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Record Nr. |
UNINA9910828803003321 |
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Titolo |
Supercapacitors : materials, systems, and applications / / edited by Fran{cedil}cois B{acute}eguin and El{dot}zbieta Fr©ıackowiak |
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Pubbl/distr/stampa |
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Weinheim, : Wiley-VCH, 2013 |
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ISBN |
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3-527-64666-3 |
3-527-64669-8 |
3-527-64668-X |
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Edizione |
[1st ed.] |
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Descrizione fisica |
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1 online resource (569 p.) |
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Collana |
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Materials for sustainable energy and development |
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Altri autori (Persone) |
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B{acute}eguinFran{cedil}cois |
Fr©ıackowiakEl{dot}zbieta |
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Disciplina |
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Soggetti |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Supercapacitors; 11 Supercapacitor Module Sizing and Heat Management under Electric, Thermal, and Aging Constraints; 11.1 Introduction; Contents; Series Editor Preface; Preface; About the Series Editor; About the Volume Editors; List of Contributors; 1 General Principles of Electrochemistry; 1.1 Equilibrium Electrochemistry; 1.1.1 Spontaneous Chemical Reactions; 1.1.2 The Gibbs Energy Minimum; 1.1.3 Bridging the Gap between Chemical Equilibrium and Electrochemical Potential; 1.1.4 The Relation between E and DGr; 1.1.5 The Nernst Equation; 1.1.6 Cells at Equilibrium; 1.1.7 Standard Potentials |
1.1.8 Using the Nernst Equation - Eh-pH Diagrams 1.2 Ionics; 1.2.1 Ions in Solution; 1.2.1.1 Ion-Solvent Interactions; 1.2.1.2 Thermodynamics; 1.2.2 The Born or Simple Continuum Model; 1.2.2.1 Testing the Born Equation; 1.2.3 The Structure of Water; 1.2.3.1 Water Structure near an Ion; 1.2.3.2 The Ion-Dipole Model; 1.2.3.3 Cavity Formation; 1.2.3.4 Breaking up the Cluster; 1.2.3.5 Ion-Dipole Interaction; 1.2.3.6 The Born Energy; 1.2.3.7 Orienting the Solvated Ion in the Cavity; 1.2.3.8 The Leftover Water Molecules; 1.2.3.9 Comparison with Experiment; 1.2.3.10 The Ion-Quadrupole Model |
1.2.3.11 The Induced Dipole Interaction 1.2.3.12 The Results; 1.2.3.13 Enthalpy of Hydration of the Proton; 1.2.4 The Solvation Number; |
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1.2.4.1 Coordination Number; 1.2.4.2 The Primary Solvation Number; 1.2.5 Activity and Activity Coefficients; 1.2.5.1 Fugacity (f'); 1.2.5.2 Dilute Solutions of Nonelectrolytes; 1.2.5.3 Activity (a); 1.2.5.4 Standard States; 1.2.5.5 Infinite Dilution; 1.2.5.6 Measurement of Solvent Activity; 1.2.5.7 Measurement of Solute Activity; 1.2.5.8 Electrolyte Activity; 1.2.5.9 Mean Ion Quantities; 1.2.5.10 Relation between f, y, andy; 1.2.6 Ion-Ion Interactions |
1.2.6.1 Introduction 1.2.6.2 Debye-Huckel Model for Calculating o2; 1.2.6.3 Poisson-Boltzmann Equation; 1.2.6.4 Charge Density; 1.2.6.5 Solving the Poisson-Boltzmann Equation; 1.2.6.6 Calculation of D ui-I; 1.2.6.7 Debye Length, K-1 or LD; 1.2.6.8 The Activity Coefficient; 1.2.6.9 Comparison with Experiment; 1.2.6.10 Approximations of the Debye-Huckel Limiting Law; 1.2.6.11 The Distance of Closest Approach; 1.2.6.12 Physical Interpretation of the Activity Coefficient; 1.2.7 Concentrated Electrolyte Solutions; 1.2.7.1 The Stokes-Robinson Treatment; 1.2.7.2 The Ion-Hydration Correction |
1.2.7.3 The Concentration Correction 1.2.7.4 The Stokes-Robinson Equation; 1.2.7.5 Evaluation of the Stokes-Robinson Equation; 1.2.8 Ion Pair Formation; 1.2.8.1 Ion Pairs; 1.2.8.2 The Fuoss Treatment; 1.2.9 Ion Dynamics; 1.2.9.1 Ionic Mobility and Transport Numbers; 1.2.9.2 Diffusion; 1.2.9.3 Fick's Second Law; 1.2.9.4 Diffusion Statistics; 1.3 Dynamic Electrochemistry; 1.3.1 Review of Fundamentals; 1.3.1.1 Potential; 1.3.1.2 Potential inside a Good Conductor; 1.3.1.3 Charge on a Good Conductor; 1.3.1.4 Force between Charges; 1.3.1.5 Potential due to an Assembly of Charges |
1.3.1.6 Potential Difference between Two Phases in Contact (Do) |
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Sommario/riassunto |
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Written by an international group of leading experts from both academia and industry, this is the first comprehensive book on the topic for 10 years. Taking into account the commercial interest in these systems and the scientific and technological developments over the past decade, all important materials and systems are covered, with several chapters devoted to topics of direct industrial relevance.The book starts by providing an introduction to the general principles of electrochemistry, the properties of electrochemical capacitors, and electrochemical characterization techniques. There |
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