Cross conjugation : modern dendralene, radialene and fulvene chemistry / / edited by Henning Hopf and Michael S. Sherburn

• Record Nr.: UNINA9910830976503321
• Pubbl/distr/stampa: Weinheim, Germany : , : Wiley-VCH, , 2016; ©2016
• ISBN: 3-527-67118-8; 3-527-67121-8; 3-527-67120-X
• Descrizione fisica: 1 online resource (601 p.)
• Disciplina: 612.1111
• Soggetti: Bioconjugates
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references at the end of each chapters and indexes.
• Nota di contenuto: Title Page; Copyright; Table of Contents; List of Contributors; Preface; Chapter 1: Synthesis of Dendralenes; 1.1 Introduction; 1.2 Multibond Forming Processes; 1.3 Solo-Bond-Forming Reactions; 1.4 Dendralenes from Dendralenes; 1.5 Functional Group Interconversion Reactions; 1.6 Concluding Remarks; References; Chapter 2: The Diene-Transmissive Hetero-Diels-Alder Reaction; 2.1 Introduction; 2.2 DTHDA Reaction of Heterotrienes; 2.3 DTHDA Reaction with Heterodienophiles; References; Chapter 3: The Nazarov Cyclization of Cross-Conjugated Ketones; 3.1 Introduction; 3.2 Mechanism; 3.3 Substituent Effects3.4 Interrupted Nazarov Reactions; References; Chapter 4: [n]Radialenes; 4.1 Introduction; 4.2 Syntheses and Reactivity; 4.3 Structural and Bonding Properties; References; Chapter 5: Oxocarbons, Pseudo-oxocarbons, and Squaraines; 5.1 Introduction; 5.2 Oxocarbons and Coordination Chemistry; 5.3 Pseudo-oxocarbons; 5.4 Conclusion and Outlook; References; Chapter 6: Recent Developments in Fulvene and Heterofulvene Chemistry; 6.1 Introduction; 6.2 Triafulvenes; 6.3 Pentafulvenes and Related Compounds; 6.4 Heptafulvenes; 6.5 Other Fulvenes; References; Chapter 7: Constructing Molecular Complexity and Diversity by Cycloaddition Reactions of Fulvenes7.1 Introduction; 7.2 Reactions of ; Pentafulvenes; 7.3 Reactions of Heptafulvenes; 7.4 Reactions of Triafulvenes; 7.5 Conclusions; Acknowledgments; References; Chapter 8: Cross-Conjugation and Electronic Structure in TTF Analogs; 8.1 Introduction; 8.2 Dendralene-Type TTF Analogs and Related Compounds; 8.3 Radialene-Type TTF Analogs (DT-Substituted Radialenes); 8.4 Cross-Conjugated TTFs and Related Compounds Linked by π-Systems; References; Chapter 9: Cross-Conjugation in Expanded Systems; 9.1 Introduction9.2 Tetrathiafulvalene and Dithiafulvene; 9.3 Communication between Two Identical Redox Centers; 9.4 Cross-Conjugation and Optical Properties; 9.5 Conjugation and Molecular Electronics; 9.6 Conclusions; References; Chapter 10: Transition Metal Complexes of Cross-Conjugated π Systems; 10.1 Introduction; 10.2 Trimethylenemethane Complexes; 10.3 Fulvene Complexes; 10.4 Fulvalene Complexes; 10.5 Azulene Complexes; 10.6 Pentalene and Acepentalene Complexes; 10.7 Various Complexes; References; Chapter 11: Cross-Conjugation and Quantum Interference; 11.1 Introduction; 11.2 Molecular Electron Transport11.3 The Transport Properties of Cross-Conjugated Molecules; 11.4 Understanding and Predicting Interference; 11.5 More than Topology; 11.6 Conclusions; References; Chapter 12: Cross-Conjugation in Synthesis; 12.1 The Rapid Generation of Structural Complexity; 12.2 Diene-Transmissive Diels-Alder Reactions; 12.3 [3]Dendralenes; 12.4 Higher Dendralenes; 12.5 Applications; 12.6 The Radialenes; 12.7 Concluding Remarks; References; Author Index; Subject Index; End User License Agreement