contributors to Volume 15. 12. Electron-Transfer and Electrochemical Reactions. 12.1. Introduction. 12.2. Electron Transfer. 12.3. Electrochemical Reactions. 13. Photochemical and Other Energized Reactions. 13.1. Introduction. 13.2. Photosubstitution and Photoisomerization. 13.3. Photoinduced Cleavage of Metal-Metal Bonds. 13.4. Photoinduced Electron-Transfer Reactions. 13.5. Pulse Radiolysis. List of Abbreviations. Author Index. Compound Index. Subject Index