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Record Nr. |
UNINA9910827804803321 |
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Autore |
Benelli Cristiano |
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Titolo |
Introduction to molecular magnetism : from transition metals to lanthanides / / Cristiano Benelli and Dante Gatteschi |
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Pubbl/distr/stampa |
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Weinheim, Germany : , : Wiley-VCH, , 2015 |
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©2015 |
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ISBN |
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3-527-69055-7 |
3-527-69054-9 |
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Descrizione fisica |
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1 online resource (465 p.) |
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Disciplina |
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Soggetti |
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Magnetochemistry |
Molecular crystals - Magnetic properties |
Rare earth metals |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references at the end of each chapters and index. |
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Nota di contenuto |
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Cover; Title Page; Copyright; Contents; Preface; Chapter 1 Introduction; 1.1 A Nano History of Molecular Magnetism; 1.2 Molecules, Conductors, and Magnets; 1.3 Origin of Molecular Magnetism; 1.4 Playing with the Periodic Table; 1.5 p Magnetic Orbitals; 1.6 d Magnetic Orbitals; 1.7 f Magnetic Orbitals; 1.8 The Goals of Molecular Magnetism; 1.9 Why a Book; 1.10 Outlook; 1.11 The Applications of Ln; 1.12 Finally SI versus emu; References; Chapter 2 Electronic Structures of Free Ions; 2.1 The Naked Ions; 2.2 Spin-Orbit Coupling; 2.3 Applying a Magnetic Field; References |
Chapter 3 Electronic Structure of Coordinated Ions3.1 Dressing Ions; 3.2 The Crystal Field; 3.3 The aquo Ions; 3.4 The Angular Overlap Model; 3.5 The Lantanum(III) with Phthalocyanine (Pc) and PolyOxoMetalates (POM); 3.6 Introducing Magnetic Anisotropy; References; Chapter 4 Coordination Chemistry and Molecular Magnetism; 4.1 Introduction; 4.2 Pyrazolylborates; 4.3 Phthalocyanines; 4.4 Cyclopentadiene and Cyclooctatetraene; 4.5 Polyoxometalates (POMs); 4.6 Diketonates; 4.7 Nitronyl-nitroxides (NITs); 4.8 Carboxylates; 4.9 Schiff Bases; References; Chapter 5 Magnetism of Ions |
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5.1 The Curie Law5.2 The Van Vleck Equation; 5.3 Anisotropy Steps in; References; Chapter 6 Molecular Orbital of Isolated Magnetic Centers; 6.1 Moving to MO; 6.2 Correlation Effects; 6.3 DFT; 6.4 The Complexity of Simple; 6.5 DFT and Single Ions; 6.6 DOTA Complexes, Not Only Contrast; References; Chapter 7 Toward the Molecular Ferromagnet; 7.1 Introduction; 7.2 A Road to Infinite; 7.3 Magnetic Interactions; 7.4 Introducing Interactions: Dipolar; 7.5 Spin Hamiltonians; 7.6 The Giant Spin; 7.7 Single Building Block; 7.8 Multicenter Interactions; 7.9 Noncollinearity |
7.10 Introducing Orbital DegeneracyReferences; Chapter 8 Molecular Orbital of Coupled Systems; 8.1 Exchange and Superexchange; 8.2 Structure and Magnetic Correlations: d Orbitals; 8.3 Quantum Chemical Calculations of SH Parameters; 8.4 Copper Acetate!; 8.5 Mixed Pairs: Degenerate-Nondegenerate; 8.6 f Orbitals and Orbital Degeneracy; References; Chapter 9 Structure and Properties of p Magnetic Orbitals Systems; 9.1 Magnetic Coupling in Organics; 9.2 Magnetism in Nitroxides; 9.3 Thioradicals; 9.4 Metallorganic Magnets; 9.5 Semiquinone Radicals; 9.6 NITR Radicals with Metals |
9.7 Long Distance Interactions in NitroxidesReferences; Chapter 10 Structure and Properties of Coupled Systems: d, f; 10.1 d Orbitals; 10.2 3d; 10.3 4d and 5d; 10.4 Introducing Chirality; 10.5 f-d Interactions; 10.6 A Model DFT Calculation; 10.7 Magneto-Structural Correlations in Gd-Cu; 10.8 f Orbital Systems and Orbital Degeneracy; References; Chapter 11 Dynamic Properties; 11.1 Introductory Remarks; 11.2 Spin-Lattice Relaxation and T1; 11.3 Phonons and Direct Mechanism; 11.4 Two Is Better than One; 11.5 Playing with Fields; 11.6 Something Real; 11.7 Spin-Spin Relaxation and T2; References |
Chapter 12 SMM Past and Present |
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Sommario/riassunto |
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This first introduction to the rapidly growing field of molecular magnetism is written with Masters and PhD students in mind, while postdocs and other newcomers will also find it an extremely useful guide. Adopting a clear didactic approach, the authors cover the fundamental concepts, providing many examples and give an overview of the most important techniques and key applications. Although the focus is one lanthanide ions, thus reflecting the current research in the field, the principles and the methods equally apply to other systems. |
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