Metal mediated template synthesis of ligands [[electronic resource] /] / Otilia Costisor, Wolfgang Linert

• Record Nr.: UNINA9910824945703321
• Autore: Costisor Otilia
• Pubbl/distr/stampa: Singapore ; ; River Edge, NJ, : World Scientific Pub. Co., c2004
• ISBN: 1-281-93470-4; 9786611934705; 981-279-481-6
• Descrizione fisica: 1 online resource (307 p.)
• Altri autori (Persone): LinertW
• Disciplina: 541.2242; 547.05; 547/.05
• Soggetti: Organometallic compounds - Synthesis; Organic compounds - Synthesis
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record
• Nota di bibliografia: Includes bibliographical references (p. 257-294) and index.
• Nota di contenuto: Contents ; Preface ; The Template Effect ; 1.1. Types of Template Effects ; 1.2. The Template Effect as a Molecular Organizer Effect ; 1.3. Factors Affecting the Product of a Template Reaction ; 1.3.1. Coordination of ligands ; 1.3.2. The chelate effect ; 1.3.3. Macrocyclic effect; 1.4. The Negative Template Effect 1.5. Advantages of Metal Template Reaction ; Alkylation Reactions ; 2.1. Alkylation of the Nitrogen Atom ; 2.2. Alkylation of the Sulfur Atom ; 2.2.1. Open chain systems ; 2.2.2. Macrocyclic ligands ; Schiff Condensation ; 3.1. Mechanistic Aspects; 3.2. Open-chain Ligands 3.3. Macrocyclic Ligands ; 3.3.1 Diimine macrocycles ; 3.3.2. Tetraimine macrocycles ; 3.4. Cage Ligands ; 3.5 Compartmental Ligands ; 3.5.1. Closed-chain ligands ; 3.5.2. Open chain ligands ; ; Mannich Condensation ; 4.1. Mechanistic Aspects; 4.2 Acyclic Ligands 4.2.1. Polyamine ligands ; 4.2.2. NO donor ligands ; 4.2.3. SN donor ligands ; 4.3. Monocyclic Ligands ; 4.3.1. Tetraaza macrocycles ; 4.3.2. Pentaaza macrocycles ; 4.3.3. Hexaaza macrocycles ; 4.3.4. Octaaza macrocycles ; 4.3.5. Azaether macrocycle; 4.3.6. Azathioether macrocycle 4.3.7. Reinforced macrocycles ; 4.3.8. Macromonocyclic dicompartmental ligands ; 4.4. Isolated Dimacrocycles ; 4.5.Condensed Polymacrocyclic Ligands ; 4.5.1. Carbon and nitrogen caped amine ligands ; 4.5.2. P- As amine cage ligands; 4.5.3. Thioamine cage ligands
• Sommario/riassunto: This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role