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Record Nr. |
UNINA9910817713003321 |
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Titolo |
Using supercritical water oxidation to treat hydrolysate from VX neutralization / / Committee on Review and Evaluation of the Army Chemical Stockpile Disposal Program, Board on Army Science and Technology, Commission on Engineering and Technical Systems, National Research Council |
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Pubbl/distr/stampa |
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Washington, D.C., : National Academy Press, 1998 |
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ISBN |
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0-309-17399-X |
1-280-18679-8 |
9786610186792 |
0-309-56255-4 |
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Edizione |
[1st ed.] |
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Descrizione fisica |
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1 online resource (82 p.) |
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Collana |
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Disciplina |
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Soggetti |
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Chemical weapons disposal |
Chemical weapons disposal - United States |
Chemical agents (Munitions) |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Bibliographic Level Mode of Issuance: Monograph |
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Nota di bibliografia |
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Includes bibliographical references (p. 55-58). |
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Nota di contenuto |
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Using Supercritical Water Oxidation to Treat Hydrolysate from VX Neutralization -- Copyright -- Preface -- Contents -- Acronyms -- Executive Summary -- BACKGROUND -- FINDINGS -- RECOMMENDATIONS -- 1 Introduction and Background -- SELECTION OF NEUTRALIZATION FOLLOWED BY SUPERCRITICAL WATER OXIDATION FOR STOCKPILE DISPOSAL AT NEWPORT, INDIANA -- VX STORAGE AT NEWPORT, INDIANA -- NEUTRALIZATION OF VX -- 2 Process Description and Scientific Principles -- PROCESS OVERVIEW -- SCIENTIFIC PRINCIPLES -- KINETICS -- PHASE BEHAVIOR -- 3 Technology Status -- PREVIOUS APPLICATIONS OF SUPERCRITICAL WATER OXIDATION TECHNOLOGY -- DEVELOPMENT PROGRAM FOR APPLICATION TO VX HYDROLYSATE -- Laboratory-Scale Tests to Establish Methylphosphonic Acid DREs -- Pilot-Scale Testing with Surrogates and VX Hydrolysate -- Toxicity of the Liquid Effluent -- Summary of Solids Management and System Performance -- STATUS OF |
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EVAPORATOR TECHNOLOGY -- 4 Scale-Up, Stability, and Reliability -- PROCESS SCALE-UP -- SALT MANAGEMENT AND REACTOR DESIGN -- Higher Pressure Systems -- Dissolution in Molten Sodium Hydroxide -- Catalyzed Oxidation -- Transpiring Wall Reactor -- Engineering Control -- Conclusion -- CHOICE OF OXIDANT, MIXING, AND HEAT BALANCE -- CORROSION AND THE MATERIALS OF CONSTRUCTION -- PRESSURE LET-DOWN SYSTEMS -- SUMMARY -- 5 Full-Scale Process Design -- PROCESS DESCRIPTION -- PROCESS START-UP AND SHUTDOWN -- PROCESS MASS AND ENERGY BALANCES -- PROCESS MONITORING AND CONTROL -- MANAGING UPSETS AND MAINTENANCE -- PROCESS SAFETY -- PROCESS EFFLUENT REQUIREMENTS -- TECHNOLOGY IMPLEMENTATION TIMELINE -- ENVIRONMENTAL PERMIT REQUIREMENTS -- 6 Findings and Recommendations -- FINDINGS -- RECOMMENDATIONS -- References -- Appendices -- Appendix A Process Flow Diagrams for the Supercritical Water Oxidation and Evaporation Process Steps. |
Appendix B Mass Balance for the Newport Chemical Agent Disposal Facility (NECDF) Process. |
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