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Record Nr. |
UNINA9910830965203321 |
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Autore |
Irie Masahiro |
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Titolo |
Diarylethene molecular photoswitches : concepts and functionalities / / Masahiro Irie |
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Pubbl/distr/stampa |
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Weinheim, Germany : , : Wiley-VCH GmbH, , [2021] |
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©2021 |
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ISBN |
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3-527-82286-0 |
3-527-34642-2 |
3-527-82285-2 |
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Descrizione fisica |
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1 online resource (239 pages) |
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Disciplina |
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Soggetti |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Introduction -- 1.1 General Introduction -- 1.2 Discovery of Diarylethene Molecular Photoswitches -- References -- Chapter 2 Reaction Mechanism -- 2.1 Basic Concepts -- 2.2 Theoretical Study -- 2.3 Reaction Dynamics -- 2.3.1 Cyclization Reaction -- 2.3.2 Cycloreversion Reaction -- References -- Chapter 3 Photoswitching Performance -- 3.1 Quantum Yield -- 3.1.1 Photocyclization Quantum Yield -- 3.1.2 Solvent Effect on Cyclization Quantum Yield -- 3.1.3 Photocycloreversion Quantum Yield -- 3.2 Thermal Stability -- 3.3 Fatigue Resistance -- 3.4 Fluorescence Property -- 3.4.1 Turn‐Off Mode Photoswitching -- 3.4.2 Turn‐On Mode Photoswitching -- 3.5 Chiral Property -- References -- Chapter 4 Photoswitchable Crystals -- 4.1 Dichroism -- 4.2 X‐Ray Crystallographic Analysis -- 4.3 Quantum Yield -- 4.4 Multicolored Systems and Nano‐Layered Periodic Structures -- 4.5 Fluorescent Crystals -- 4.6 Photomechanical Response -- 4.6.1 Surface Morphology Change -- 4.6.2 Reversible Shape Change -- 4.6.3 Bending Response of Mixed Crystals -- References -- Chapter 5 Memory -- 5.1 Single‐Molecule Memory -- 5.2 Near‐Field Optical Memory -- 5.3 Three‐Dimensional Optical Memory -- 5.4 Readout Using Infrared Absorption, Raman Scattering, and Refractive Index Changes -- References -- Chapter 6 Switches -- 6.1 Single‐Molecule |
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Conductance Photoswitch -- 6.2 Optical Switch Based on Refractive Index Change -- 6.3 Magnetism -- References -- Chapter 7 Surface Properties -- 7.1 Surface Wettability -- 7.2 Selective Metal Deposition -- 7.3 Subwavelength Nanopatterning -- References -- Chapter 8 Polymers and Liquid Crystals -- 8.1 Polymers -- 8.2 Liquid Crystals -- References -- Chapter 9 Applications -- 9.1 Organic Field‐Effect Transistors (OFETs) -- 9.2 Metal Organic Frameworks (MOFs). |
9.3 Super‐Resolution Fluorescence Microscopy -- 9.3.1 Control of Cycloreversion Quantum Yield -- 9.3.2 Fatigue Resistance -- 9.3.3 Photoswitching with Single‐Wavelength Visible Light -- 9.3.4 Super‐Resolution Bioimaging -- 9.4 Chemical Reactivity Control -- 9.5 Biological Activity -- 9.6 Color Dosimeters -- References -- Appendix A Synthesis Procedures of Typical Diarylethenes -- A.1 1,2‐Bis(2,4‐dimethyl‐5‐phenyl‐3‐thienyl)perfluorocyclopentene (7) [5-7] -- A.2 1,2‐Bis(2‐ethyl‐6‐phenyl‐1‐benzothiophene‐1,1‐ dioxide‐3‐yl)‐perfluorocyclopenetene (11) [8-10] -- References -- Index -- EULA. |
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