Solid-phase palladium chemistry / / edited by Peter J.H. Scott

• Record Nr.: UNINA9910812850103321
• Pubbl/distr/stampa: Hoboken, New Jersey : , : Wiley, , [2012]; ©2012
• ISBN: 1-280-77848-2; 9786613688873; 1-118-33670-4; 1-118-33695-X; 1-118-33669-0
• Descrizione fisica: 1 online resource (186 p.)
• Collana: Wiley series on solid-phase organic syntheses ; ; 2
• Classificazione: SCI013050
• Disciplina: 547.056362; 547/.056362
• Soggetti: Organopalladium compounds; Organic compounds - Synthesis; Solid-phase synthesis
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Solid-Phase Organic Syntheses; CONTENTS; Contributors; Preface; Abbreviations; PART I INTRODUCTION; 1. An Introduction to Solid-Phase Palladium Chemistry; PART II PALLADIUM-MEDIATED SPOS; 2. Pd-Catalyzed Solid-Phase Decoration of the2(1H)-Pyrazinone Scaffold; 3. One-Step Palladium- and Phenylsilane-ActivatedAmidation of Solid-Supported Ally Esters; 4. Solid-Phase Reactions of Polymer-BoundArenesulfonates with Aryl Grignard Reagents; 5. Fluorous Synthesis of 3-Aminoimidazo[1,2-a]-Pyridine/Pyrazine Library; 6. Resin-to-Resin Transfer Reactions (RRTR) viaSonogashira Coupling; PART III IMMOBILIZED CATALYSTS AND LIGANDS7. Polymer-supported Palladium Catalysts for Suzukiand Heck Reactions; 8. Solid-Phase Catalytic Activity of aPolymer-Supported Palladium Complex; 9. Polyaniline-immobilized Palladium forSuzuki-Miyaura Coupling Reaction in Water; 10. Synthesis of Polymer-SupportedAryldicyclohexylphosphine for an Efficient; 11. C-C or C-N ; Reactions Catalyzed byDiadamanthylphosphine Palladium-Based CatalystSupported on Dab-Dendrimers; PART IV PALLADIUM-MEDIATED MULTIFUNCTIONALCLEAVAGE; 12. Solid-Phase Reactions of Resin-Supported BoronicAcids; 13. A Simple Diversity Linker Strategy Using ImmobilizedEnol Phosphonates as Electrophiles forSuzuki-Miyaura Reactions14. Heck Cleavage of Resin-bound Triazenes; 15. Pd-Mediated Cleavage fromTetrafluoroarylsulfonate Linker Units; 16. Palladium-Catalyzed Solid-Phase Synthesis ofAllylic Amines; 17. Palladium-Catalyzed Solid-Phase Synthesis of4-Methylene Pyrrolidines; Index
• Sommario/riassunto: "This series informs researchers of major accomplishments in solid-phase organic synthesis and provides actual experimental details and specific references. With this series, a reader will be able to sharpen hands-on skills by following the experimental procedures and refining understanding of the science by studying the chosen reactions. More importantly, this series guides readers in designing novel compound libraries, and may also inspire future breakthroughs. This second volume focuses on palladium chemistry in solid-phase synthesis, and discusses: palladium catalysts and reactions, procedures for preparation and utilization, ligands, and linker reactions"--