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Record Nr. |
UNINA9910876936903321 |
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Autore |
Mason W. Roy |
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Titolo |
A practical guide to magnetic circular dichroism spectroscopy / / W. Roy Mason |
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Pubbl/distr/stampa |
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Hoboken, N.J., : Wiley-Interscience, c2007 |
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ISBN |
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1-280-91673-7 |
9786610916733 |
0-470-13923-4 |
0-470-13922-6 |
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Descrizione fisica |
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1 online resource (237 p.) |
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Disciplina |
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Soggetti |
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Molecular spectroscopy |
Molecular spectra |
Magnetic circular dichroism |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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A PRACTICAL GUIDE TO MAGNETIC CIRCULAR DICHROISM SPECTROSCOPY; CONTENTS; PREFACE; 1. Introduction; 2. Polarized Light; 2.1. Linear Polarization and Plane Polarized Waves; 2.2. Circular Polarization and Circularly Polarized Waves; 2.3. Absorption Probabilities; 3. Theoretical Framework: Definition of MCD Terms; 3.1. Born-Oppenheimer/Franck-Condon Approximation; 3.2. Rigid-Shift Approximation; 3.3. A(1)-, B(0)-, and C(0)-Term Parameters; 3.4. A Terms; 3.5. C Terms; 3.6. B Terms; 3.7. Pseudo A Terms: Overlapping B Terms; 3.8. Overlapping C Terms; 3.9. Ground-State Near Degeneracy |
5.3. The Wigner-Eckart Theorem and Reduced Matrix Elements (RMEs)5.4. MCD-Term Equations Involving RMEs; 5.5. Evaluation of RMEs for MCD Terms; 5.6. Evaluation of Matrix Elements for LCAO-MO Functions; 5.7. Spin-Orbit Coupling Considerations; 5.8. Herzberg-Teller Approximation for Vibronic Transitions; 6. Case Studies I. Diamagnetic Systems: A and B Terms; 6.1. A and B Terms for Diamagnetic Atoms and Molecules; 6.2. Atomic Mercury Vapor; 6.3. The Sodide Ion Na(-) in a Solid NH(3) Matrix; 6.4. Square Complexes of D(4h) Symmetry; 6.4.1. Ligand Field Spectra for PtCl4(2-)(4) |
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