Rheokinetics [[electronic resource] ] : rheological transformations in synthesis and reactions of oligomers and polymers / / A. Ya. Malkin and S.G. Kulichikhin

• Record Nr.: UNINA9910830970003321
• Autore: Malkin Aleksandr I͡Akovlevich
• Pubbl/distr/stampa: Zug ; ; Oxford, Conn., : Hüthig & Wepf, c1996
• ISBN: 1-281-84265-6; 9786611842659; 3-527-61495-8; 3-527-61494-X
• Descrizione fisica: 1 online resource (328 p.)
• Altri autori (Persone): KulichikhinS. G (Sergeĭ Grigorʹevich)
• Disciplina: 0068.9
• Soggetti: Polymers - Rheology
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Rheological Transformations in Synthesis and Reactions of Oligomers and Polymers; Table of Contents; Chapter 1 Introduction; 1.1 References for Chapter 1; Chapter 2 Rheokinetics of Linear Polymer Formation; 2.1 General; 2.2 Ionic Polymerization; 2.2.1 A Direct Rheokinetic Problem; 2.2.2 Anionic Polymerization with Varying Amounts of Active Centres; 2.2.3 An Inverse Kinetic Problem; 2.2.4 Experimental Methods; 2.2.5 Anionic Polymerization of Dodecalactam; 2.2.6 Increase of Viscosity during Anionic Polymerization with Changing Concentration of Active Centres; 2.2.7 Anionic Polymerization of &-caprolactam2.2.8 References for Section 2.2; 2.3 Free Radical Polymerization; 2.3.1 Rheokinetics of the Process - Theoretical Considerations; 2.3.2 Steady Stage of Polymerization - Experimental; 2.3.3 Viscosity of the Medium - Its Role; 2.3.4 Gel Effect; 2.3.5 Polymerization in Heterogeneous Medium; 2.3.6 References for Section 2.3; 2.4 Polycondensation; 2.4.1 Introduction; 2.4.2 Rheokinetic Pattern of the Process; 2.4.3 Experimental; 2.4.4 References for Section 2.4; Chapter 3 Rheokinetics of Oligomer Curing; 3.1 General principles; 3.1.1 References for Section 3.13.2 Determination of the Point of Gel Formation; 3.2.1 References for Section 3.2; 3.3 Viscosity Increase to ; the Point of Gel Formation; 3.3.1 References for Section 3.3; 3.4 Microphase Separation in Reactive Systems; 3.4.1 References for Section 3.4; 3.5 Curing After the Point of Gel Formation; 3.5.1 References for Section 3.5; 3.6 Rheokinetic Equations of Curing; 3.6.1 References for Section 3.6; 3.7 Non-isothermal Curing; 3.7.1 Causes of Non-isothermal Behaviour; 3.7.2 Determination of Kinetic Constants in an Adiabatic Process; 3.7.3 Non-isothermal Curing - Calculations3.7.4 Heat Transfer from an External Source (Linear Temperature Increase); 3.7.5 Curing at High Shear Rates; 3.7.6 References for Section 3.7; 3.8 Structuring Peculiarities of Different Forms of Oligomers and Polymers; 3.8.1 Curing Phenolformaldehyde Resins and Related Oligomers; 3.8.2 Production of Polyurethanes; 3.8.3 The Curing of Unsaturated Polyesters; 3.8.4 Silico-organic Polymers; 3.8.5 Amino-formaldehyde Resins; 3.8.6 Epoxy silico-organic Oligomers; 3.8.7 Rubber Compositions; 3.8.8 Thermo-reactive Pol yamides; 3.8.9 Epoxy Oligomers; 3.8.10 References for Section 3.8Chapter 4 Transformation in Polymeric Systems; 4.1 Polymer-analogous Transformations; 4.1.1 Transformations in the Solid Phase; 4.1.2 Photo-viscous Effect; 4.1.3 References for Section 4.1; 4.2 Gelation (Curing in Solution); 4.2.1 General Remarks; 4.2.2 Antithixotropy During Gel Formation; 4.2.3 The Role of the Solvent; 4.2.4 Gelation Kinetics; 4.2.5 Gelation of Plastisols; 4.2.6 References for Section 4.2; 4.3 Rheolunetics of Phase Transitions; 4.3.1 Plotting Phase Diagrams; 4.3.2 Crystallization; 4.3.3 Phase Transformations in Reactive Systems; 4.3.4 References for Section 4.3