Calibration in analytical science : methods and procedures / / Paweł Kościelniak

• Record Nr.: UNINA9910830002703321
• Autore: Kościelniak Paweł
• Pubbl/distr/stampa: Weinheim, Germany : , : Wiley-VCH, , [2023]; ©2023
• ISBN: 3-527-83111-8; 3-527-83110-X
• Descrizione fisica: 1 online resource (387 pages)
• Disciplina: 543
• Soggetti: Analytical chemistry; Calibration
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Calibration Fundamentals -- 1.1 Analytical Context -- 1.2 Principles of Analytical Calibration -- 1.3 Calibration Standards and Models -- 1.4 Calibration Procedures and Methods -- 1.5 Calibration in the Context of Measurement Errors -- 1.5.1 Uncontrolled Analytical Effects -- 1.5.2 Elimination and Compensation of Uncontrolled Effects -- 1.6 Calibration in Qualitative Analysis -- 1.7 Calibration in Quantitative Analysis -- 1.8 General Rules for Correct Calibration -- References -- Chapter 2 "Calibration‐Free" Analysis -- 2.1 Novel Approach -- 2.2 Empirical Calibration -- 2.3 Theoretical Calibration -- 2.3.1 Fixed Models -- 2.3.2 Flexible Models -- References -- Chapter 3 Calibration Methods in Qualitative Analysis -- 3.1 Classification -- 3.2 External Calibration Methods -- 3.2.1 External Standard Method -- 3.2.2 Reference Sample Method -- 3.3 Internal Calibration Methods -- 3.3.1 Internal Standard Method -- 3.3.2 Indirect Method -- 3.4 Standard Addition Method -- References -- Chapter 4 Introduction to Empirical Calibration in Quantitative Analysis -- 4.1 Classification -- 4.2 Formulation of Model Functions -- 4.3 Examination of Interference Effect -- 4.4 Mathematical Modeling of Real Function -- References -- Chapter 5 Comparative Calibration Methods -- 5.1 External Calibration Methods -- 5.1.1 External Standard Method -- 5.1.1.1 Modified ; Procedures -- 5.1.2 Dilution Method -- 5.2 Internal Calibration Methods -- 5.2.1 Internal Standard Method -- 5.2.2 Indirect Method -- References -- Chapter 6 Additive Calibration Methods -- 6.1 Basic Aspects -- 6.2 Standard Addition Method -- 6.2.1 Extrapolative Variant -- 6.2.1.1 Modified Procedures -- 6.2.2 Interpolative Variants -- 6.2.3 Indicative Variant -- 6.3 Titration -- 6.4 Isotope Dilution Method -- 6.4.1 Radiometric Isotope Dilution.; 6.4.2 Isotope Dilution Mass Spectrometry -- 6.4.2.1 Modified Procedures -- References -- Chapter 7 Calibration in Nonequilibrium Conditions -- 7.1 Flow Injection Analysis -- 7.1.1 Manipulation Techniques -- 7.1.2 Gradient Technique -- 7.2 Kinetic Analysis -- References -- Chapter 8 Complex Calibration Approaches -- 8.1 Extrapolative Methods -- 8.1.1 Extrapolative Indirect Method -- 8.1.2 Extrapolative Internal Standard Method -- 8.1.3 Extrapolative Dilution Method -- 8.2 Mixed Methods -- 8.3 Combined Methods -- 8.3.1 Integrated Calibration Methods -- 8.3.1.1 Simple Integrated Method -- 8.3.1.2 Complementary Dilution Method -- 8.3.2 Generalized Calibration Strategy -- 8.3.2.1 Versatile Flow Injection Calibration Module -- 8.3.3 Standard Dilution Analysis -- References -- Chapter 9 Calibration Approaches for Detection and Examination of Interference Effects -- 9.1 Introduction -- 9.2 Simple Procedures for Detection and Examination of Interference Effects -- 9.3 Detection and Compensation of Additive Interference Effect -- 9.3.1 Interpolative Procedure -- 9.3.2 Extrapolative Procedure -- 9.3.3 Integrated Procedure -- References -- Chapter 10 Calibration‐Based Procedures for Correction of Preparative Effects -- 10.1 Introduction -- 10.2 Specific Procedures -- 10.3 Surrogate Recovery Method -- 10.3.1 Reliability of the Method -- 10.3.2 Interpretations of the Method -- 10.3.3 Recovery vs. Interference Effect -- 10.3.4 Recovery vs. Speciation Effect -- References -- Chapter 11 Calibration‐Related Applications of Experimental Plans -- 11.1 Introduction -- 11.2 Examination of Interference Effects -- 11.3 Modeling of Real Functions -- 11.4 Multicomponent Analysis -- References -- Chapter 12 Final Remarks -- References -- Index -- EULA.