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Record Nr. |
UNINA9910788555303321 |
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Autore |
Lin Y.-H |
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Titolo |
Polymer viscoelasticity [[electronic resource] ] : basics, molecular theories, experiments and simulations / / Yn-Hwang Lin |
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Pubbl/distr/stampa |
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Singapore ; ; Hackensack, N.J., : World Scientific, c2011 |
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ISBN |
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1-283-14464-6 |
9786613144645 |
981-4313-04-1 |
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Edizione |
[2nd ed.] |
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Descrizione fisica |
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1 online resource (350 p.) |
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Disciplina |
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Soggetti |
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Polymers - Viscosity |
Viscoelasticity |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references and index. |
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Nota di contenuto |
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Contents; Preface; Preface to the Second Edition; 1. Conformation of Polymer Chains; 2. Rubber Elasticity; 3. Polymer Chain Dynamics; 4. Linear Viscoelasticity; 5. Stress and Strain; 6. Molecular Theory of Polymer Viscoelasticity - Elastic Dumbbell Model; 7. Molecular Theory of Polymer Viscoelasticity-The Rouse Model; 8. Molecular Theory of Polymer Viscoelasticity - Entanglement and the Doi-Edwards (Reptation) Model; 9. Molecular Theory of Polymer Viscoelasticity-The Extended Reptation Model; 10. Comparison of the Extended Reptation Theory (ERT) with Experiments |
11. ERT vs. Rouse Theory, Concentration Dependence and Onset of Entanglement, and Tube Dilation 12. Molecular Theory of Polymer Viscoelasticity - Nonlinear Relaxation Modulus of Entangled Polymers; 13. Number of Entanglement Strands per Cubed Entanglement Distance, nt; 14. Glass Transition-Related Thermorheological Complexity in Polystyrene Melts; 15. The Basic Mechanism for the Thermorheological Complexity in Polystyrene Melts; 16. Monte Carlo Simulations of Stress Relaxation of Rouse Chains |
17. Monte Carlo Simulations of Stress Relaxation of Fraenkel Chains - Linear Viscoelasticity of Entanglement-Free Polymers 18. Monte Carlo Simulations of Stress Relaxation of Fraenkel Chains - Nonlinear Viscoelasticity of Entanglement-Free Polymers; Index |
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Sommario/riassunto |
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This book covers in great detail the Rouse-segment-based molecular theories in polymer viscoelasticity - the Rouse theory and the extended reptation theory (based on the framework of the Doi-Edwards theory) - that have been shown to explain experimental results in a consistently quantitative way. The explanation for the 3.4 power law of viscosity, quantitative line-shape analyses of viscoelastic responses and agreements between different sorts of viscoelastic responses, the consistency between the viscoelasticity and diffusion results, the clarification of the onset of entangelement, |
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