1.

Record Nr.

UNINA9910739477903321

Titolo

Heterocycles from Carbenes and Nitrenes : Methods, Reactions and Synthetic Applications / / edited by Michael P. Doyle, Xinfang Xu

Pubbl/distr/stampa

Cham : , : Springer International Publishing : , : Imprint : Springer, , 2023

ISBN

9783031367359

3031367359

Edizione

[1st ed. 2023.]

Descrizione fisica

1 online resource (381 pages)

Collana

Topics in Heterocyclic Chemistry, , 1861-9290 ; ; 59

Altri autori (Persone)

DoyleMichael P. <1949->

XuXinfang, Professor

Disciplina

547.59

Soggetti

Chemistry

Chemistry, Organic

Heterogeneous catalysis

Materials

Chemical Synthesis

Organic Chemistry

Heterogeneneous Catalysis

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Nota di contenuto

Photo-induced Carbene Transformations to Heterocycles -- Heterocycles from Onium Ylides -- Heterocycles from Sulfur Ylides -- Heterocycles from Cascade Reactions via Carbene gem-difunctionalization -- Cyclopropanation of Heterocycles -- Heterocycles from Cycloaddition Reaction -- Alkynes as Carbene Precursors for the Synthesis of Heterocycles -- Heterocycles from Donor/Donor Carbenes -- Heterocycles by Nitrene Transfer Reactions.

Sommario/riassunto

This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of recent developments in the applications of reactions involving carbene and nitrene intermediates directed to the synthesis of heterocyclic compounds. Multiple pathways through which diverse heterocyclic compounds are accessed occur from a variety of carbene and nitrene precursors through C-H/X-H insertions, cycloadditions,



ylide transformations, rearrangements, and cascade reactions. Catalytic processes that form metallo-carbenes and nitrenes offer unparalleled chemo-, regio-, and stereo-selectivities. Insights are provided into the scope of these methodologies and the inherent control of catalyst ligands on reaction selectivities.