1.

Record Nr.

UNINA9910830297403321

Titolo

Reviews of reactive intermediate chemistry [[electronic resource] /] / edited by Matthew S. Platz, Robert A. Moss, Maitland Jones, Jr

Pubbl/distr/stampa

Hoboken, N.J., : Wiley-Interscience, c2007

ISBN

1-280-82710-6

9786610827107

0-470-12082-7

0-470-12081-9

Descrizione fisica

1 online resource (492 p.)

Altri autori (Persone)

PlatzMatthew

MossRobert A

JonesMaitland <1937->

Disciplina

547.2

547/.2

Soggetti

Intermediates (Chemistry)

Chemistry, Organic

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

; Pt. 1. Reactive intermediates. Tetrahedral intermediates derived from carbonyl compounds, pentacoordinate intermediates derived from phosphoryl and sulfonyl compounds, and concerted paths which avoid them / J. P. Guthrie ; Silicon-, germanium-, and tin-centered cations, radicals, and anions / V. Y. Lee ; and A. Sekiguchi. -- ; Pt. 2. Methods and applications. An introduction to time-resolved resonance Raman spectroscopy and its application to reactive intermediates / D. L. Phillips, W. M. Kwok, ; and C. Ma ; Time-resolved infrared (TRIR) studies of organic reactive intermediates / J. P. Toscano ; Studies of the thermochemical properties of reactive intermediates by mass spectrometric methods / P. G. Wenthold ; Reactive intermediates in combustion / J. K. Merle ; and C. M. Hadad ; Reactive intermediates in crystals: form and function / L. M. Campos ; and M. A. Garcia-Garibay ; The chemical reactions of DNA damage and degradation / K. S. Gates ; Conical intersection species as reactive intermediates / M. J. Bearpark ; and M. A. Robb ; Quantum mechanical tunneling in organic reactive



intermediates / R. S. Sheridan.

Sommario/riassunto

The chemistry of reactive intermediates is central to a modern mechanistic and quantitative understanding of organic chemistry. Moreover, it underlies a significant portion of modern synthetic chemistry and is integral to a molecular view of biological chemistry. Reviews in Reactive Intermediate Chemistry presents an up-to-date, authoritative guide to this fundamental topic. Although it follows Reactive Intermediate Chemistry by the same authors, it serves as a free-standing resource for the entire chemical and biochemical community. The book includes:Relevant, practical appli