Extrinsic and intrinsic approaches to self-healing polymers and polymer composites / / Ming Qiu Zhang, Min Zhi Rong

• Record Nr.: UNINA9910566696803321
• Autore: Zhang Ming Qiu
• Pubbl/distr/stampa: Hoboken, New Jersey : , : Wiley, , [2022]; ©2022
• ISBN: 1-119-63000-2; 1-119-62997-7; 1-119-62999-3
• Descrizione fisica: 1 online resource (355 pages)
• Disciplina: 620.192
• Soggetti: Polymers; Self-healing materials; Polymeric composites
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 Basics of Self-Healing - State of the Art -- 1.1 Background -- 1.1.1 Adhesive Bonding for Healing Thermosetting Materials -- 1.1.2 Fusion Bonding for Healing Thermoplastic Materials -- 1.1.3 Bioinspired Self-Healing -- 1.2 Intrinsic Self-Healing -- 1.2.1 Self-Healing Based on Reversible Covalent Chemistry -- 1.2.1.1 Healing Based on General Reversible Covalent Reactions -- 1.2.1.2 Healing Based on Dynamic Reversible Covalent Reactions -- 1.2.2 Self-Healing Based on Supramolecular Interactions -- 1.2.2.1 Coordination Bonds -- 1.2.2.2 Ionic Associations -- 1.2.2.3 Hydrogen Bonds -- 1.2.2.4 Other Intermolecular Forces -- 1.2.2.5 Host-Guest Inclusion -- 1.3 Extrinsic Self-Healing -- 1.3.1 Self-Healing in Terms of Healant Loaded Pipelines -- 1.3.1.1 Hollow Tubes and Fibers -- 1.3.1.2 Three-Dimensional Microvascular Networks -- 1.3.2 Self-Healing in Terms of Healant Loaded Microcapsules -- 1.3.2.1 Methods of Microencapsulation -- 1.3.2.2 Healing Chemistries -- 1.4 Insights for Future Work -- References -- Chapter 2 Extrinsic Self-Healing via Addition Polymerization -- 2.1 Design and Selection of Healing System -- 2.2 ; Microencapsulation of Mercaptan and Epoxy by In-Situ Polymerization -- 2.2.1 Microencapsulation of Mercaptan -- 2.2.2 Microencapsulation of Epoxy -- 2.3 Filling Polymeric Tubes with Mercaptan and Epoxy -- 2.4 Characterization of Self-Healing Functionality -- 2.4.1 Self-Healing Epoxy Materials with Embedded Dual Encapsulated Healant - Healing of Crack Due to Monotonic Fracture -- 2.4.2 Factors Related to Performance Improvement -- 2.4.3 Self-Healing Epoxy Materials with Embedded Dual Encapsulated Healant - Healing of Fatigue Crack -- 2.4.4 Self-Healing Epoxy/Glass Fabric Composites with Embedded Dual Encapsulated Healant - Healing of Impact Damage.; 2.4.5 Self-Healing Epoxy/Glass Fabric Composites with Self-Pressurized Healing System -- 2.5 Concluding Remarks -- References -- Chapter 3 Extrinsic Self-Healing Via Cationic Polymerization -- 3.1 Thermosetting -- 3.1.1 Microencapsulation of Epoxy by Ultraviolet Irradiation-Induced Interfacial Copolymerization -- 3.1.2 Encapsulation of Boron-Containing Curing Agent -- 3.1.2.1 Loading Boron-Containing Curing Agent onto Porous Media -- 3.1.2.2 Microencapsulation of Boron-Containing Curing Agent Via the Hollow Capsules Approach -- 3.1.3 Characterization of Self-Healing Functionality -- 3.1.3.1 Self-Healing Epoxy Materials with Embedded -- 3.1.3.2 Self-Healing Epoxy Materials with Embedded Dual Encapsulated Healant -- 3.1.4 Preparation of Silica Walled Microcapsules Containing SbF5·HOC2H5/HOC2H5 -- 3.1.5 Self-Healing Epoxy Materials with Embedded Epoxy-Loaded Microcapsules and SbF5·HOC2H5/HOC2H5-Loaded Silica Capsules -- 3.1.6 Preparation of Silica Walled Microcapsules Containing TfOH -- 3.1.7 Self-Healing Epoxy Materials with Embedded Epoxy-Loaded Microcapsules and TfOH-Loaded Silica Capsules -- 3.2 Thermoplastics -- 3.2.1 Preparation of IBH/GMA-Loaded Microcapsules -- 3.2.2 Self-Healing PS Composites Filled with IBH/GMA-Loaded Microcapsules and NaBH4 Particles -- 3.3 Concluding Remarks -- References -- Chapter 4 Extrinsic Self-Healing via Anionic Polymerization -- 4.1 Preparation of Epoxy-Loaded Microcapsules and Latent Hardener -- 4.1.1 Microencapsulation of Epoxy by In-Situ Condensation -- 4.1.2 Preparation of Imidazole Latent Hardener -- 4.2 Self-Healing Epoxy Materials with Embedded Epoxy-Loaded Microcapsules and Latent Hardener -- 4.3 Self-Healing Epoxy/Woven Glass Fabric Composites with Embedded Epoxy-Loaded Microcapsules and Latent Hardener - Healing of Interlaminar Failure -- 4.4 Durability of Healing Ability.; 4.5 Self-Healing Epoxy/Woven Glass Fabric Composites with Embedded Epoxy-Loaded Microcapsules and Latent Hardener - Healing of Impact Damage -- 4.6 Concluding Remarks -- References -- Chapter 5 Extrinsic Self-Healing Via Miscellaneous Reactions -- 5.1 Extrinsic Self-Healing Via Nucleophilic Addition and Ring-Opening Reactions -- 5.1.1 Microencapsulation of GMA by In-Situ Polymerization -- 5.1.2 Self-Healing Epoxy Materials with Embedded Single-Component Healant -- 5.2 Extrinsic Self-Healing Via Living Polymerization -- 5.2.1 Preparation of Living PMMA and Its Composites with GMA-Loaded Microcapsules -- 5.2.2 Self-Healing Performance of Living PMMA Composites Filled with GMA-Loaded Microcapsules -- 5.2.3 Preparation of GMA-Loaded Multilayered Microcapsules and their PS-Based Composites -- 5.2.4 Self-Healing Performance of PS Composites Filled with GMA-Loaded Multilayered Microcapsules -- 5.3 Extrinsic Self-Healing Via Free Radical Polymerization -- 5.3.1 Microencapsulation of Styrene and BPO -- 5.3.2 Self-Healing Performance of Epoxy Composites Filled with Dual Capsules -- 5.4 Concluding Remarks -- References -- Chapter 6 Intrinsic Self-Healing Via the Diels-Alder Reaction -- 6.1 Molecular Design and Synthesis -- ; 6.1.1 Synthesis of DGFA -- 6.1.2 Reversibility of DA Bonds and Crack Remendability of DGFA-Based Polymer -- 6.1.3 Synthesis and Characterization of FGE -- 6.1.4 Reversibility of DA Bonds and Crack Remendability of FGE-Based Polymer -- 6.2 Blends of DGFA and FGE -- 6.2.1 Reversibility of DA Bonds -- 6.2.2 Crack Remendability of Cured DGFA/FGE Blends -- 6.3 Concluding Remarks -- References -- Chapter 7 Intrinsic Self-Healing Via Synchronous Fission/Radical Recombination of the CON Bond -- 7.1 Thermal Reversibility of Alkoxyamine in Polymer Solids -- 7.2 Self-Healing Cross-linked Polystyrene -- 7.2.1 Synthesis -- 7.2.2 Characterization.; 7.3 Self-Healing Epoxy -- 7.3.1 Synthesis -- 7.3.2 Characterization -- 7.4 Self-Healing Polymers Containing Alkoxyamine with Oxygen Insensitivity and Reduced Homolysis Temperature -- 7.4.1 Synthesis -- 7.4.2 Characterization -- 7.5 Reversible Shape Memory Polyurethane Network with Intrinsic Self-Healability of Wider Crack -- 7.5.1 Synthesis -- 7.5.2 Characterization -- 7.6 Concluding Remarks -- References -- Chapter 8 Intrinsic Self-Healing Via Exchange Reaction of the Disulfide Bond -- 8.1 Room-Temperature Self-Healable and Remoldable Cross-Linked Polysulfide -- 8.2 Sunlight Driven Self-Healing Cross-Linked Polyurethane Containing the Disulfide Bond -- 8.2.1 Cross-Linked Polyurethane -- 8.2.1.1 Bulk Polymer -- 8.2.1.2 Composites with Silver Nanowires as Strain Sensor -- 8.2.2 Commercial Silicone Elastomer -- 8.3 Self-Healing and Reclaiming of Vulcanized Rubber -- 8.4 Concluding Remarks -- References -- Index -- EULA.