Fruit and vegetables nutritional value has been gaining interest for consumers and it plays an important role for human health and diet. The nutritional value is generally represented by the accumulation of bioactive molecules that are in large part constituted by secondary metabolites and antioxidant compounds. The biosynthesis of these compounds mainly occurs thorough the phenylpropanoid pathway. The accumulation of bioactive compounds is highly dependent on the plant species considered, cultivar/genotype, agronomic management, and environmental conditions before harvest and during postharvest. The preservation of the nutritional value after harvest is influenced by storage conditions, packaging systems, and postharvest treatments. Fruits and vegetables bioactive compounds content is very important for consumers, but it is also important for the produce preservation during the distribution chain as, for instance, produce with higher antioxidant compounds also have a longer shelf life. Among bioactive compounds, ascorbic acid, phenolic compounds, carotenoids, and glucosinolates represent the most important groups. The storage conditions and postharvest technologies can help to reduce the degradation or losses of bioactive compounds and even promote their accumulation. The physiological, biochemical and molecular changes can be correlated to the nutraceutical variations in pre- and |