1.

Record Nr.

UNINA9910143557903321

Autore

Tidwell Thomas T. <1939->

Titolo

Ketenes II [[electronic resource] /] / Thomas T. Tidwell

Pubbl/distr/stampa

Hoboken, N.J., : Wiley-Interscience, c2006

ISBN

1-280-28821-3

9786610288212

0-470-36177-8

0-471-76767-0

0-471-76766-2

Edizione

[2nd ed.]

Descrizione fisica

1 online resource (672 p.)

Disciplina

547.036

547.436

547/.436

Soggetti

Ketenes

Electronic books.

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

Description based upon print version of record.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

KETENES II; Contents; Preface; Introduction; References; 1 Structure, Bonding, and Thermochemistry of Ketenes; 1.1 Theoretical and Computational Studies of Ketenes; 1.1.1 Molecular and Electronic Structure and Energy; References; 1.1.2 Theoretical and Computational Studies of Ketene Reactions; References; 1.1.3 Substituent Effects on Ketenes; References; 1.2 Molecular Structure Determinations; References; 1.3 Thermochemistry of Ketenes; References; 2 Spectroscopy and Physical Properties of Ketenes; 2.1 Nuclear Magnetic Resonance Spectroscopy; References

2.2 Ultraviolet Spectra, Photoelectron Spectra, and Chiroptical PropertiesReferences; 2.3 Infrared Spectra and Raman Spectra; References; 2.4 Dipole Moments; References; 2.5 Mass Spectrometry and Gas Phase Ion Chemistry; References; 3 Preparation of Ketenes; 3.1 Ketenes from Ketene Dimers; References; 3.2 Ketenes from Carboxylic Acids and their Derivatives; 3.2.1 Ketenes from Carboxylic Acids and Anhydrides; 3.2.1.1 Ketenes from Carboxylic Acids; References; 3.2.1.2 Ketenes from Acid Anhydrides; References; 3.2.2 Ketenes from Acyl



Halides and Activated Acids; References

3.2.3 Ketenes from Esters3.2.3.1 Ketenes from Ester Enolates; 3.2.3.2 Ketenes by Ester Pyrolysis; References; 3.2.4 Ketenes by Dehalogenation of a-Halo Carboxylic Acid Derivatives; References; 3.3 Ketenes from Diazo Ketones (Wolff Rearrangements); 3.3.1 Thermal Wolff Rearrangement; 3.3.2 Catalyzed Wolff Rearrangement; 3.3.3 Photochemical Wolff Rearrangement; 3.3.4 Other Routes to Ketocarbene Rearrangements; References; 3.4 Ketenes by Photochemical and Thermolytic Methods; 3.4.1 Ketenes from Cyclobutanones and Cyclobutenones; References

3.4.2 Ketenes from Photolysis of Cycloalkanones and EnonesReferences; 3.4.3 Ketenes from Cyclohexadienones and other Cycloalkenones; References; 3.4.4 Ketenes from Dioxinones; References; 3.4.5 Ketenes by Thermolysis of Alkynyl Ethers; References; 3.4.6 Ketenes from other Thermolytic and Photochemical Routes; References; 3.5 Ketenes from Metal Carbene Complexes; References; 3.6 Ketene Formation from Cations and Free Radicals; References; 3.7 Ketenes from Oxidation of Alkynes; References; 3.8 Other Routes to Ketenes; References; 4 Types of Ketenes; 4.1 Carbon-Substituted Ketenes

4.1.1 AlkylketenesReferences; 4.1.2 Alkenylketenes; References; 4.1.3 Alkynyl- and Cyanoketenes; References; 4.1.4 Aryl- and Heteroarylketenes; References; 4.1.5 Cyclopropyl-, Cyclopropenyl-, and Oxiranylketenes; References; 4.1.6 Acylketenes; References; 4.1.7 Imidoylketenes; References; 4.1.8 Cumulene-Substituted Ketenes; References; 4.1.9 Ketenes with Charged, Radical, or Carbenic Side Chains; References; 4.1.10 Fulvenones and Cumulenones; 4.1.10.1 Triafulvenones; 4.1.10.2 Pentafulvenones; References; 4.1.11 Oxoquinone Methides, Oxoxylylenes, and Related Species; References

4.2 Nitrogen-Substituted Ketenes

Sommario/riassunto

The most up-to-date single reference on ketene chemistry for the practicing researcherKetenes are valued by both practicing organic synthetic chemists and pharmaceutical researchers for their ease of preparation, high reactivity, and versatility of use.Ketenes, Second Edition is an updated version of the premier resource on this important class of compounds, and features a comprehensive, self-contained guide to all aspects of ketene chemistry, including:* Types of ketenes* Theoretical studies* Thermochemistry* Ketene preparation* Reactions, including mechani



2.

Record Nr.

UNINA9910633952203321

Autore

Yang Yang <1975, >

Titolo

Age-period-cohort analysis : new models, methods, and empirical applications / / Yang Yang and Kenneth C. Land

Pubbl/distr/stampa

Boca Raton, Fla. : , : CRC Press, , 2013

ISBN

1-000-21873-2

0-429-09620-8

1-4665-0753-5

9781466507524

9781466507531

Edizione

[1st edition]

Descrizione fisica

1 online resource (339 p.)

Collana

Chapman & Hall/CRC interdisciplinary statistics series

Altri autori (Persone)

LandKenneth C

Disciplina

001.42/2

001.422

300.727

Soggetti

Cohort analysis

Age groups - Statistical methods

statistical method

distribution by age

sociology

data processing

Lingua di pubblicazione

Inglese

Formato

Materiale a stampa

Livello bibliografico

Monografia

Note generali

A Chapman & Hall book.

Nota di bibliografia

Includes bibliographical references and index.

Nota di contenuto

1. Introduction -- 2. Why cohort analysis? -- 3. APC analysis of data from three common research designs -- 4. Formalities of the age-period-cohort analysis conundrum and a generalized linear mixed models (GLMM) framework -- 5. APC accounting/multiple classification model, part I : model identification and estimation using the intrinsic estimator -- 6. APC accounting/multiple classification model, part II : empirical applications -- 7. Mixed effects models : hierarchical APC-cross-classified random effects models (HAPC-CCREM), part I : the basics -- 8. Mixed effects models : hierarchical APC-cross-classified random effects models (HAPC-CCREM), part II : advanced analyses -- 9. Mixed effects models : hierarchical APC-growth curve analysis of



prospective cohort data -- 10. Directions for future research and conclusion.

Sommario/riassunto

Age-Period-Cohort Analysis: New Models, Methods, and Empirical Applications is based on a decade of the authors' collaborative work in age-period-cohort (APC) analysis. Within a single, consistent HAPC-GLMM statistical modeling framework, the authors synthesize APC models and methods for three research designs: age-by-time period tables of population rates or proportions, repeated cross-section sample surveys, and accelerated longitudinal panel studies. The authors show how the empirical application of the models to various problems leads to many fascinating findings on how outcome variables d