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Record Nr. |
UNINA9910830515703321 |
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Titolo |
Reactivity in molecular crystals / / edited by Yuji Ohashi |
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Pubbl/distr/stampa |
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Tokyo, Japan ; ; Weinheim, [Germany] : , : Kodansha : , : VCH, , 1993 |
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©1993 |
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ISBN |
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1-281-84295-8 |
9786611842956 |
3-527-61613-6 |
3-527-61612-8 |
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Descrizione fisica |
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1 online resource (362 p.) |
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Disciplina |
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Soggetti |
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Molecular crystals |
Chemical reactions |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references at the end of each chapters and index. |
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Nota di contenuto |
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Reactivity in Molecular Crystals; List of Contributors; Contents; Preface; 1. THEORETICAL APPROACH; 1.1 Potential Energy Calculations of Crystals; 1.2 A Novel Molecular-Dynamics Method to Predict Molecular Crystal Structures; 2. PHYSICO-CHEMICAL APPROACH; 2.1 Development of a New X-Ray Diffractometer (IPD-WAS) for Rapid Measurement; 2.2 Reaction Process in Solid State Studied by High Resolution Electron Spectromicroscopy; 2.3 Analysis of Charge Transfer Complex Formation in the Solid State by Penning lonilation Electron Spectroscopy |
2.4 Analysis of Reactive Species by Time Resolved Infrared Reflection Absorption Spectroscopy2.5 Molecular Motion in Clathrate Crystals Analyred by Solid-state NMR Method; 2.6 Asymmetric Structure Analysis for Reaction Centers of a Molecular Crystal and on a Crystal Surface by EXAFS Spectroscopy; 2.7 Excitation Energy Transfer Between Metal Complexes in Solids; 3. CRYSTALLINE-STATE REACTION; 3.1 Dynamic Structure Analysis of Crystalline-State Reaction; 3.2 Reversible Intercalation of Guest Molecules in Crystals of Cholic Acid |
3.3 How can Crystalline Environment Provide Outstanding Chemistry for |
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Diarylcarbenes or Arylnitrenes4. Solid-to- Solid Organic Reactions; 4.1 Introduction; 4.2 Pinacol and Benzylic Acid Rearrangement; 4.3 Baeyer-Villiger Oxidation; 4.4 Reduction with NaBH4; 4.5 Grignard, Reformatsky and Luche Reactions; 4.6 Coupling Reactions; 4.7 Witting-Horner Reaction; 4.8 Aldol Condensation; 4.9 Dehydration, Rearrangement, Chlorination and Etherification of Secondary Alcohols; 4.10 Host-Guest Inclusion Complexation in the Solid State; 5. Streoselective Solid-State Photoreaction |
5.1 Determining Factors of Molecular Arrangement and Reaction Course in the Crystalline-State Photoreaction of Unsymmetrically Substituted Diolefins5.2 Stereoselectivity in Reactions of Clathrate Crystals; 5.3 Solid-state Photochromism of Tetraphenyldihydro-1,3,5-Triazine and Related Heterocycles; 5.4 Solid-state Photoracemization and Photoisomerization of Alkyl Cobalt Complexes; 6. REACTIVITY AND CRYSTAL STRUCTURE; 6.1 Packing Effect in Solid-State Polymerization of Diethynylbenzene Derivatives by Radiation |
6.2 High Selective Reaction Deduced by Tunneling Effect in the Crystalline Environment6.3 Formation of Bimolecular Films and Crystal Structure; 6.4 Reactivity and Reaction Pathway of the Sulfur Compounds; 6.5 Stereoselectivity and Molecular Recognition in Double Macrocyclic Inclusion Crystals; Index |
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Sommario/riassunto |
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Do you need to design syntheses that are* highly selective* fast* enantioselective with quantitative enantiomeric yield? This book describes in detail how best to exploit the enormous synthetic potential of solid state reactions. Written by leading experts, it provides in-depth information on* the theoretical and physico-chemical approach to solid state reactions* solid-to-solid organic reactions* stereoselective solid state photoreactions* reactivity and crystal structureAn ideal companion to Dunitz and Bürgi's 'Structure Correlation', this |
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