1.

Record Nr.

UNINA9910830073403321

Titolo

Metallomesogens : synthesis, properties, and applications / / edited by José Luis Serrano

Pubbl/distr/stampa

Weinheim, [Germany] : , : VCH, , 1996

©1996

ISBN

1-281-84270-2

9786611842703

3-527-61509-1

3-527-61508-3

Descrizione fisica

1 online resource (520 p.)

Disciplina

669.95

Soggetti

Metallomesogens

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references at the end of each chapters and index.

Nota di contenuto

Metallomesogens; Biography; Preface; Contents; List of Contributors; 1 Introduction; 1.1 General Concepts: Metallomesogens; 1.2 General Concepts: Liquid Crystals; 1.3 Mesophases; 1.3.1 Calamitic Mesophases; 1.3.2 Discotic Mesophases [30]; 1.3.3 Lyotropic Mesophases; References; Part A Materials; 2 Low Molecular Weight Lyotropic Metallomesogens; 2.1 Micellar Lyotropic Metallomesogens; 2.2 Chromonic Metallomesogens; 2.3 Summary; References; 3 Low Molecular Weight Calamitic Metallomesogens; 3.1 Metal-Organic Liquid Crystals; 3.1.1 Metal-Organic Liquid Crystals with Monodentate Ligands

3.1.1.1 Nitrile Ligands3.1.1.2 Pyridine Ligands; 3.1.1.3  Amine Ligands; 3.1.1.4 Thiolate Ligands; 3.1.1.5 Summary; 3.1.2 Metal-Organic Liquid Crystals with Bidentate Ligands; 31.2.1  2-Substituted Pyrrole Derivatives; 3.1.2.2 Salicylideneamine Derivatives; 3.1.2.3 Enaminoketone Derivatives; 3.1.2.4 Aroylhydrazine Derivatives; 3.1.2.5 β-P-Diketone Derivatives; 3.1.2.6 Salicylaldehyde Derivatives; 3.1.2.7 Alkylcarboxylate Derivatives; 3.1.2.8 Monothio-β-Diketone Derivatives; 3.1.2.9 Dithiolene Derivatives; 3.1.2.10 Dithiobenzoate Derivatives; 3.1.2.11 Dithiocarbamate Derivatives



3.1.2.12 Summary3.1.3 Metal-Organic Liquid Crystals with Tetradentate Ligands; 3.1.3.1 Annelide Derivatives; 3.1.3.2 Porphyrin Derivatives; 3.1.3.3 Salicylidenediamine Derivatives; 3.1.3.4   2,2 '-Bipyridine Derivatives; 3.1.3.5 1,10-Diaza-4,7,13,16-Tetrathiacyclooctadecane Derivatives; 3.1.3.6 Summary; 3.2 Organometallic Liquid Crystals; 3.2.1 Organometallic Liquid Crystals with Monodentate Ligands; 3.2.1.1 Alkynyl Derivatives; 3.2.1.2 Isonitrile Derivatives; 3.2.1.3 Summary; 3.2.2 Organometallic Liquid Crystals with Bidentate Ligands; 3.2.2.1 Dinuclear ortho-Palladated Complexes

3.2.2.2 Mononuclear ortho-Metallated Complexes3.2.2.3 Summary; 3.2.3 Organometallic Liquid Crystals with Meta-π Bonds; 3.2.3.1 Metallocene Derivatives; 3.2.3.2 Butadiene Complexes; 3.2.3.3 Summary; References; 4 Low Molecular Weight Discotic Metallomesogens; 4.1 Mononuclear Metal Complexes with Bidentate Ligands; 4.1.1 β-Diketonate Complexes; 4.1.1.1 Complexes with one Aliphatic Ring at each Phenyl Ring; 4.1.1.2 Complexes with two or more Aliphatic Chains at each Phenyl Ring; 4.1.2 Dithiolene Complexes; 4.1.3    1. 2.Dioxime Complexes; 4.2 Dinuclear Metal Complexes with Bidentate Ligands

4.2.1 Carboxylate Complexes4.2.2 Dithiocarboxylate Complexes; 4.2.3 Benzalimine Complexes; 4.3 Metal Complexes with Tridentate Ligands; 4.3.1 1.4. 7-Triazacyclononane Complexes; 4.3.2 Pyridinediyl-2, 6.dimethanol Complexes; 4.3.3 1.3. 5-Triketonate Complexes; 4.4 Mononuclear Metal Complexes with Tetradentate Ligands; 4.4.1 Phthalocyanine Complexes; 4.4.2 Porphyrin Complexes; 4.4.3 Tetraazaporphyrin Complexes; 4.4.4 Tetrapyrazinoporphyrazine Complexes; 4.4.5   1.4.8. 11-Tetraazacyclotetradecane Complexes; 4.4.6 Bis(salicylidene)diimine Complexes; 4.4.7 P-Diketonate Schiff Base Complexes

4.4.8 Calixarene Complexes

Sommario/riassunto

Research on metal-containing liquid crystals is a rapidly expanding, multidisciplinary field with new materials continually being synthesized and novel applications being developed. 'Metallomesogens' is the first comprehensive survey of the field, introducing the reader to:* materials design* synthesis* physical properties* emerging applicationsCarefully selected references round off this well-organized compendium. It is an indispensable guide to experienced researchers in coordination and organometallic chemistry as well as in liquid-crystal and materials science.