1.

Record Nr.

UNINA9910831067503321

Autore

Staab Heinz A

Titolo

Azolides in Organic Synthesis and Biochemistry

Pubbl/distr/stampa

[Place of publication not identified], : Wiley VCH Imprint, 1998

ISBN

1-280-55850-4

9786610558506

3-527-60083-3

Descrizione fisica

1 online resource (503 pages)

Disciplina

547.0430459

Soggetti

Amides

Azo Compounds

Heterocyclic compounds - Synthesis

Organic chemistry

Organic compounds - Synthesis

Pyrroles

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Bibliographic Level Mode of Issuance: Monograph

Nota di contenuto

Reactivity of azolides -- Preparation and properties of azolides -- Syntheses of carboxylic and carbonic esters -- Syntheses of amides and analogous compounds with CO-NR functions -- Synthesis of peptides -- Modification and immobilization of proteins (enzymes) -- Syntheses of heterocycles -- Synthesis of isocyanates, isothiocyanates, aminoisocyanates, aminoisothiocyanates, and N-sulfinylamines -- Reactions of imino analogues of azolides -- Syntheses of sulfonates, sulfinates, sulfonamides, sulfoxylates, sulfones, sulfoxides, sulfites, sulfates, and sulfanes -- Reaction of phosphines with N, N1-carbonyldiimidazole (CDI) -- Phosphorylation and nucleotide-syntheses -- Syntheses of acid anhydrides and acyl chlorides -- C-Acylations by azolides -- Reduction of azolides to aldehydes and alcohols -- Deoxygenation of alcohols and C-C coupling reactions -- Synthesis of glycosides and ethers -- Dehydration reactions -- Substitution reactions on azoles -- Azoic-transfer reactions to carbon atoms -- Syntheses of organic halides/pseudohalides and aromatic amines -- Reactions of vinylogous azolides -- Photochemical reactions --



Azolides in medicinal and industrial fields and in analytical methods.

Sommario/riassunto

Preparation, properties and the manifold synthetic applications of "azolides" in organic syntheses are the topics of this book. Since the first review in "Angewandte Chemie" in 1962, shortly after the discovery of this class of compounds by H. Staab, they became widely used in different fields of organic chemistry.