1.

Record Nr.

UNISALENTO991001098889707536

Autore

Coco, Nicola

Titolo

"...e sullo schermo apparve un codice" : produzione telematica e tutela giuridica del minore / Nicola Coco

Pubbl/distr/stampa

Roma : SEAM, 1996

ISBN

8881790157

Descrizione fisica

327 p. ; 21 cm.

Collana

Maschere. Psicologia e giustizia ; 2

Lingua di pubblicazione

Italiano

Formato

Materiale a stampa

Livello bibliografico

Monografia

2.

Record Nr.

UNINA9910830243803321

Autore

Ishikawa Tsutomu

Titolo

Superbases for organic synthesis [[electronic resource] ] : guanidines, amidines and phosphazenes and related organocatalysts / / editor, Tsutomu Ishikawa

Pubbl/distr/stampa

Chichester, UK, : John Wiley & Sons, 2009

ISBN

1-282-69052-3

9786612690525

0-470-74085-X

0-470-74086-8

Descrizione fisica

1 online resource (346 p.)

Disciplina

541.395

547.2

Soggetti

Amidines

Guanidines

Phosphazo compounds

Organic bases

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia



Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

Superbases for Organic Synthesis: Guanidines, Amidines, Phosphazenes and Related Organocatalysts; Contents; Preface; Acknowledgements; Contributors; 1. General Aspects of Organosuperbases; References; 2. Physico-Chemical Properties of Organosuperbases; 2.1 Introduction; 2.2 Proton Sponges; 2.2.1 'Classical' Proton Sponges; 2.2.2 Proton Sponges with Other Aromatic Backbones; 2.2.3 Polycyclic Proton Sponges; 2.3 Amidines; 2.4 Guanidines; 2.5 Phosphazenes; 2.6 Guanidinophosphazenes; 2.7 Other Phosphorus Containing Superbases : Verkade's Proazaphosp hatranes; 2.8 Theoretical Methods

2.9 Concluding RemarksReferences; 3. Amidines in Organic Synthesis; 3.1 Introduction; 3.2 Preparation of Amid ines; 3.2.1 Alkylation of Amidines; 3.2.2 Condensation of 1,2-Diamine; 3.2.3 Coupling of Imines (Isoamarine Synthesis); 3.2.4 Modification of Amide Derivatives; 3.2.5 Multi-Component Reaction; 3.2.6 Oxidative Amidination; 3.2.7 Oxidative Cyclization to Bisamidine; 3.2.8 Ring Opening of Aziridine; 3.3 Application of Amidines to Organic Synthesis; 3.3.1 Acetoxybromination; 3.3.2 Aldol -Like Reaction; 3.3.3 Azidation; 3.3.4 Aziridination; 3.3.5 Baylis-Hillman Reaction

3.3.6 Cycloaddition3.3.7 Dehydrohalogenation; 3.3.8 Deprotection; 3.3.9 Deprotonation; 3.3.10 Displacement Reaction; 3.3.11 Horner-Wadsworth-Emmons Reaction; 3.3.12 Intramolecular Cyclization; 3.3.13 Isomerization; 3.3.14 Metal -Mediated Reaction; 3.3.15 Michael Reaction; 3.3.16 Nef Reaction; 3.3.17 Nucleophilic Epoxidation; 3.3.18 Oxidation; 3.3.19 Pudovik-phospha-Brook Rearrangemen t; 3.3.20 [1,4]-Silyl Transfer; 3.3.21 Tandem Reaction; 3.4 Amidinium Salts: Design and Synthesi s; 3.4.1 Catalyst; 3.4.2 Molecular Recognition; 3.4.3 Reagent Source; 3.5 Concluding Remarks; References

4. Guanidines in Organic Synthesis4.1. Introduction; 4.2. Preparation of Chiral Guanidines; 4.2.1 Polysubstituted Acyclic and Monocyclic Guanidines; 4.2.2 Monosubstituted Guanidines (Guanidinylation); 4.2.3 Bicyclic Guanidines; 4.2.4 Preparation Based on DMC Chemistry; 4.3 Guanidines as Synthetic Tools; 4.3.1 Addition; 4.3.2 Substitution; 4.3.3 Others; 4.4 Guanidinium Salt; 4.4.1 Guanidinium Ylide; 4.4.2 Ionic Liquid; 4.4.3 Tetramethylguanidinium Azide (TMGA); 4.5 Concluding Remarks; References; 5. Phosphazene: Preparation, Reaction and Catalytic Role; 5.1 Introduction

5.2 Deprotonative Transformations Using Stoichiometric Phosphazenes5.2.1 Use of P1 Base; 5.2.2 Use of P2 Base; 5.2.3 Use of P4 Base; 5.2.4 Use of P5 Base; 5.3 Transformation Using Phosphazene Catalyst; 5.3.1 Addition of Nucleophiles to Alkyne; 5.3.2 Catalytic Activation of Silylated Nucleophiles; 5.4 Proazaphosphatrane Base (Verkade's Base); 5.4.1 Properties of Proazaphosphatrane; 5.4.2 Synthesis Using Proazphosphatrane; 5.5 Concluding Remarks; References; 6. Polymer-Supported Organosuperbases; 6.1 Introduction; 6.2 Acylation Reactions; 6.3 Alkylation Reactions; 6.4 Heterocyclization

6.5 Miscellaneous

Sommario/riassunto

Guanidines, amidines and phosphazenes have been attracting attention in organic synthesis due to their potential functionality resulting from their extremely strong basicity. They are also promising catalysts because of their potential for easy molecular modification, possible recyclability, and reduced or zero toxicity. Importantly, these molecules can be derived as natural products - valuable as scientists move towards "sustainable chemistry", where reagents and catalysts are derived from biomaterial sources. Superbases for Organic Synthesis is an essential guide to these important



3.

Record Nr.

UNINA9910734998503321

Titolo

Hormones and cancer

Pubbl/distr/stampa

New York, : Springer

ISSN

1868-8500

Descrizione fisica

online resource (volumes : color illustrations ; ; 28 cm)

Disciplina

616.994

Soggetti

Cancer - Endocrine aspects

Cancer - Hormone therapy

Endocrine glands - Cancer

Neoplasms, Hormone-Dependent

Neoplastic Processes

Antineoplastic Agents, Hormonal - therapeutic use

Càncer

Glàndules endocrines

Endocrinologia

Periodical

Fulltext

Internet Resources.

Periodicals.

Revistes electròniques.

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Periodico

Note generali

Refereed/Peer-reviewed

Editor: Jonathan J. Li.

Published in cooperation with the Endocrine Society.

Sommario/riassunto

"Translational research in hormone-associated cancers as it relates to risk assessment, causation, prevention, treatment, tumor recurrence, and resistance"--V. 1, no. 1, p. [1].