1.

Record Nr.

UNINA9910767505803321

Autore

Marmisollé Waldemar A

Titolo

Binding Phenomena : General Description and Analytical Applications / / by Waldemar A. Marmisollé, Dionisio Posadas

Pubbl/distr/stampa

Cham : , : Springer International Publishing : , : Imprint : Springer, , 2023

ISBN

3-031-39736-3

Edizione

[1st ed. 2023.]

Descrizione fisica

1 online resource (190 pages)

Collana

Physical Chemistry in Action, , 2197-4357

Altri autori (Persone)

PosadasDionisio

Disciplina

541.224

Soggetti

Physical chemistry

Analytical chemistry

Chemistry, Physical and theoretical

Distribution (Probability theory)

Physical Chemistry

Analytical Chemistry

Theoretical Chemistry

Distribution Theory

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Nota di contenuto

Introduction -- Binding to simple substrates with one binding site -- One substrate with two different binding sites. Competitive binding. Two different binding species. Two different binding substrates -- Titration of simple substrates -- Continuous Distribution Functions. Cumulative and Density Distribution Functions. Known Examples -- Elements of adsorption on heterogeneous substrates -- Theoretical bases for the interpretation of the titration curves of macromolecules -- Acid-Base equilibria at complex substrates. Polyacids and Polybases -- Acid-Base Titration of complex substrates -- The Acid-Base Behaviour of Polyampholytes. The Case of Colloidal Oxides -- Titration of polyampholytes. Polyzwitterions and other examples -- Electron titrations of electrochemically active Macromolecules -- Appendices.

Sommario/riassunto

This book presents a unified description of binding equilibrium for a wide variety of systems focusing on acid-base and coordination chemistry, adsorption at interfaces, and electron binding in



electrochemistry. It overviews more complex phenomena such as competitive binding to different sites and of different ligands. Multiple sites such as those occurring in macromolecules, colloidal oxides, humid substances, and proteins are briefly discussed and many experimental results for these types of systems are analyzed. Titrations and consideration of the distribution of binding constants are also presented. The book is mainly directed at undergraduate/graduate students of chemistry, biology, and earth sciences. It is supplementary to the standard physical and analytical chemistry courses and will help both students and teachers get a more in-depth knowledge and understanding of the systems analyzed.