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1. |
Record Nr. |
UNINA9910787418903321 |
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Titolo |
Handbook of metathesis . Volume 2 Applications in organic synthesis / / editors, Prof. Robert H. Grubbs, Prof. Daniel J. O'Leary |
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Pubbl/distr/stampa |
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Weinheim an der Bergstrasse, Germany : , : Wiley-VCH, , 2015 |
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©2015 |
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ISBN |
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3-527-69404-8 |
3-527-69402-1 |
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Edizione |
[2nd ed.] |
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Descrizione fisica |
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1 online resource (772 p.) |
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Disciplina |
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Soggetti |
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Metathesis (Chemistry) |
Alkenes |
Organic compounds - Synthesis |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references at the end of each chapters and index. |
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Nota di contenuto |
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Cover; Contents; Preface; List of Contributors; List of Abbreviations; Chapter 1 General Ring-Closing Metathesis; 1.1 Introduction; 1.2 Carbocycles (Introduction); 1.2.1 Small-Sized Carbocycles; 1.2.2 Medium-Sized Carbocycles; 1.2.3 Spiro Carbocycles; 1.3 Synthesis of Bridged Bicycloalkenes; 1.4 Synthesis of Heterocycles Containing Si, P, S, or B; 1.4.1 Si-Heterocycles; 1.4.2 P-Heterocycles; 1.4.3 S-Heterocycles; 1.4.4 B-Heterocycles; 1.5 Synthesis of O-Heterocycles; 1.5.1 Small and Medium-Size Cyclic Ethers; 1.5.2 Polycyclic Ethers; 1.6 Synthesis of N-Heterocycles; 1.6.1 N-Heterocycles |
1.6.2 Small and Medium-Sized Lactams1.7 Synthesis of Cyclic Conjugated Dienes; 1.8 Alkyne Metathesis; 1.9 Enyne Metathesis; 1.9.1 General Enyne Metathesis; 1.9.2 Dienyne Metathesis; 1.10 Tandem Processes; 1.10.1 Tandem ROM/RCM; 1.10.2 Other Tandem RCMs; 1.11 Synthesis of Macrocycles; 1.11.1 Macrocycles; 1.11.2 Macrolactones; 1.11.3 Macrolactams; 1.12 RCM and Isomerization via Ru-H; 1.13 Relay RCM (RRCM); 1.14 Z-Selective RCM; 1.14.1 Substrate-Controlled Z-Selective RCM; 1.14.2 Catalyst-Controlled Z-Selective RCM; 1.15 Enantioselective RCM; 1.16 Conclusion; Acknowledgments; References |
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Chapter 2 Cross-Metathesis2.1 Early Examples Using Well-Defined Molybdenum and Ruthenium Catalysts; 2.2 The General Model for Selectivity in CM Reactions; 2.3 Definition of Cross-Metathesis Reaction Categories and Chapter Organization; 2.4 Hydrocarbons; 2.4.1 Alkane Extensions; 2.4.2 Unsaturated Hydrocarbons, Including Styrene; 2.4.3 Ethylene Cross-Metathesis; 2.5 Boron; 2.6 Nitrogen; 2.6.1 Amines; 2.6.2 Amines as CM Partners in Heterocycle Syntheses; 2.6.3 Acrylonitrile and Other Nitrile-Based CM Applications; 2.6.4 Other Nitrogenous Substrates; 2.7 Oxygen |
2.7.1 Primary Allylic Alcohols and Derivatives2.7.2 Secondary Allylic Alcohols and Derivatives; 2.7.3 Tertiary Allylic Alcohols and Derivatives; 2.7.4 Homoallylic Alcohols and Derivatives; 2.7.5 Vinyl Ethers; 2.7.6 Acrolein, Crotonaldehyde, and Methacrolein; 2.7.7 Methyl Vinyl Ketone and Related Systems; 2.7.8 Acrylic Acid; 2.7.9 Acrylic Acid Derivatives, Including Esters, Thioesters, and Amides; 2.8 Halides; 2.9 Phosphorus; 2.10 Sulfur; 2.11 Fragment Coupling Reactions; 2.11.1 Acetogenins; 2.11.2 Cross-Metathesis Selectivity; 2.11.3 Tuning Metathesis Selectivity |
2.11.4 CM as an Alternative Coupling Strategy2.11.5 CM-Based Analog Synthesis; 2.11.6 Polyene Metathesis; 2.11.7 Cross-Metathesis Reaction Optimization: Pinnaic Acid; 2.12 Conclusions; References; Chapter 3 Vignette: Extending the Application of Metathesis in Chemical Biology - The Development of Site-Selective Peptide and Protein Modifications; 3.1 Introduction; 3.2 Cross-Metathesis Methodology Studies in Aqueous Media; 3.2.1 Allyl Sulfides are Reactive Substrates in Olefin Metathesis; 3.2.2 Sulfur-Relayed Cross-Metathesis |
3.2.3 Application of Aqueous Metathesis of Allyl Sulfides in Synthesis |
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Sommario/riassunto |
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The second edition of the ""go-to"" reference in this field is completely updated and features more than 80% new content, with emphasis on new developments in the field, especially in industrial applications. No other book covers the topic in such a comprehensive manner and in such high quality. Edited by the Nobel laureate R. H. Grubbs and D. J. O ́Leary, this volume 2 of the 3-volume work focusses on applications in organic synthesis. With a list of contributors that reads like a ""Who's-Who"" of metathesis, this is an indispensable one-stop reference for chemists in academia and industry. |
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2. |
Record Nr. |
UNINA9910819768703321 |
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Autore |
Cigar Norman L. |
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Titolo |
Al-Qaida, the tribes, and the government : lessons and prospects for Iraq's unstable triangle / / Norman Cigar |
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Pubbl/distr/stampa |
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Quantico, Virginia : , : Marine Corps University Press, , 2011 |
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©2011 |
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ISBN |
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Descrizione fisica |
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1 online resource (168 pages) |
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Collana |
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Middle East Studies Occasional Papers ; ; Number 2 |
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Disciplina |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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3. |
Record Nr. |
UNINA9910817408303321 |
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Autore |
Alapati Sundeep |
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Titolo |
Laryngeal Cancer : Clinical Case-Based Approaches / / by: Dedivitis, Rogério A., Peretti, Giorgio, Hanna, Ehab, Cernea, Claudio R. |
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Pubbl/distr/stampa |
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New York, New York : , : Thieme, , [2019] |
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©2019 |
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ISBN |
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1-63853-619-8 |
1-68420-002-4 |
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Descrizione fisica |
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1 online resource (xxiii, 193 pages) : illustrations |
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Disciplina |
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Soggetti |
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Larynx - Cancer - Surgery |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Sommario/riassunto |
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"Ongoing advances in innovative technologies have improved the diagnosis and treatment of laryngeal cancer, resulting in more optimal oncologic and functional patient outcomes. Laryngeal Cancer: Clinical Case-Based Approaches, by distinguished head and neck surgeon Rogério A. Dedivitis and internationally recognized coeditors, is a comprehensive reference that presents multiple options for similar lesions. Contributions from a diverse group of globally renowned subspecialists reflect the multidisciplinary treatment of laryngeal cancer. The book focuses on diverse primary subsites of laryngeal cancer; local, early-stage, and advanced disease stages; and current available treatment modalities for each type. Case study chapters include insightful discussion of several potential approaches, rationale for surgical decision making, radiographic findings, pearls, and pitfalls"--Provided by publisher. |
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