s-Triazines and derivatives / / Edwin M. Smolin and Lorence Rapoport

• Record Nr.: UNINA9910876692503321
• Autore: Smolin Edwin M
• Pubbl/distr/stampa: New York, : Interscience Publishers, 1959
• ISBN: 1-282-30147-0; 9786612301476; 0-470-18662-3; 0-470-18812-X
• Descrizione fisica: 1 online resource (670 p.)
• Collana: The chemistry of heterocyclic compounds ; ; 13
• Altri autori (Persone): RapoportLorence <1919-1999.>
• Disciplina: 547; 547/.59/05
• Soggetti: Triazines; Heterocyclic compounds
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliography.
• Nota di contenuto: s-Triazines and Derivatives; Contents; Introduction; I. General; II. s-Triazine; 1. General; 2. Synthesis; 3. Reactions; A. Salt Formation; B. Hydrolysis; C. Reaction with Hydrogen Chloride; D. Reaction with Amines; E. Reaction with Halogens; F. Reaction with Sodamide; G. Hydrogenation; H. Friedel-Crafts Reaction of s-Triazine and Its Hydrochloride Derivatives; I. Grignard Reaction; I. Cyanuric Acid and Derivatives; I. Introduction; II. Cyanuric Acid; 1. Historical; 2. Physical Properties; A. General; B. Density; C. Thermal Properties; D. Heat of Neutralization; E. Dissociation Constant; F. Percentage Dissociated at 35°G. Conductivity; H. Viscosity and Density of Solutions; I. Specific Heat; J. Magnetic Susceptibility; K. Raman, Infrared, and Ultraviolet Spectra; L. Polarographic Behavior; M. Crystallography and Miscellaneous Properties; 3. Synthesis and Occurrence; A. Natural Occurrence; B. From Cyanuric Halides; C. Polymerization of Cyanic Acid; D. From Urea and Urea Derivatives; E. From Uric Acid; F. From Allophanates and Carbamyl Chlorides; G. From Carbonyl Diurethane and Carbethoxybiuret; H. From Formamide Electrolytically; I. From Acetoxamide; J. From Carbaminothioglycolic Acid AnilideK. Miscellaneous ; Preparations; 4. Structure; 5. Salts of Cyanuric Acid; 6. Reactions of Cyanuric Acid; A. Hydrolysis; B. Reaction with Active Halogen Compounds; C. Thermal Action; D. Reaction with Ammonia; E. Esterification; F. Acetylation; G. Reaction with Fatty Acids; H. Reaction with α-Haloacids; I. Rearrangement .; 7. Applications of Cyanuric Acid; A. Physiological and Technical Significance; B. Melamine Formation; C. Rubber Manufacture; D. Resins; III. Cyanuric Halides; 1. Cyanuric Chloride; A. History; B. Physical Properties; C. Synthetic Methods(1) From Cyanogen Chloride; (2) From Hydrocyanic Acid; (3) From Cyanuric Acid; (4) Miscellaneous Methods; D. Structure; E. Reactions; (1) Hydrolysis and Alcoholysis; (2) Reaction with Hydroxy Compounds; (3) Reaction with Amino Compounds; (4) Reaction with Sulfhydryl Compounds; (5) Reaction with Salts of Hydrazoic Acid; (6) Reaction with Silver Nitrate; (7) Grignard Reaction; (8) Wurtz-Fittig Reaction; (9) Friedel-Crafts Reaction; (10) Reaction with Carboxylic Acids and Salts; (11) Reaction with Malonic Ester; (12) Reaction with Hydriodic Acid; (13) Reduction; (14) Reaction with BenzamideF. Physiological Properties; 2. Cyanuric Bromide; A. Synthesis; (1) Polymerization of Cyanogen Bromide; (2) From Bromine and Potassium Ferrocyanide; B. Reactions and Structure; (1) Hydrolysis; (2) Reaction with Amines; (3) With Acetic Acid; (4) Reaction with Urea; 3. Cyanuric Iodide; 4. Cyanuric Fluoride; 5. 2-Bromo-4,6-dichloro-s-triazine; 6. 2-Chloro-4,6-diiodo-s-triazine; IV. Cyanuric Acid Esters; 1. Alkyl Esters; A. Methyl Esters; (1) Trimethyl Ester; (2) Diethyl Ester; (3) Halomethoxy-s-triazines; (4) Mixed Methyl Esters; B. Ethyl Esters; (1) Triethyl Ester; (2) Dimethyl Ester
• Sommario/riassunto: Chemistry of Heterocyclic Compounds publishes articles, letters to the Editor, reviews, and minireviews on the synthesis, structure, reactivity, and biological activity of heterocyclic compounds including natural products. The journal covers investigations in heterocyclic chemistry taking place in scientific centers of all over the world, including extensively the scientific institutions in Russia, Ukraine, Latvia, Lithuania and Belarus.