Metal organic frameworks for wastewater contaminant removal / / edited by Arun Lal Srivastav [and three others]

• Record Nr.: UNINA9910830301803321
• Pubbl/distr/stampa: Weinheim, Germany : , : WILEY-VCH GmbH, , [2023]; ©2023
• ISBN: 3-527-84152-0; 3-527-84153-9
• Edizione: [1st ed.]
• Descrizione fisica: 1 online resource (464 pages)
• Disciplina: 547.05
• Soggetti: Metal-organic frameworks; Sewage - Purification - Metals removal; Sewage - Purification - Organic compounds removal
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Includes index.
• Nota di contenuto: Intro -- Title Page -- Copyright Page -- Preface -- 1 Application of MOFs on Removal of Emerging Water Contaminants -- Abbreviated list -- 1.1 Introduction -- 1.1.1 Sources of Emerging Water Contaminants -- 1.1.2 Emerging Water Contaminants Treatment Methods -- 1.1.3 MOFs as Exceptional Materials for Water Remediation -- 1.2 MOFs Strategies in Water Remediation -- 1.2.1 Adsorption -- 1.2.2 Catalyst -- 1.2.3 Synergistic Effect of Adsorption and Photocatalyst -- 1.3 Emerging Water Contaminants by MOFs -- 1.3.1 Organic Dyes -- 1.3.2 Adsorption -- 1.3.3 Photocatalytic and Electrostatic Activities -- 1.3.4 PPCPs -- 1.3.5 Adsorption -- 1.3.6 Photocatalytic Activities -- 1.3.7 Herbicides and Pesticides -- 1.3.8 Adsorption -- 1.3.9 Photocatalytic Activities -- 1.3.10 Industrial Compounds/By-products -- 1.3.11 Adsorption -- 1.3.12 Photocatalytic Activities -- 1.4 Challenges and Perspective in Using MOFs for the Removal of Emerging Water Contaminants -- 1.5 Conclusion -- 2 Metal-Organic Frameworks and Their Stepwise Preparatory Methods (Synthesis) for Water Treatment -- 2.1 Introduction -- 2.2 Classification of Metal-Organic Frameworks -- 2.3 Synthesis of MOFs -- 2.3.1 Conventional Solvothermal/Hydrothermal and Non-Solvothermal Method -- 2.3.2 ; Room-Temperature Synthesis -- 2.3.3 Unconventional Methods -- 2.4 Alternative Synthesis Methods -- 2.4.1 Microwave-Assisted Synthesis -- 2.4.2 Electrochemical Synthesis -- 2.4.3 Sonochemical Synthesis -- 2.4.4 Surfactant-Assisted Synthesis -- 2.4.5 Layer-by-Layer Synthesis -- 2.5 Factors Affecting the Synthesis of MOFs -- 2.5.1 Solvents -- 2.6 Temperature and pH Effects on the Synthesis of MOFs -- 2.7 Water Regeneration and Wastewater Treatment Using MOF Membranes -- 2.8 Membrane Filtration -- 2.9 Microfiltration (MF) -- 2.10 Ultrafiltration (UF) -- 2.11 Nanofiltration (NF).; 2.12 Reverse Osmosis (RO) and Forward Osmosis (FO) -- 2.13 Membrane Distillation (MD) -- 2.14 Membrane Pervaporation (PV) -- 2.15 Conclusion -- 3 Application of MOFs in the Removal of Pharmaceutical Waste from Aquatic Environments -- 3.1 Introduction -- 3.2 The Potential of MOFs and Their Analogs to Resist Water Stability -- 3.3 Methods for the Development and Design of Aqueous-Stable Composites of Metal-Organic Frameworks -- 3.4 Synthesis and Design of Water-Stable MOF-Derived Materials -- 3.5 MOFs and Their Hybrids as Versatile Adsorbents for Capturing Pharmaceutical Drugs -- 3.6 MILs and Their Derived Compounds -- 3.7 Pristine MILs -- 3.8 MILs Composites -- 3.9 MILs-Derived Materials -- 3.10 ZIFs and Their Derived Compounds -- 3.11 Pristine ZIFs -- 3.12 ZIFs Composites -- 3.13 Materials Derived from ZIFs -- 3.14 UiOs Composite Materials -- 3.15 UiOs-Derived Materials -- 3.16 Pharmaceutical Drug Resistance -- 3.17 Conclusion -- 4 Efficiency of MOFs in Water Treatment Against the Emerging Water Contaminants Such as Endocrine Disruptors, Pharmaceuticals, Microplastics, Pesticides, and Other Contaminants -- 4.1 Introduction -- 4.2 Chemical Contaminants: Those Mysterious Ingredients in Ground and Surface Water -- 4.2.1 Endocrine Disruptors (EDs) -- 4.2.2 Microplastics (MPs) -- 4.2.3 Contaminants from the Agriculture Sector -- 4.2.4 Pharmaceutical Effluents -- 4.3 MOFs -- 4.3.1 MOF Stability in the Aqueous Phase -- 4.3.2 Improving the Water Stability of MOFs: General Enhancement Strategies -- 4.4 Possibilities for Wastewater Treatment Applications Using MOFs -- 4.4.1 MOF-Supported Adsorption &amp -- Photocatalysis -- 4.4.2 π-π Interactions -- 4.4.3 Electrostatic Interactions -- 4.4.4 Hydrophobic Interactions -- 4.4.5 H-Bonding -- 4.5 Use of MOFs for Water Remediation: Issues &amp -- Perspectives -- 4.6 Future -- 4.7 Conclusions.; 5 Metal-Organic Frameworks for Wastewater Contaminants Removal -- 5.1 Introduction -- 5.2 Aqueous Phase MOF Stability -- 5.3 MOF Degradation in Water -- 5.4 Influence of MOF Structure -- 5.5 2D Nanostructured Coating -- 5.6 3D Nanostructure of MOF -- 5.7 MOF-Based Materials' Adsorption Processes for Heavy Metal Oxyanion -- 5.8 Remediation Through Perfect MOFs -- 5.9 Interaction of MOFs with Other Species -- 5.10 With the Use of MOF Composites -- 5.11 Removal of Metal Ions through Adsorption -- 5.12 MOF Composites are Used for Removal -- 5.13 COFs are a New Class of Materials that Have Similar MOF Structures -- 5.14 Application of MOF Composites -- 5.15 Gas Separation and Adsorption -- 5.16 MOF Composites -- 5.17 Agrochemical Adsorption and Removal -- 5.18 Pharmaceutical and Personal Care Adsorption Removal Products (PPCPs) -- 5.19 MOFs for Photocatalytic Elimination of Organic Pollutants -- 5.20 Conclusion -- Acknowledgment -- Author Contributions -- Conflicts of Interest -- 6 "Green Applications of Metal-Organic Frameworks for Wastewater Treatment" -- 6.1 Introduction -- 6.2 Role of Green Chemistry in Preparation of MOFs -- 6.3 Green Application of MOFs in the Removal of Contaminants from Wastewater -- 6.3.1 MOFs for the Removal of Inorganic Contaminants -- 6.3.2 MOFs for the Removal of Organic ; Contaminants -- 6.4 Conclusion and Future Prospects -- 6.5 Conflict of Interest -- 7 Case Studies (Success Stories) on the Application of Metal-Organic Frameworks (MOFs) in Wastewater Treatment and Their Implementations -- Review -- 7.1 Introduction -- Sewage Treatment Policies and State Implementation Strategies -- 7.2 Metal-Organic Framework (MOF) -- 7.2.1 Properties and Applications of MOFs -- 7.3 Applications of MOFs in Wastewater Treatment: Case Studies -- 7.3.1 Forward Osmosis (FO) Membranes -- 7.3.2 Application and Effectiveness.; 7.3.3 Reverse Osmosis (RO) Membranes -- 7.3.4 Application and Effectiveness -- 7.3.5 Nano Filter (NF) Membranes -- 7.3.6 Application and Effectiveness -- 7.3.7 Ultrafiltration (UF) Membranes -- 7.3.8 Application and Effectiveness -- Summary -- Acknowledgment -- 8 Prospects and Potentials of Microbial Applications on Heavy-Metal Removal from Wastewater -- 8.1 Introduction -- 8.2 Mainstream Avenues to Remediate Heavy Metals in Wastewater -- 8.3 The Microbial Recycling Approach -- 8.4 General Overview of Heavy-Metal Pollution in Wastewater -- 8.5 Techniques for Heavy-Metal Removal -- 8.6 Microbial and Biological Approaches for Removing Heavy Metals from Wastewater -- 8.7 Biological Remediation Approaches for Heavy-Metal Removal -- 8.8 Microbial Bioremediation Approaches -- 8.9 Bioengineering Approaches on Microbes for Improving Heavy-Metal Removal from Wastewater -- 8.10 Conclusion -- Acknowledgment -- 9 Removal of Organic Contaminants from Aquatic Environments Using Metal-Organic Framework (MOF) Based Materials -- 9.1 Introduction -- 9.2 MOF-Based Materials -- 9.2.1 MOF-Metal Nanoparticle Materials -- 9.2.2 MOF-MO Materials -- 9.2.3 MOF-Quantum Dot Materials -- 9.2.4 MOF-Silica Materials -- 9.2.5 MOF-Carbon Materials -- 9.2.6 Core-shell Structures of MOFs -- 9.2.7 MOF-Enzyme Materials -- 9.2.8 MOF-Organic Polymer Materials -- 9.3 Environmental Effects of MOF-Based Materials -- 9.4 Conclusion -- 10 Reformed Metal-Organic Frameworks (MOFs) for Abstraction of Water Contaminants - Heavy-Metal Ions -- 10.1 Introduction -- 10.2 Metal-Organic Frameworks -- 10.3 Sorption Enrichment by Modification of MOFs -- 10.4 Toxic-Metal Ion Adsorption by MOFs -- 10.4.1 MOFs for Mercury Adsorption -- 10.4.2 MOFs for Lead Adsorption -- 10.4.3 MOFs for Cadmium Adsorption -- 10.4.4 MOFs for Chromium Removal -- 10.4.5 MOFs for Arsenic Removal.; 10.4.6 MOFs for Heavy Metals Phosphate Removal -- 10.4.7 MOFs for Nickel Adsorption -- 10.4.8 MOFs for Selenium Adsorption -- 10.4.9 MOFs for Uranium Adsorption -- 10.5 Future Perspective -- 10.6 Future Scope -- 10.7 Conclusions -- 11 Application of Algal-Polysaccharide Metal-Organic Frameworks in Wastewater Treatment -- 11.1 Introduction -- 11.1.1 Water Pollutants and Sources -- 11.1.2 Common Wastewater Treatment Techniques -- 11.1.3 Metal-Organic Frameworks for Wastewater Treatment -- 11.1.4 Polysaccharide-Metal-organic Frameworks (Ps-MOFs) -- 11.2 Polysaccharides in Algae/cyanobacteria (AlPs) -- 11.2.1 Polysaccharides in Cyanophyceae -- 11.2.2 Polysaccharides in Chlorophyceae -- 11.2.3 Polysaccharides in Rhodophyceae -- 11.2.4 Polysaccharides in Phaeophyceae -- 11.3 Synthesis of Algal Polysaccharide MOFs (ALPs-MOFs) -- 11.3.1 Alginate-MOFs -- 11.3.2 Cellulose-MOFs -- 11.3.3 Agar-MOFs -- 11.4 Characterization of AlP-MOFs -- 11.5 Adsorption Mechanism of AlPs-MOFs -- 11.6 Regeneration of AlPs-MOFs -- 11.7 Conclusion and Future Prospects -- 12 Ecological Risk Assessment of Heavy Metal Pollution in Water Resources -- 12.1 Introduction -- 12.2 Natural and Anthropogenic Sources of Heavy Metals in the Environment -- 12.3 Impacts of Heavy Metal Pollution -- 12.4 Water Quality Assessment ; Using Pollution Indices -- 12.4.1 Heavy Metal Pollution Index (HPI) -- 12.4.2 Statistical Technique -- 12.5 MOFs for Heavy Metal Contaminant Removal from Water -- 12.6 Conclusion -- 13 Organic Contaminants in Aquatic Environments: Sources and Impact Assessment -- 13.1 Introduction -- 13.2 The Various Forms and Causes of Chemical Pollutants -- 13.3 Increasing Contaminant Occurrence in Aquatic Systems -- 13.4 Identifying Potential Points of Entry for New Pollutants into Aquatic Systems -- 13.5 Groups of Trace Pollutants and ECs -- 13.5.1 Polybrominated Diphenyl Ethers (PBDEs).; 13.6 Pharmaceuticals and Personal Care Products (PPCPs).