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Record Nr. |
UNINA9910643494803321 |
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Titolo |
Electron-transfer and electrochemical reactions [[electronic resource] ] : photochemical and other energized reactions / / editor, J.J. Zuckerman; subject index editor, A.P. Hagen |
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Pubbl/distr/stampa |
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[Deerfield Beach, FL], : VCH, c1986 |
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ISBN |
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1-282-30827-0 |
9786612308277 |
0-470-14530-7 |
0-470-14551-X |
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Descrizione fisica |
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1 online resource (426 p.) |
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Collana |
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Inorganic reactions and methods ; ; v. 15 |
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Altri autori (Persone) |
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ZuckermanJ. J <1936-1987.> (Jerold J.) |
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Disciplina |
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Soggetti |
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Photochemistry |
Charge transfer |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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Description based upon print version of record. |
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Nota di bibliografia |
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Includes bibliographical references. |
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Nota di contenuto |
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Inorganic Reactions and Methods; Contents; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 15; Electron-Transfer and Electrochemical Reactions; Introduction; Electron Transfer; Introduction; Classification of Electron-Transfer Reactions; Outer-Sphere Reactions; Examples of Outer-Sphere Reactions; Outer-Sphere Transition States; Inner-Sphere Reactions; Inner-Sphere Reactions: Scheme I; Inner-Sphere Reactions: Scheme II; Inner-Sphere Reactions: Scheme Ill; Double-Ligand Bridging; Other Reaction Classes |
Mixed Outer- and Innersphere ReactionsIntramolecular Electron Transfer; Two-Electron Transfers; Theory of Electron-Transfer Reactions; The Stability of the Precursor Complex; Potential-Energy Surfaces; of Zero Order.; of First Order.; The Electronic Factor; Electron-Exchange Reactions; The Reorganization Energy; Nuclear Tunneling in Electron Exchange; Quantum-Mechanical Treatment; Comparison of Observed and Calculated Parameters for Electron Exchange; Electron Transfer Accompanied by a Net Chemical Change; Semiclassical |
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Treatment; Cross Reactions and Electron-Exchange Rates |
Quantum-Mechanical TreatmentConclusions; General Reactivity Patterns in Electron Transfer; The Inner-Shell Reorganization Energy: Exchange Rates of Aquo Ions; Variations with Ligand: The Outer-Shell Reorganization Energy; Electronic Factors: Nonadiabaticity; Free-Energy Relations; Inner-Sphere Versus Outer-Sphere Electron Transfer; Rate Saturation in Electron Transfer; Specific Reactivity Patterns in Electron-Transfer Reactions; Variation with the Reductant; One-Electron Reductants; Two-Electron Reductants; Variation with the Oxidant; One-Electron Oxidants; Multiple-Electron Oxidants |
Oxidation and Reduction of Coordinated LigandsCatalysis in Electron-Transfer Reactions; Catalyzed Electron Transfer; Catalyzed Ligand Substitution; Induced Electron-Transfer Reactions; Photoinduced Electron-Transfer Reactions; Electrochemical Reactions; Introduction; The Electrode Process; Reversibility; Electrochemical Reversibility; Chemical Reversibility; Complex Electrode Mechanisms; Diagnostic Electrochemical Measurements; Voltammetric Methods; Direct-Current Polarography; Pulse-Polarographic Methods; Alternating-Current Polarography; Cyclic Voltammetry; Evaluation of Formal Potentials |
Involving Stable Reactants and Products.Involving Unstable Electrode Products.; Involving Reactants Undergoing Multiple- Electrode Reactions.; Chemical Reactions Accompanying Electrode Reactions; Reactions Preceding Electron Transfer (CE); Slow-Reaction (1 >a) Limit; Intermediate-Reaction Kinetics; Reactions Following Electron Transfer (EC); Giving Electroinactive Products.; Giving Electroactive Products (ECE).; Other Coupled Chemical Reactions; Electrochemical Synthesis; by Controlled-Potential Electrolysis.; Involving Bulk Preparations.; Conclusions |
Thermodynamics of Simple Electrochemical Reactions |
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Sommario/riassunto |
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How to Use this Book. Preface to the Series. Editorial Consultants to the Series. Contributors to Volume 15. 12. Electron-Transfer and Electrochemical Reactions. 12.1. Introduction. 12.2. Electron Transfer. 12.3. Electrochemical Reactions. 13. Photochemical and Other Energized Reactions. 13.1. Introduction. 13.2. Photosubstitution and Photoisomerization. 13.3. Photoinduced Cleavage of Metal-Metal Bonds. 13.4. Photoinduced Electron-Transfer Reactions. 13.5. Pulse Radiolysis. List of Abbreviations. Author Index. Compound Index. Subject Index |
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2. |
Record Nr. |
UNINA9910795638103321 |
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Autore |
Hartenstein Friedhelm <1960-> |
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Titolo |
The Hermeneutics of the ban on images : exegetical and systematic theological approaches / / Friedhelm Hartenstein and Michael Moxter, translated by Linda Maloney |
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Pubbl/distr/stampa |
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New York, New York ; ; Mahwah, New Jersey : , : Paulist Press, , [2021] |
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©2021 |
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ISBN |
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Edizione |
[1st ed.] |
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Descrizione fisica |
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1 online resource (248 pages) |
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Disciplina |
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Soggetti |
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God |
Image of God |
Image (Theology) |
Idols and images |
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Lingua di pubblicazione |
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Formato |
Materiale a stampa |
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Livello bibliografico |
Monografia |
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Note generali |
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"Originally published as Hermeneutik des Bilderverbots. Exegetische und systematisch-theologische Annaherungen. Forum Theologische Literaturzeitung, copyright 2016." |
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Nota di contenuto |
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Intro -- Title Page -- Copyright Page -- Contents -- Illustrations and Acknowledgments -- Preface -- I. Introduction -- II. Exegetical and Religious-Historical Perspectives -- 1. Religious-Historical Contexts -- 1.1 Basics of Ancient Near Eastern Image Cults -- a. What is a sanctuary? -- b. Anthropomorphic cultic images: Production, worship, significance -- c. Symbols of gods: Equivalent or competing media? -- d. "Aniconic" cult symbols: Complementary or contrary to images? -- e. What do we know about Jerusalem's cultic symbolism? -- 1.2 The Cult's Frame of Reference: "Mental Iconography" -- a. The bodies of the gods -- b. Transcendence of the divine beings -- 2. The Ban on Images: Character and Origin -- 2.1 The Pre-Socratics' Critique of Images -- 2.2 Ancient Jewish Critique of Images -- a. Hellenistic-Roman authors on monotheism and prohibition of images: The view from outside -- b. Critique of images in ancient Jewish witnesses and texts of the postexilic period (5th-3rd c. BCE): The view from within -- b.1) Ancient Jewish texts -- b.2) Old Testament critique of images from the postexilic period -- 2.3 The Ban on Images: Origin, Variants, Rationale |
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-- a. The Decalogue's prohibition of images -- b. Further explicit prohibitions of images in the Old Testament and their relationship to the Decalogue -- 2.4 Preconditions for the Beginnings of a Prohibition of Images -- a. Judaic-Babylonian cultural contacts and the origins of the ban on images -- b. Two older preconditions for the ban of images in Israel and Judah: Critique of certain visual representations -- b.1) The bull imagery at Bethel in the Northern Kingdom of Israel: Hosea and Exodus 32 (8th/7th c. BCE) -- b.2) Josiah of Judah's reform measures (end of the 7th c. BCE) -- 3. Consequences for a Hermeneutics of the Ban on Images from an Exegetical Perspective. |
3.1 The Ban on Images and the Image of God Conveyed in Words -- a. Biblical metaphorics as limit conceptuality -- b. Iconicity of the Psalms -- 3.2 Models of a Critical Hermeneutics of Imagery in the Old Testament -- a. The Sinai theophany: Transitory imagery and the image in words -- b. The "enduring disappearance" of the theophany as "figure" of memory -- c. Humans as image of God in the Priestly writing and relevance for a hermeneutics of imagery -- III. Systematic Perspectives -- 1. Contexts -- 2. Powerful Images -- 2.1 Representations of Dominance -- 2.2 Bodies and Images of Kings -- 2.3 Prohibition of Images as Critique of Power -- 3. Image and Body -- 3.1 God Has No Body? -- 3.2 Negative Evaluation of Corporeality -- 3.3 Philosophical Critique of Images (Plato) -- 3.4 Philosophical Critique of the Imagination (Descartes) -- 3.5 Repression of the Senses -- 3.6 Body as Imago Dei? -- 3.7 Embodiment and Christology -- 3.8 Christianity as a Crisis of the Body? -- 3.9 Preliminary Conclusion -- 4. Ban on Images, Monotheism, and Negative Theology -- 4.1 Hermeneutics of the Ban on Images as a Hermeneutics of Violence -- 4.2 Hermeneutics of the Ban on Images as Rationalistic Apologetics -- 4.3 Hermeneutics of the Ban on Images as Phenomenology of Alterity -- 4.4 Negative Theology: Pre-Socratic -- 4.5 Transcendence as Negativity and Otherness -- 4.6 Representation of What Cannot Be Represented: Kant's Reception of the Ban on Images -- 4.7 The Ban on Images and the Media Revolution -- 5. Invisibility or Hiddenness of God? -- 5.1 God's Invisibility -- 5.2 Dimensions of the Concept of Images in Luther's Theology -- 5.3 The Ban on Images and the "Image of God" -- 5.4 "Images Let Us See" -- 6. The Power of Images: Making Present and Intensifying Presence -- 6.1 Ambivalent Presentations -- 6.2 Folding Together of Presence and Absence -- 6.3 Presence and Magic. |
6.4 (Re)presentation and Image -- 6.5 Preliminary Conclusion -- 6.6 Concentration of Presence and Availability -- 6.7 Image and Sacrament -- 7. Seeing versus Hearing, Image versus Word: Protestant Constellations of a Theology of Images? -- 8. Christological Rehabilitation of Images: Systematic Considerations on the Ban on Images in Ancient Christianity -- 8.1 Didactic Rehabilitation of Images -- 8.2 Theological Perspectives -- 8.3 Participation in the Holy -- 8.4 Theology of the Image and Christology -- 9. Aesthetics within the Horizon of a Ban on Images -- 9.1 Prohibition of Images in Critical Theory -- 9.2 Image-Producing Dimensions of Reformation theology -- 9.3 Iconoclasm as Aesthetic Strategy -- 9.4 Once Again: The Representation of What Cannot Be Represented -- 9.5 The End of the Image? -- 10. Concluding Reflection on the Systematic Section -- IV. Prospect -- Notes. |
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Sommario/riassunto |
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"Recognizing both the potential of biblical prohibition of images for causing religious conflict and the promise of a more nuanced appreciation of the role of images in human experience, this book constructs a framework for understanding the place of images, and their prohibition, within the biblical text and Christian religious |
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