Inorganic reactions and methods . Volume 12A The formation of bonds to elements of group IVB (C, SI, Ge, Sn, Pb) . (Part 4) / / founding editor, J.J. Zuckerman ; editor, A.P. Hagen

• Record Nr.: UNINA9910830906203321
• Pubbl/distr/stampa: [Somerset] : , : VCH, , [1991]; ©1991
• ISBN: 1-282-30822-X; 9786612308222; 0-470-14527-7; 0-470-14548-X
• Descrizione fisica: 1 online resource (480 p.)
• Collana: Inorganic reactions and methods
• Disciplina: 541.3/9; 541.39
• Soggetti: Chemical reaction, Conditions and laws of; Inorganic compounds - Synthesis
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Includes index.
• Nota di bibliografia: Includes bibliographical references and indexes.
• Nota di contenuto: Inorganic Reactions and Methods; Contents; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 12A; The Formation of Bonds to Elements of Group IVB (C, Si, Ge, Sn, Pb) (Part 4); Formation of Bonds between Elements of Groups IVB (C, Si, Ge, Sn, Pb) and Transition and Inner-Transition Metals; Introduction.; Formation of the Carbon-Transition and Inner Transition Metal Bond.; from the Elements.; from Saturated Hydrocarbons.; n1 s-Alkyl Complexes by Direct Hydrocarbon Activation.; n1 s-Alkyl and -Aryl Complexes by Cyclometallation on y and More Remote Carbon-Hydrogen Bonds.n1 s-Alkyl Complexes by Cyclometallation of Donor Ligands.; Metallacycles by Oxidative Addition of Strained Carbocyclic Rings.; n2 pi-Olefin Complexes by B-Hydride Elimination.; Alkylidene Complexes by A-Hydride Elimination.; from Monoolefins; n2 pi-Olefin Complexes by Reaction of Metal Complexes with Monoolefins by Ligand Displacement.; n2 pi-olefin Complexes by Reaction of Metal Vapors with Monoolefins.; n1 s-Alkyl Complexes by ; Addition of Metal Hydrides to Monoolefins.; n1 s-Alkyl Complexes from Nucleophilic Attack on pi-Olefin Metal Complexes.n1 s-Alkyl Complexes by Insertion of Monoolefins into s-Alkyl-, s-Aryl-, s-Vinyl-, and s-AcyI-Metal Bonds.; Metallacycles from Insertion of Monoolefins into Metal-Carbene Complexes.; MetaIIacycles by CycIodimerization of Monoolefins.; pi-Allyl Complexes from Allylic C-H Bond Cleavage in olefins by Metal Complexes.; Metallacyclobutanes from Nucleophilic Attack on pi-Ally-Metal Complexes.; pi-Olefin Complexes from Nucleophilic Attack on pi-Ally-Metal Complexes.; Metal-Carbene Complexes from Olefin Metathesis Reactions.; from Conjugated DienesConjugated Diene Complexes by Reaction with Metal Complexes by Ligand Displacement.; Diene Complexes by Nucleophilic Attack on Metal Cationic Complexes.; Cationic Dienyl Complexes from Metal Diene Complexes.; pi-Allyl Complexes by Nucleophilic Attack.; pi-Allyl Metal Complexes by oligomerization of Conjugated Dienes.; pi-Allyl Metal Complexes by Metal- Atom and Related Reactions.; from Chelating Dienes; Chelating Diene Complexes by Direct Reaction with Metal Complexes via Ligand Displacement.; n1-s-Alkyl Complexes by Nucleophilic Attack on Metal- Chelating Diene Complexes.by Metal-Atom and Related Reactions.; from Arenes; Formation of (n6-Arene) Metal Complexes by Ligand Displacement; Formation of n5-Cyclohexdienyl Complexes by Nucleophilic Attack on (n6-Arene) Metal Complexes.; Formation of n5-Cyclohexadienide Complexes via Electrophilic Addition to Metal Arene Complexes.; n1 p-Aryl-Metal Complexes by Orthometallation Reactions.; n1 s-Aryl-Metal Complexes by oxidative Addition of Arenes.; n1 s-Aryl-Metal Complexes by Electrophilic Attack on Arenes.; by Metal-Atom and Related Reactions.
• Sommario/riassunto: For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson).Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximize