1.

Record Nr.

UNINA9910877114503321

Autore

Pérez Emilio M

Titolo

Mechanically Interlocked Materials : Polymers, Nanomaterials, MOFs, and More

Pubbl/distr/stampa

Newark : , : John Wiley & Sons, Incorporated, , 2024

©2024

ISBN

9783527828951

3527828958

9783527828968

3527828966

9783527828975

3527828974

Edizione

[1st ed.]

Descrizione fisica

1 online resource (300 pages)

Disciplina

547.1226

Soggetti

Molecular machinery

Metal-organic frameworks

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Nota di contenuto

Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Force‐Promoted Transformations in Mechanically Linked Molecules --   1.1 Introduction --   1.2 SMFS in the Study of Non‐covalent Interactions --     1.2.1 Rotaxanes --     1.2.2 Poly‐(pseudo)rotaxanes --     1.2.3 Catenanes --   1.3 Strength of Mechanical Bonds --     1.3.1 Polymers Containing a Rotaxane --     1.3.2 Polymers Containing a Catenane --   1.4 Changes in Optical Properties – Reversible and Irreversible Changes of Optical Properties by Movement of Macrocycle in a Rotaxane --   1.5 Conclusions --   References -- Chapter 2 Colloidal Nanomaterials with Mechanically Interlocked Parts --   2.1 Introduction --   2.2 Installing and Actuating Mechanically Interlocked Molecular Architectures at Colloidal Nanoparticle Surfaces --   2.3 Modulating Nanoparticle Physicochemical Properties Using Switchable Mechanically Interlocked Architectures --   2.4 Interlocked Gates for Nanoparticle Pores: From Cargo Release to Nanoscale Communication --     2.4.1 Optimizing Mechanisms for Cargo Release --     2.4.2 Autonomous Drug Delivery



Triggered By Endogenous Conditions --     2.4.3 Cargo Release Using Tissue‐Penetrating External Triggers --     2.4.4 Nanoscale Communication Between Responsive Nanoparticles --   2.5 Mechanically Interlocked Molecular Links for Nanoparticle Assemblies --     2.5.1 Pseudorotaxane‐linked Nanoparticle Assembly–Disassembly --     2.5.2 Fully Interlocked Molecular Links for Nanoparticle Assemblies --   2.6 From Switches to Motors and Beyond: The Future of Colloidal Nanomaterials with Mechanically Interlocked Parts

Sommario/riassunto

This book, edited by Emilio M. Pérez, explores the field of mechanically interlocked molecules (MIMs) and their applications in materials science. It covers a variety of topics including the synthesis and properties of rotaxanes and catenanes, the interaction of MIMs with metal-organic frameworks (MOFs), and their use in molecular motors and nanotubes. The book also delves into the creation and utility of DNA-based interlocked structures, as well as synthetic mechanically interlocked polymers. Targeting researchers and professionals in chemistry and materials science, the book aims to provide an in-depth understanding of the dynamic mechanical properties of MIMs and their potential to advance technology in diverse fields.