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1. |
Record Nr. |
UNINA9910829994003321 |
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Titolo |
Design and synthesis of conjugated polymers [[electronic resource] /] / edited by Mario Leclerc, Jean-Francois Morin |
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Pubbl/distr/stampa |
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Weinheim, : Wiley-VCH, c2010 |
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ISBN |
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1-282-78382-3 |
9786612783821 |
3-527-62978-5 |
3-527-62979-3 |
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Descrizione fisica |
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1 online resource (381 p.) |
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Altri autori (Persone) |
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LeclercMario <1961-> |
MorinJean-Franc ʹois <1978-> |
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Disciplina |
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Soggetti |
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Polymers - Electric properties |
Polymers |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Design and Synthesis of Conjugated Polymers; Contents; Preface; List of Contributors; 1 Synthesis and Functionality of Substituted Polyacetylenes; 1.1 Introduction; 1.2 Polymer Syntheses; 1.2.1 Catalysts; 1.2.2 Polymerization Behaviors; 1.2.3 Polymer Reactions; 1.3 Functional Properties; 1.3.1 Electrical Conductivity and Photoconductivity; 1.3.2 Liquid Crystallinity; 1.3.3 Luminescence; 1.3.4 Fluorescence Sensing; 1.3.5 Patterning and Imaging; 1.3.6 Chromism; 1.3.7 Optical Activity; 1.3.8 Supramolecular Assembly; 1.3.9 Optical Nonlinearity; 1.3.10 Biological Compatibility |
1.4 Conclusions and ProspectsAcknowledgments; References; 2 Suzuki Polycondensation: A Powerful Tool for Polyarylene Synthesis; 2.1 Introduction; 2.2 General Remarks; 2.3 How to Do an SPC and Aspects of Characterization; 2.3.1 Monomer Purity, Stoichiometry, and Solvents; 2.3.2 Brief Note on Optimization; 2.3.3 Reduced Catalyst Amount and Product Purification; 2.3.4 Molar Mass Determination; 2.4 Methodological Developments; 2.4.1 Boronic Acid/Boronate Monomers; 2.4.2 Boron-Based Ate Complexes; 2.4.3 Halo and Related Monomers; |
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2.4.4 Catalysts; 2.4.5 Chain Growth SPC |
2.4.6 Microwave and Technical Scale Microreactor Applications2.5 Selected Classes of Polyarylenes and Related Polymers; 2.5.1 Poly(para-phenylene)s; 2.5.2 Polyfluorenes; 2.5.3 Poly(para-meta-phenylene)s; 2.5.4 Shielded Polyarylenes; 2.5.5 Miscellaneous; 2.6 Conclusions and Outlook; Acknowledgments; References; 3 Advanced Functional Regioregular Polythiophenes; 3.1 Introduction; 3.2 Unsubstituted Polythiophene; 3.3 Poly(3-alkylthiophene)s; 3.4 Head-to-Tail Regioregular Poly(3-alkylthiophene)s (rrP3ATs); 3.4.1 Design and Synthesis of rrP3ATs; 3.4.1.1 McCullough Method; 3.4.1.2 Rieke Method |
3.4.1.3 GRIM Method3.4.1.4 Other Methods; 3.4.2 Mechanism of the Nickel-Catalyzed Polymerization; 3.4.3 End Group Functionalization; 3.4.3.1 Postpolymerization End Group Functionalization; 3.4.3.2 In situ End Group Functionalization; 3.4.4 Fundamental Properties of rrP3ATs; 3.4.4.1 UV-vis Absorption; 3.4.4.2 Microstructure and Morphology in Thin Films; 3.4.4.3 Electrical Conductivity; 3.4.5 rrP3ATs in Electronic Devices; 3.4.5.1 rrP3ATs in PLEDs; 3.4.5.2 rrP3ATs in OFETs; 3.4.5.3 rrP3ATs in OPVs; 3.5 Regiosymmetric Poly(alkylthiophene)s |
3.5.1 Head-to-Head-, Tail-to-Tail-Coupled Poly(alkylthiophene)s3.5.2 Regiosymmetric Alkylthiophene-Thiophene Copolymers; 3.6 Regiosymmetric Polythiophenes with (Hetero)aromatic Rings; 3.7 Polythiophene Block Copolymers; 3.7.1 All-Conjugated rrP3AT-Based Block Copolymers; 3.7.2 Conjugated-Nonconjugated rrP3AT-Based Block Copolymers; 3.8 Conclusion; References; 4 Poly(phenylenevinylenes); 4.1 Introduction; 4.2 Poly(p-phenylenevinylene)s via Polymerization Methods; 4.2.1 Gilch Approach; 4.2.2 The Wessling Method; 4.3 Poly(p-phenylenevinylene)s via Polycondensation |
4.3.1 Wittig and Horner-Wadsworth-Emmons Reaction |
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Sommario/riassunto |
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This first systematic compilation of synthesis methods for different classes of polymers describes well-tested and reproducible procedures, thus saving time, money and chemicals.Each chapter presents the latest method for a specific class of conjugated polymers with a particular emphasis on the design aspects for organo-electronic applications. In this concise and practically oriented manner, readers are introduced to the strategies of influencing and controlling the polymer properties with respect to their use in the desired device.This style of presentation quickly helps researchers |
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2. |
Record Nr. |
UNINA9910254684303321 |
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Autore |
Nakoinz Oliver |
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Titolo |
Modelling Human Behaviour in Landscapes : Basic Concepts and Modelling Elements / / by Oliver Nakoinz, Daniel Knitter |
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Pubbl/distr/stampa |
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Cham : , : Springer International Publishing : , : Imprint : Springer, , 2016 |
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ISBN |
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Edizione |
[1st ed. 2016.] |
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Descrizione fisica |
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1 online resource (XIX, 255 p. 119 illus., 12 illus. in color.) |
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Collana |
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Quantitative Archaeology and Archaeological Modelling , , 2366-5998 |
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Disciplina |
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Soggetti |
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Archaeology |
Computer simulation |
Statistics |
Simulation and Modeling |
Statistics for Social Sciences, Humanities, Law |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Nota di contenuto |
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Chapter 1:Introduction and Mathematics -- Chapter 2: Theory of Modelling -- Chapter 3: Software -- Chapter 4: Density -- Chapter 5: Regression and Interpolation -- Chapter 6: Location and Characterisation -- Chapter 7: Point Pattern -- Chapter 8: Boundaries -- Chapter 9: Networks -- Chapter 10: Interaction -- Chapter 11: Perception of Landscapes -- Chapter 12: Simulations. |
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Sommario/riassunto |
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This volume is designed as a 12-lecture textbook, which can serve as a course companion, self teaching guide and handbook for basic concepts. Each lecture comprises 20 pages, in which the methods are introduced, examples shown and the code is given. All examples are computed with open source software, mainly R, and with archaeological data available from the book's website. The book does not describe elaborated high-end models but rather very basic modelling concepts that serve as components in more complex models. The book enables the reader to construct such models by themselves and be sensitive for certain problems. In addition it gives hints for the interpretation of the results. Students are usually quick to apply fancy methods yet fail in the proper interpretation due to a lack of understanding of the |
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underlying principles. This problem is addressed by the proposed book through three concepts: 1. Command line software forces the students to first learn some details before they are able to produce results on their own. 2. The book is focused on principles and methods. When the students understand a few basic principles, they have far better access to a wide range of related methods. 3. Examples of poor analysis highlight common pitfalls. The volume attempts to be an applied, minimalistic and efficient textbook and is based upon several successful courses. |
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