1.

Record Nr.

UNINA9910819092303321

Autore

Rozenbaum V. M (Viktor Mikhailovich)

Titolo

Spectroscopy and dynamics of orientationally structured adsorbates / / V.M. Rozenbaum, S.H. Lin

Pubbl/distr/stampa

River Edge, N.J., : World Scientific, c2002

ISBN

981-277-650-8

Edizione

[1st ed.]

Descrizione fisica

1 online resource (208 p.)

Collana

World scientific lecture and course notes in chemistry ; ; v. 7

Altri autori (Persone)

LinS. H <1937-> (Sheng Hsien)

Disciplina

530.417

Soggetti

Surface chemistry

Adsorption

Spectrum analysis

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references (p. 183-191) and index.

Nota di contenuto

Contents               ; Preface              ; 1. Introduction                      ; 2. Orientational structures of adsorbates                                                ; 2.1. Brief survey of experimental data and theoretical approaches                                                                        ; 2.2. Orientational ordering in two-dimensional dipole systems

2.3. Lateral interactions of nonpolar molecules and expressing them in a quasi-dipole form                                                                                                 2.4. Ground states and phase transitions for a system of nonpolar molecules on a square lattice                                                                                                      ; 2.5. Orientational phase transitions in planar systems of nonpolar molecules

3. Dispersion laws for collective excitations on complex planar lattices                                                                               3.1. Complex orientational structures and corresponding Davydov-split spectral lines                                                                                           ; 3.2. Lattice-sublattice relations and its application to orientational structures on square and honeycomb lattices

3.3. Chain orientational structures on planar lattices                                                             4. Temperature dependences of spectral line shifts and widths                                                                    ; 4.1. Resonant nature of low-frequency collective excitations of  adsorbed molecules

4.2. Markov approximation for Green's functions of molecular subsystems in the condensed phase                                                                                                     4.2.1. The exact solution for the exchange dephasing model                                                                



; 4.2.2. Valence-deformation vibrations of a molecular subsystem in condensed phase

4.2.3. Perturbation theory for transition rates in the Pauli equation

Sommario/riassunto

This book provides a detailed and rigorous presentation of the spectroscopy and dynamics of orientationally structured adsorbates. It is intended largely for specialists and graduate students in solid state theory and surface physics. To make the book readable also for beginners in surface science, a lucid style is used and a wealth of references on orientational surface structures and vibrational excitations in them is offered. The book is supplemented with two indices (alphabetical listing of subjects and authors, as well as cross-references) which will enable the reader to easily access th