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Record Nr. |
UNINA9910830045603321 |
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Titolo |
Carbon materials for catalysis [[electronic resource] /] / edited by Philippe Serp, José Luís Figueiredo |
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Pubbl/distr/stampa |
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Hoboken, N.J., : John Wiley & Sons, c2009 |
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ISBN |
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1-282-00187-6 |
9786612001871 |
0-470-40370-5 |
0-470-40369-1 |
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Descrizione fisica |
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1 online resource (603 p.) |
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Classificazione |
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Altri autori (Persone) |
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FigueiredoJosé Luís |
SerpPhilippe |
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Disciplina |
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Soggetti |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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CARBON MATERIALS FOR CATALYSIS; Contents; Contributors; Preface; 1 Physicochemical Properties of Carbon Materials: A Brief Overview; 1.1. Introduction; 1.2. Formation of Carbons; 1.2.1. Gas Phase; 1.2.2. Liquid Phase; 1.2.3. Solid Phase; 1.3. Structure and Properties of Carbons; 1.3.1. Macrostructure; 1.3.2. Microstructure; 1.3.3. Nanostructure; 1.3.4. Bulk Properties; 1.3.5. Surface Properties; 1.4. Reactions of Carbons; 1.4.1. Gas Phase; 1.4.2. Liquid Phase; 1.4.3. Solid Phase; 1.5. Conclusions; References; 2 Surface Chemistry of Carbon Materials; 2.1. Introduction |
2.2. Surface Functionalities2.2.1. Oxygen-Containing Functionalities; 2.2.2. Nitrogen-Containing Functionalities; 2.2.3. Hydrogen-Carbon Species; 2.2.4. Sulfur, Phosphorus, and Halogen Functionalities; 2.3. Surface Modifications; 2.3.1. Oxidation; 2.3.2. Introduction of Nitrogen-Containing Species; 2.3.3. Introduction of Sulfur Functionality; 2.3.4. Halogenization; 2.3.5. Impregnation and Dry Mixing; 2.3.6. Heat Treatment; 2.4. Characterization of Surface |
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Chemistry; 2.4.1. Elemental Analysis; 2.4.2. Titration; 2.4.3. pH of Carbons, Point of Zero Charge, and Isoelectric Point |
2.4.4. Spectroscopic Methods2.4.5. Calorimetric Techniques; 2.4.6. Inverse Gas Chromatography; 2.4.7. Temperature-Programmed Desorption; 2.4.8. Characterization of Surface Functionalities by Electrochemical Techniques; 2.5. Role of Surface Chemistry in the Reactive Adsorption on Activated Carbons; 2.6. Role of Carbon Surface Chemistry in Catalysis; References; 3 Molecular Simulations Applied to Adsorption on and Reaction with Carbon; 3.1. Introduction; 3.2. Molecular Simulation Methods Applied to Carbon Reactions; 3.2.1. Electronic Structure Methods (or Quantum Mechanics Methods) |
3.2.2. Molecular Dynamics Simulations3.2.3. Monte Carlo Simulations; 3.3. Hydrogen Adsorption on and Reaction with Carbon; 3.3.1. Atomic Hydrogen Adsorption on the Basal Plane of Graphite; 3.3.2. Reactivities of Graphite Edge Sites and Hydrogen Reactions on These Sites; 3.3.3. Hydrogen Storage in Carbon Nanotubes; 3.4. Carbon Reactions with Oxygen-Containing Gases; 3.4.1. Carbon Reactions with Oxygen-Containing Gases and the Unified Mechanism; 3.4.2. Catalyzed Gas-Carbon Reactions; 3.4.3. More Specific Studies on NO(x), H(2), CO(2), and O(2)-Carbon Reactions; 3.5. Metal-Carbon Interactions |
3.6. ConclusionsReferences; 4 Carbon as Catalyst Support; 4.1. Introduction; 4.2. Properties Affecting Carbon's Role as Catalyst Support; 4.2.1. Surface Area and Porosity; 4.2.2. Surface Chemical Properties; 4.2.3. Inertness; 4.3. Preparation of Carbon-Supported Catalysts; 4.3.1. Impregnation; 4.3.2. Other Methods; 4.4. Applications; 4.4.1. Ammonia Synthesis; 4.4.2. Hydrotreating Reactions; 4.4.3. Hydrogenation Reactions; 4.5. Summary; References; 5 Preparation of Carbon-Supported Metal Catalysts; 5.1. Introduction; 5.2. Impregnation and Adsorption |
5.2.1. Interaction Between Support and Precursor |
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Sommario/riassunto |
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This is the first comprehensive book covering all aspects of the use of carbonaceous materials in heterogeneous catalysis. It covers the preparation and characterization of carbon supports and carbon-supported catalysts; carbon surface chemistry in catalysis; the description of catalytic, photo-catalytic, or electro-catalytic reactions, including the development of new carbon materials such as carbon xerogels, aerogels, or carbon nanotubes; and new carbon-based materials in catalytic or adsorption processes. This is a premier reference for carbon, inorganic, and physical chemists, materials sc |
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