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Record Nr. |
UNINA9910825617503321 |
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Autore |
Ott J. Bevan <1934-> |
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Titolo |
Chemical thermodynamics : advanced applications / / J. Bevan Ott and Juliana Boerio-Goates |
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Pubbl/distr/stampa |
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London, UK ; ; San Diego, : Academic Press, c2000 |
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ISBN |
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1-281-03846-6 |
9786611038465 |
0-08-050098-6 |
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Edizione |
[1st ed.] |
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Descrizione fisica |
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1 online resource (689 p.) |
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Altri autori (Persone) |
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Disciplina |
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Soggetti |
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Thermodynamics |
Chemistry, Physical and theoretical |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Front Cover; Chemical Thermodynamics: Principles and Applications; Copyright Page; Contents; Preface to the Two-Volume Series; Preface to the First Volume; Chapter 1. Introduction; 1.1 Thermodynamics - A Pre-eminent Example of an Exact Science; 1.2 The Language of Thermodynamics; 1.3 Thermodynamic Variables; 1.4 The Mathematics of Thermodynamics; 1.5 Derivation of Thermodynamic Equations using the Properties of the Exact Differential; 1.6 Calculation of Changes in the Thermodynamic Variable; 1.7 Use of Units; References; Chapter 2. The First and Second Laws of Thermodynamics |
2.1 The First Law of Thermodynamics2.2 The Second Law of Thermodynamics; 2.3 Implications of the Laws; References; Chapter 3. Thermodynamic Relationships and Applications; 3.1 The Gibbs Equations; 3.2 Partial Differential Relationships; 3.3 Applications of the Differential Relationships; 3.4 Relationship Between Free Energy and Work; References; Chapter 4. The Third Law and Absolute Entropy Measurements; 4.1 Verification of the Third Law; 4.2 Exceptions to the Third Law; 4.3 Implications and Applications of the Third Law; 4.4 Production of Low Temperatures and the Inaccessibility of Absolute |
4.5 Thermodynamic Functions References; Chapter 5. The Chemical Potential and Equilibrium; 5.1 Composition as a Variable; 5.2 The Chemical Potential; 5.3 Partial Molar Properties; 5.4 The Gibbs-Duhem |
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Equation; 5.5 Determination of Partial Molar Properties; 5.6 Criteria for Equilibrium; References; Chapter 6. Fugacity, Activity, and Standard States; 6.1 Fugacity; 6.2 The Activity; 6.3 Standard States; 6.4 Activities of Electrolyte Solutions; 6.5 Determination of Activity; References; Chapter 7. The Thermodynamic Properties of Solutions |
7.1 Change in the Thermodynamic Properties of Nonelectrolyte Solutions due to the Mixing Process7.2 Calculation of the Thermodynamic Properties of Strong Electrolyte Solutes: The Debye - Hückel Theory; 7.3 Relative Partial Molar and Apparent Relative Partial Molar Thermal Properties; 7.4 The Osmotic Pressure; References; Chapter 8. The Equilibrium Condition Applied to Phase Equilibria; 8.1 Phase Equilibria for Pure Substances; 8.2 Phase Equilibria for Mixtures; References; Chapter 9. The Equilibrium Condition Applied to Chemical Processes; 9.1 The Equilibrium Constant |
9.2 Enthalpies and Gibbs Free Energies of Formation9.3 Examples of Chemical Equilibrium Calculations; 9.4 Electrochemical Cells; References; Chapter 10. Statistical Thermodynamics; 10.1 Energy Levels of an Ideal Gas Molecule; 10.2 Distribution of Energy Among Energy Levels; 10.3 The Boltzmann Distribution Law; 10.4 The Partition Function; 10.5 Relationship Between the Partition Function and the Thermodynamic Properties; 10.6 Evaluation of the Partition Function for the Ideal Gas; 10.7 Calculation of the Thermodynamic Properties of the Ideal Gas |
10.8 Calculation of the Thermodynamic Properties of Solids |
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Sommario/riassunto |
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Chemical Thermodynamics: Principles and Applications presents a thorough development of the principles of thermodynamics--an old science to which the authors include the most modern applications, along with those of importance in developing the science and those of historical interest. The text is written in an informal but rigorous style, including anecdotes about some of the great thermodynamicists (with some of whom the authors have had a personal relationship), and focuses on ""real"" systems in the discussion and figures, in contrast to the generic examples that are often use |
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