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Record Nr. |
UNINA9910830944803321 |
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Titolo |
Complex macromolecular architectures [[electronic resource] ] : synthesis, characterization, and self-assembly / / editors, Nikos Hadjichristidis ... [et al.] |
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Pubbl/distr/stampa |
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Singapore, : John Wiley & Sons (Asia) Pte Ltd., 2011 |
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ISBN |
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0-470-82827-7 |
1-283-37244-4 |
9786613372444 |
0-470-82515-4 |
0-470-82514-6 |
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Descrizione fisica |
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1 online resource (858 p.) |
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Classificazione |
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Altri autori (Persone) |
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HadjichristidisNikos <1943-> |
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Disciplina |
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Soggetti |
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Macromolecules |
Polymerization |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly; Contents; List of Contributors; Preface; About the Editors; Part One: Synthesis; 1 Cyclic and Multicyclic Topological Polymers; 1.1 Introduction; 1.2 The Progress on the Synthesis of Ring Polymers; 1.2.1 Ring-Expansion Polymerization; 1.2.2 Cyclization by Telechelic Polymer Precursors; 1.3 Functional Ring Polymers and Topology Effects Thereby; 1.3.1 Polymer Catenanes Using a Ring Polymer Precursor Having an H-Bonding Unit; 1.3.2 Single-Molecule Spectroscopy Using a Ring Polymer Having a Chromophore Unit |
1.3.3 Crystallization Dynamics Using a Defect-Free Ring Polymer1.4 New Developments in the Construction of Multicyclic Polymer Topologies; 1.4.1 Fused Multicyclic Polymers; 1.4.2 Spiro Multicyclic Polymers; 1.4.3 Bridged Multicyclic Polymers; 1.5 Conclusions and Perspectives; References; 2 Ultrarapid Approaches to Mild Macromolecular Conjugation; 2.1 Introduction; 2.2 RAFT-HDA Chemistry; 2.3 Ultrafast RAFT-HDA Chemistry; 2.4 Cycloadditions with |
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Strained or Activated Alkynes; 2.5 Thiol-Ene/Thiol-Yne Chemistry; 2.6 Thiol-Isocyanate Chemistry; 2.7 Thio-Bromo Chemistry |
2.8 Inverse Electron Demand Diels-Alder2.9 Cycloadditions Involving Nitrile Oxides; 2.10 Oxime Formation; 2.11 Tetrazole-Ene Reaction; 2.12 Concluding Remarks; References; 3 Synthesis and Self-Assembly of Hydrogen-Bonded Supramolecular Polymers; 3.1 Introduction; 3.1.1 Dynamics of Hydrogen Bonds; 3.1.2 Other Experimental Methods in Supramolecular Polymer Science; 3.2 Synthetic Strategies Towards Hydrogen-Bonded Supramolecular Polymers; 3.2.1 Carbocationic Polymerization; 3.2.2 Anionic Polymerization; 3.2.3 Ring-Opening Metathesis Polymerization (ROMP) |
3.2.4 Controlled Radical Polymerization (CRP)3.2.5 Polycondensation Methods; 3.2.6 Ring-Opening Polymerization (ROP); 3.2.7 Other Postmodification Methods; 3.3 Self-Assembly of Supramolecular Polymers via Hydrogen Bonds; 3.3.1 Microphase-Separated H-Bonded Polymers: Towards Pseudoblock Copolymers; 3.3.2 Ordering on Surfaces; 3.3.3 Small-Molecule Ordering into Polymers via H Bonds; 3.3.4 Applications of H-Bonded Supramolecular Polymers; 3.4 Conclusions and Outlook; Acknowledgment; References; 4 Recent Synthetic Developments in Miktoarm Star Polymers with More than Three Different Arms |
4.1 Introduction4.2 Miktoarm Star-Branched Polymers up to 2000; 4.3 Novel and Versatile Methodology Based on an "Iterative Approach" for Miktoarm Star Polymer Syntheses; 4.3.1 Iterative Methodology with Regeneration of DPE Function; 4.3.2 Iterative Methodology with Regeneration of Two or More DPE Functions; 4.3.3 Iterative Methodology with Regeneration of 1,3-Butadiene Function; 4.3.4 Iterative Methodology with Regeneration of Benzyl Bromide Function; 4.3.5 Convergent Synthesis of Miktoarm Star-Branched Polymers Using Polymer Anions |
4.4 Miktoarm Star Polymers by Other Methodologies Based on Living Anionic Polymerization |
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Sommario/riassunto |
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The field of CMA (complex macromolecular architecture) stands at the cutting edge of materials science, and has been a locus of intense research activity in recent years. This book gives an extensive description of the synthesis, characterization, and self-assembly of recently-developed advanced architectural materials with a number of potential applications. The architectural polymers, including bio-conjugated hybrid polymers with poly(amino acid)s and gluco-polymers, star-branched and dendrimer-like hyperbranched polymers, cyclic polymers, dendrigraft polymers, rod-coil and helix-coil b |
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