1.

Record Nr.

UNINA9910820826903321

Titolo

Grignard reagents and transition metal catalysts : formation of C-C bonds by cross-coupling / / edited by Janine Cossy

Pubbl/distr/stampa

Berlin, [Germany] ; ; Boston, [Massachusetts] : , : De Gruyter, , 2016

©2016

ISBN

1-5231-1642-0

3-11-038343-8

3-11-035272-9

Descrizione fisica

1 online resource (298 p.)

Disciplina

543.028/4

Soggetti

Grignard reagents

Chemical tests and reagents

Transition metal catalysts

Chemical bonds

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Includes index.

Nota di contenuto

Front matter -- Contents -- Contributing Authors -- Introduction -- 1. Grignard Reagents and Palladium / Nelson, David J. / Cazin, Catherine S. J. / Nolan, Steven P. -- 2. Grignard Reagents and Nickel / Fache, Fabienne / Pelotier, Béatrice / Piva, Olivier -- 3. Grignard Reagents and Iron / Legros, Julien / Figadère, Bruno -- 4. Grignard Reagents and Cobalt / Rérat, Alice / Gosmini, Corinne -- 5. Grignard reagents and Manganese / Cahiez, Gérard / Moyeux, Alban -- 6. Grignard reagents and Copper / Ouali, Armelle / Taillefer, Marc -- 7. Grignard Reagents and Silver / Cossy, Janine -- Index

Sommario/riassunto

In 1912, the Chemistry Nobel Prize was awarded for the discovery of the so-called Grignard reagents. Nowadays, many transition metal variants are developed to modify reactivity and selectivity of the C-C bond formation reaction. The Grignard reaction is one of the fundamental organometallic reactions, often used in alcohol syntheses. With transition metals like iron, cobalt and nickel or with noble metals like copper, silver and palladium, modern Grignard reagents can be designed in reactivity, selectivity and functional group tolerance. This



book, written by international experts,  presents an overview on timely Grignard chemistry involving transition metals.