Chemical equilibria / / Michel Soustelle

• Record Nr.: UNINA9910809214603321
• Autore: Soustelle Michel
• Pubbl/distr/stampa: Hoboken, NJ : , : Wiley, , 2015
• ISBN: 1-119-17856-8; 1-119-17854-1; 1-119-17855-X
• Descrizione fisica: 1 online resource (179 p.)
• Collana: Chemical engineering series : chemical thermodynamics set ; ; volume 4
• Disciplina: 541.392
• Soggetti: Thermodynamics - Mathematical models; Chemical equilibrium - Mathematical models; Phase transformations (Statistical physics)
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Table of Contents; Title; Copyright; Preface; Notations and Symbols; 1: Physico-Chemical Transformations and Equilibria; 1.1. Characteristic parameters of physico-chemical transformations; 1.2. Entropy production during the course of a transformation in a closed system; 1.3. Affinity of a transformation; 1.4. De Donder's inequality - direction of the transformations and equilibrium conditions; 1.5. Heats of transformation; 1.6. Set of points representing the equilibrium states of a transformation; 1.7. Closed systems accommodating multiple reactions; 1.8. Direction of evolution and equilibrium conditions in an open system1.9. Azeotropic transformations; 2: Properties of States of Physico-Chemical Equilibrium; 2.1. Laws of displacement of an equilibrium; 2.2. Properties of all the equilibria in a system; 2.3. Phase laws; 2.4. Indifferent states; 2.5. Thermodynamically-equivalent systems; 2.6. Stability of equilibria; 3: Molecular Chemical Equilibria; 3.1. Law of mass action - equilibrium constants; 3.2. Graphical representations of equilibria - pole diagrams; 3.3. Representation of the evolution of an equilibrium with the temperature; 3.4. Binary diagrams for chemical equilibrium3.5. Ternary diagrams of ; chemical equilibria; 3.6. Quaternary diagrams of chemical equilibria; 4: Determination of the Values Associated with Reactions - Equilibrium Calculations; 4.1. Reminders of a few thermodynamic relations; 4.2. Enthalpies of reaction - thermochemistry; 4.3. Reaction entropies; 4.4. Specific heat capacities; 4.5. Experimental determination of the equilibrium constants; 4.6. Calculation of the equilibrium constants on the basis of other thermodynamic data; 4.7. Determination of the equilibrium constants on the basis of spectral data and statistical thermodynamics4.8. Thermodynamic tables and databanks; 4.9. Estimation of thermodynamic data; 4.10. Thermodynamic calculations for complex systems; APPENDICES; Appendix 1: Recap on the Reference States of Solutions; A1.1. Concentration and molar fraction; A1.2. Chemical potentials and activity coefficients; A1.3. Characterization of the imperfection of a real solution by the excess Gibbs energy; Appendix 2: Recap of statistical thermodynamics; A2.1. The three branches of statistics; A2.2. Partition functions of a molecule objectA2.3. Canonical partition function; A2.4. Canonical partition functions and thermodynamic functions; A2.5. Equilibrium constants and molecular partition functions; Bibliography; Index; End User License Agreement