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Record Nr. |
UNINA9910830494103321 |
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Titolo |
Oligomerization and polymerization [[electronic resource] ] : formation of intercalation compounds / / founding editor, J.J. Zuckerman; editor, A.P. Hagen |
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Pubbl/distr/stampa |
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New York, : Wiley-VCH, c1990 |
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ISBN |
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1-282-30809-2 |
9786612308093 |
0-470-14532-3 |
0-470-14553-6 |
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Descrizione fisica |
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1 online resource (462 p.) |
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Collana |
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Inorganic reactions and methods ; ; v. 17 |
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Altri autori (Persone) |
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Disciplina |
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Soggetti |
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Polymerization |
Clathrate compounds |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and indexes. |
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Nota di contenuto |
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Inorganic Reactions and Methods; Contents; Ring-ring and Ring-chain interconversions.; in Cage Polyboranes and Carboranes.; The Formation of Sheet Structures; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 17; Oligomerization and Polymerization; Introduction; Definitions and Scope.; Definitions of Oligomers and Polymers.; General Synthesis Methods.; Scope.; Small-Ring Systems-Examples of Synthesis.; Cages-ExampIes of Synthesis.; Short Chains-Examples of Synthesis.; Long Chains- Long Chains-Examples of |
Characteristic Differences Between Small and Large Molecules as Related to Their Synthesis.Special Characteristics of Small Cyclic and Linear Molecules.; Special Characteristics of Long-Chain MolecuIes.; Chain-Chain , Chain-Ringand Ring-Ring Equilibria; Bond Lability in Inorganic Systems.; Some Important Relationships Based on Theory.; The Chain Population.; The Ring Population and Network Macromolecules.; Introduction; Scrambling in Inorganic Systems.; All-Neso Systems.; Oligomers and Polymers in QZ,-QT, Systems with Z |
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Bridging.; Exchange of Segments Between CycIic MoIecules. |
Chains and Rings from Scrambling Between Two Kinds of Central Moieties.Ring-Ring and Ring-Polymer Ring-Ring and Ring-Polymer Interconversions; Introduction; lnterconversion of Sulfur or Selenium Rings and Chains; Theory; Experimental Techniques; Viscosity Measurements.; Ultrasonic Absorption in Liquid Selenium.; Quenching Experiments.; Diamagnetic SusceptibiIity Measurements.; Paramagnetic SusceptibiIity Measurements.; Electron Spin Resonance Absorption (ESR); Optical Absorption.; Vibrational Spectroscopy of Sulfur.; Nuclear Magnetic Resonance (NMR) Measurements on Selenium. |
Dielectric Constant Measurements of SuIfur.Specific Heat Measurements on Sulfur and Selenium.; Density Measurements.; Thermal Conductivity in Liquid Selenium.; Electrical Conductivity of Sulfur.; In Oligomeric Catenates of P, As, Sb and Bi.; General Trends.; Phosphorus.; Arsenic.; Antimony.; Stabilized Rings and Chains.; In Silicon-Silicon Systems.; Formation of Cyclic Silicon-Silicon Systems.; Perarylcyclosilanes.; Permethylcyclosilanes.; Other Peralkylcyclosilanes.; AIkyIarylcyclosiIanes .; Reactions of Cyclosilanes.; Substitutional Reactions.; Ring-Cleavage Reactions.; Photolysis. |
Ring-Ring and Chain-Ring Interconversion.Cage Polysilanes.; Silane High Polymers.; in Boron-Nitrogen Systems.; Synthesis of Ring Compounds; Borazines and Related Compounds.; Coordinately Saturated B-N Rings.; Factors Affecting Stability of Ring Species.; Preparation of Linear Boron-Nitrogon 0ligomers.; lnterconversions in Boron-Nitrogen System; Preparation of Boron-Nitrogen Polymers.; Linear Boron-Nitrogen Chains.; Polycyclic Chains.; in Boron-Oxygen and Boron-Sulfur Systems; Anionic Boron-Oxygen Compounds.; Molecular Boron-Oxygen Species.; Boron-SuIfur Compounds. |
Ring-Ring and Ring-Polymer interconversions. |
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Sommario/riassunto |
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For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson).Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximize |
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