Handbook of metathesis . Volume 3 Polymer synthesis / / edited by Robert H. Grubbs and Ezat Khosravi

• Record Nr.: UNINA9910787418803321
• Pubbl/distr/stampa: Weinheim, Germany : , : Wiley-VCH, , 2015; ©2015
• ISBN: 3-527-69405-6; 3-527-69407-2
• Edizione: [2nd ed.]
• Descrizione fisica: 1 online resource (424 p.)
• Disciplina: 547.412
• Soggetti: Polymerization; Metathesis (Chemistry)
• Lingua di pubblicazione: Tedesco
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references at the end of each chapters and index.
• Nota di contenuto: Cover; Contents; Preface; List of Contributors; Chapter 1 Synthesis of Homopolymers and Copolymers; 1.1 Introduction; 1.2 Initiators; 1.3 Monomers; 1.4 Synthesis of Polymers with Complex Architectures; 1.5 Stereochemistry and Sequence Control in ROMP; 1.6 Conclusion; References; Chapter 2 ROMP in Dispersed Media; 2.1 Introduction; 2.2 Emulsion ROMP; 2.2.1 Mini-emulsion ROMP; 2.2.2 Micro-emulsion ROMP; 2.2.3 Micellar ROMP; 2.2.4 ROMP in Nonaqueous Emulsions; 2.3 Dispersion ROMP; 2.3.1 Biomedical Applications of PNBE-PEO Core-Shell Nanoparticles; 2.4 Suspension ROMP; 2.5 Formation of Nanoparticles2.5.1 Photoactive ROMP Assemblies; 2.5.2 Miscellaneous; 2.6 Conclusion; References; Chapter 3 Telechelic Polymers; 3.1 Introduction; 3.2 Mono-telechelic Polymers; 3.2.1 Reaction with Substituted Vinyl Ethers; 3.2.2 Vinyl Lactone Quenching; 3.2.3 Terminal Cross Metathesis; 3.2.3.1 Using Symmetrical Olefins; 3.2.3.2 Using Asymmetrical Olefins; 3.2.4 Reaction with Oxygen; 3.2.5 Sacrificial Diblock Copolymer Synthesis; 3.2.6 Catalyst Prefunctionalization; 3.2.6.1 Functional Catalysts from Precursor Complexes; 3.2.6.2 Functional Catalysts via Cross Metathesis; 3.2.7 Aldehyde Quenching3.3 Homo-telechelic Polymers; 3.3.1 Degradation of Unsaturated Polymers and ADMET Polymerization; 3.3.2 ; ROMP/Chain Transfer; 3.3.3 Sacrificial Multiblock Copolymers; 3.4 Hetero-telechelic Polymers; 3.4.1 Prefunctionalization with Functional Alkylidene Initiators; 3.4.2 Prefunctionalization with Sacrificial Synthesis; 3.5 Conclusions and Outlook; Acknowledgments; References; Chapter 4 Supramolecular Polymers; 4.1 Introduction; 4.2 Main-Chain Supramolecular Polymers; 4.2.1 Macromonomers; 4.2.2 ABC Triblock Copolymers; 4.3 Side-Chain-Functionalized Supramolecular Polymers; 4.3.1 Hydrogen-Bonding Recognition Motifs4.3.2 Metal Coordination-Based Recognition Motifs; 4.3.3 Mixed Orthogonal Recognition Motifs; 4.4 Supramolecular Architectures by Design; 4.5 Conclusion; References; Chapter 5 Synthesis of Materials with Nanostructured Periodicity; 5.1 Introduction; 5.2 Sequential ROMP; 5.3 Inorganic Composite Materials; 5.4 ABA Triblock Copolymers; 5.5 Nanostructures with Domain Sizes Exceeding 100 nm; 5.6 Conclusions; References; Chapter 6 Synthesis of Nanoparticles; 6.1 Introduction; 6.2 Formation of Nanoparticles; 6.3 Synthesis via Grafting-through Approach; 6.4 Synthesis via Grafting-to Approach6.4.1 Grafting-to Polymer Backbones via an Activated Ester; 6.4.2 Grafting-to Polymer Backbones via Copper-Catalyzed Click Reaction; 6.5 Synthesis via Grafting-from Approach; 6.6 Summary; References; Chapter 7 Synthesis of Biodegradable Copolymers; 7.1 Introduction; 7.2 Polyester-Functionalized Polymers; 7.3 Peptide-Functionalized Polymers; 7.4 Carbohydrate-Functionalized Polymers; 7.5 Antimicrobial Polymers; 7.6 Polymeric Betaines; 7.7 ROMP Polymers as Drug Carriers; 7.8 ROMP Polymers for Tissue Scaffolds; 7.9 Conclusion; References; Chapter 8 Biologically Active Polymers
• Sommario/riassunto: The second edition of this ultimate reference in this field is completely updated and features more than 80% new content, with emphasis on new developments in the field, especially in industrial applications. No other book covers the topic in such a comprehensive manner and in such high quality. Edited by the Nobel laureate R. H. Grubbs and E. Khosravi, this volume 3 of the 3-volume work focusses on polymer synthesis. With a list of contributors that reads like a ""Who's-Who"" of metathesis, this is an indispensable one-stop reference for chemists in academia and industry. Other available