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Record Nr. |
UNINA9910840524803321 |
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Titolo |
Activating unreactive substrates [[electronic resource] ] : the role of secondary interactions / / edited by Carsten Bolm and F. Ekkehardt Hahn |
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Pubbl/distr/stampa |
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Weinheim, : Wiley-VCH, c2009 |
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ISBN |
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1-282-02201-6 |
9786612022012 |
3-527-62546-1 |
3-527-62547-X |
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Descrizione fisica |
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1 online resource (483 p.) |
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Altri autori (Persone) |
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BolmCarsten |
HahnF. Ekkehardt |
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Disciplina |
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Soggetti |
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Catalysis |
Activation (Chemistry) |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Activating Unreactive Substrates: The Role of Secondary Interactions; Contents; Preface; List of Contributors; 1 Chemistry of Metalated Container Molecules; 1.1 Introduction; 1.2 Metalated Container Molecules: A Brief Overview; 1.3 Metalated Container Molecules of Binucleating Supporting Ligands; 1.3.1 Synthesis; 1.3.2 Coordination Chemistry of Binucleating Supporting Ligands; 1.3.3 Effects of N-alkylation on the Molecular and Electronic Structures of the Complexes; 1.3.4 The Ligand Matrix as a Medium; 1.3.5 Variation, Coordination Modes and Activation of Coligands |
1.3.6 Reactivity of the Complexes1.4 Conclusions; References; 2 The Chemistry of Superbasic Guanidines; 2.1 Properties of the Guanidine Functionality; 2.2 Design of Superbasic Proton Sponges; 2.3 Some Perspectives in Proton Sponge Chemistry; 2.4 Multidentate Superbasic Guanidine Ligands as Receptors for Metal Cations; 2.5 The Chemistry of Guanidine Copper Complexes; 2.6 The Chemistry of Guanidine Zinc Complexes; 2.7 Conclusions; References; 3 Iron Complexes and Dioxygen Activation; 3.1 Introduction; 3.2 Dinuclear Iron Peroxo |
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