1.

Record Nr.

UNINA9910830866403321

Autore

Schubert U (Ulrich)

Titolo

Modern terpyridine chemistry [[electronic resource] /] / Ulrich S. Schubert, Harald Hofmeier, George R. Newkome

Pubbl/distr/stampa

Weinheim, : Wiley-VCH, c2006

ISBN

1-280-72357-2

9786610723577

3-527-60848-6

3-527-60842-7

Descrizione fisica

1 online resource (239 p.)

Altri autori (Persone)

HofmeierHarald

NewkomeGeorge R (George Richard)

Disciplina

151.79

658.51

Soggetti

Pyridine

Chemistry

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Modern Terpyridine Chemistry; Preface; Contents; 1 Introduction; References; 2 Syntheses of Functionalized 2,2 ́:6 ́,2 ́ ́-Terpyridines; 2.1 Introduction; 2.2 Basic Synthetic Strategies; 2.2.1 Ring Assembly; 2.2.2 Cross-Coupling Procedures; 2.3 Synthesis of 2,2 ́:6 ́,2 ́ ́-Terpyridine Derivatives; 2.3.1 4 ́-Substituted-2,2 ́:6 ́,2 ́ ́-Terpyridinoxy Derivatives; 2.3.2 4 ́-Aryl-Substituted 2,2 ́:6 ́,2 ́ ́-Terpyridines; 2.3.3 Other 4 ́-Functionalized 2,2 ́:6 ́ ́2 ́-Terpyridines; 2.3.4 Unsymmetrically Terminally Substituted 2,2 ́:6 ́,2 ́ ́-Terpyridines; 2.3.5 Symmetrically Terminally Substituted 2,2 ́:6 ́,2 ́ ́-Terpyridines

2.3.6 Uniform All-Ring Substituted 2,2 ́:6 ́,2 ́ ́-Terpyridines2.3.7 Multifunctional 2,2 ́:6 ́,2 ́ ́-Terpyridines with Variable Substituents; 2.4 Summary and Outlook; References; 3 Chemistry and Properties of Terpyridine Metal Complexes; 3.1 Introduction; 3.2 Synthetic Strategies; 3.2.1 Metal Complexes; 3.2.1.1 Ruthenium Complexes; 3.2.1.2 Other Luminescent Metal Complexes; 3.3 Mononuclear Bisterpyridine Ruthenium Complexes; 3.4 Chiral Complexes; References; 4 Metallo-Supramolecular Terpyridine Architectures; 4.1



Introduction; 4.2 Dyads and Triads; 4.2.1 Switchable Dyads and Triads

4.3 Supramolecular Assemblies4.3.1 Grids and Racks; 4.3.2 Helicates; 4.3.3 Rotaxanes and Catenanes; 4.3.4 Other Assemblies; 4.4 Cycles; 4.5 Fullerene Terpyridine Complexes; 4.6 Complexes Containing Biochemical Groups; References; 5 New Functional Polymers Incorporating Terpyridine Metal Complexes; 5.1 Introduction; 5.2 Polymers with Terpyridine Units in the Side Chain; 5.2.1 Polymers with Terpyridine Units in the Polymer Backbone; 5.2.2 Polymers from Rigid Organic Building Blocks; 5.2.3 Polymers from Flexible Organic Building Blocks; 5.2.4 Polymers from Polymeric Building Blocks

5.2.5 Other Systems5.3 Biopolymers and Terpyridine Metal Complexes; References; 6 Functional 3-D Architectures Based on Terpyridine Complexes; 6.1 Introduction; 6.2 Dendrimers Containing Terpyridine Metal Complexes in the Dendrimer Core; 6.3 Dendrimers Containing Bisterpyridine Complexes as Non-Core Connectors; 6.4 Dendrimers Containing Bisterpyridine Complexes at the Surface; 6.5 Micelles Composed of Terpyridine-Complex-Containing Polymers; 6.6 Resins and Beads Modified with Terpyridine; References; 7 Surfaces Modified with Terpyridine Metal Complexes; 7.1 Introduction

7.2 Assemblies and Layers7.3 Surface Catalysts; 7.4 Photoactive Materials; References; Subject Index

Sommario/riassunto

The first book to didactically illustrate this particular, prominent class of supramolecular building-blocks covers topics ranging from terpyridine syntheses, via their chemistry and properties, supramolecular structures, and multinuclear metal complexes, right up to functionalized polymers, 3D-architectures, and surfaces.Invaluable for students and lecturers in chemistry and biochemistry, materials scientists, as well as polymer, complex and physicochemists.