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Record Nr. |
UNINA9910830203803321 |
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Autore |
Auner Norbert |
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Titolo |
Organosilicon Chemistry Set : From Molecules to Materials / / Norbert Auner, Johann Weis |
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Pubbl/distr/stampa |
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Weinheim, Germany : , : Wiley-VCH, , 2005 |
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©2005 |
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ISBN |
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Descrizione fisica |
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Disciplina |
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Soggetti |
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Organosilicon compounds |
Silicon compounds |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Sommario/riassunto |
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Aryl ligands carrying oxygen, phosphorus or sulfur donor atoms in the side chain are introduced at silicon. Here we report on the synthesis of silyl chlorides and silyl triflates. The interaction between the silicon centre and the donor atom are discussed on the basis of NMR and X-ray crystallographic data. In the reaction of bis[2-(methoxymethyl)phenyl]methylsilyl triflate 8 with nucleophiles, reactivity of oxonium as well as of siliconium ions is observed. |
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