1.

Record Nr.

UNINA9910876548503321

Titolo

Stereochemical aspects of organolithium compounds / / Robert E. Gawley, ed

Pubbl/distr/stampa

Weinheim ; ; Chichester, : Wiley-VCH, c2010

ISBN

1-283-14107-8

9786613141071

3-906390-62-4

3-906390-63-2

Edizione

[2nd ed.]

Descrizione fisica

1 online resource (307 p.)

Collana

Topics in stereochemistry ; ; 26

Classificazione

VK 5800

Altri autori (Persone)

GawleyRobert E

Disciplina

547.05381

Soggetti

Organolithium compounds

Lithium

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references.

Nota di contenuto

Stereochemical Aspects of Organolithium Compounds; Foreword; Preface; Contributors; Contents; Chapter 1 Asymmetric Deprotonations Using Chiral Lithium Amide Bases; Chapter 2 Self-Regeneration of Stereocenters (SRS) via Stereolabile Axially Chiral Intermediates; Chapter 3 Overview of Carbanion Dynamics and Electrophilic Substitutions in Chiral Organolithium Compounds; Chapter 4 Oxiranyllithiums as Chiral Synthons for Asymmetric Synthesis; Chapter 5 Test on the Configurational Stability/Lability of Organolithium Compounds

Chapter 6 Mechanism and Stereochemical Features in Asymmetric Deprotonation Using RLi/(-)-Sparteine BasesChapter 7 Dynamic Resolutions of Chiral Organolithiums

Sommario/riassunto

This series deals with important issues in stereochemistry, which is the three-dimensional spatial orientation of molecules, also called the chirality (or handedness) of molecules. Topics in Stereochemistry, previously edited by ""the father of stereochemistry"" Ernest L. Eliel, is a longstanding, successful series covering the most important advances in the field. The much-anticipated Volume 26 on stereochemical aspects of organolithium compounds includes chapters on Asymmetric



Deprotonations Using Chiral Lithium Amide Bases, Self-Regeneration of Stereocenters (SRS) via Stereolabile Axially C