Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme

• Record Nr.: UNINA9910806234203321
• Autore: Saluzzo Christine
• Pubbl/distr/stampa: New York, : Nova Science Publishers, c2011
• ISBN: 1-61728-101-8
• Edizione: [1st ed.]
• Descrizione fisica: 1 online resource (185 p.)
• Collana: Polymer science and technology
• Altri autori (Persone): GuillarmeStéphane
• Disciplina: 541/.395
• Soggetti: Asymmetric synthesis; Enantioselective catalysis; Ligands; Nitrogen compounds
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Intro -- ASYMMETRIC HETEROGENEOUS SUPPORTED CATALYSIS: USE OF NITROGEN-CONTAINING LIGANDS -- Library of Congress Cataloging-in-Publication Data -- Contents -- Preface -- Chapter 1: Introduction -- Chapter 2: Reduction of C=O and C=N Bond -- 2.1. Hydrogenation -- 2.2. Hydrogenation Transfer Reduction -- 2.2.1. 1,2-Diamine and Derivatives -- 2.2.2. Imprinting Technique for Hydrogen Transfer Reduction with 1,2-Diamines -- 2.2.3. Aminoalcohol as Ligand -- 2.2.4. Dialdimine Ligand as Ligand -- 2.3. Enantioselective Hydride Reduction -- 2.4. Hydrosilylation with Ligands as Pendent Group -- 2.5. Reduction of C=N bond -- Chapter 3: Cyclopropanation -- 3.1. Oxazolines Ligands -- 3.1.1. Insoluble Supported-Polymer Box a Ligands -- 3.1.2. Insoluble Supported-Polymer AzaBOX as Ligands -- 3.1.3. Insoluble Supported-Polymer PyBox as Ligands -- 3.1.4. Immobilization of PyBox on Natural Polymers -- 3.1.5. Soluble Supported-Polymer Box as Ligands -- 3.1.6. Soluble Supported-Polymer AzaBox as Ligands -- 3.2. Porphyrins -- 3.3. Miscellaneous -- Chapter 4: Cycloadditions and Heterocycloadditions -- 4.1. Supported Box Ligands -- 4.2. Supported Aminoalcohol and N-Sulfonylamino Acid-Derived Oxazaborolidine or Oxazaborolidinone -- 4.3. Supported Salen as Ligand -- Chapter 5: Addition of Organometallic Reagents to ; Aldehydes, Ketones and Imines -- 5.1. Supported Aminoalcohols as Ligands -- 5.2. Supported Sulfonamide -- and N-Sulfonylated Aminoalcohols -- 5.3. Supported Oxazoline -- or Oxazolidine as Ligands -- 5.4. Supported Salen as Chiral Ligands -- Chapter 6: Asymmetric (-Allylic Substitution -- Chapter 7: Dihydroxylation and Aminohydroxylation -- 7.1. Insoluble Supported Alkaloid as Ligand -- 7.2. Soluble Supported Alkaloid as Ligand -- Chapter 8: Epoxidation -- 8.1. Supported Salen as Ligand -- 8.2. Porphyrins -- 8.3. Soluble Polymers.; Chapter 9: Kinetic Resolution of Terminal Epoxides -- Chapter 10: Miscellaneous -- Chapter 11: Conclusion -- References -- Index.