Sulfur-containing polymers : from synthesis to functional materials / / edited by Xing-Hong Zhang and Patrick Theato

• Record Nr.: UNINA9910555275303321
• Pubbl/distr/stampa: Weinheim, Germany : , : Wiley-VCH, , [2021]; ©2021
• ISBN: 3-527-82380-8; 3-527-82381-6; 3-527-82379-4
• Descrizione fisica: 1 online resource (xxv, 446 pages) : illustrations
• Disciplina: 547.06
• Soggetti: Organosulfur compounds; Electronic books.
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Nota di contenuto: Cover -- Title Page -- Copyright -- Contents -- Introduction -- Chapter 1 Synthesis of Sulfur‐Containing Polymers Through Multicomponent Polymerizations -- 1.1 Introduction -- 1.2 Multicomponent Polymerizations of Elemental Sulfur -- 1.2.1 Multicomponent Polymerization of Sulfur, Dialdehydes, and Diamines -- 1.2.2 Multicomponent Polymerization of Sulfur, Diynes, and Aliphatic Amines -- 1.2.3 Multicomponent Polymerization of Sulfur, Benzyl Diamines, and Aliphatic Diamines -- 1.2.4 Multicomponent Polymerization of Sulfur, Diarylacetic Acids, and Aliphatic/Aromatic Diamines -- 1.2.5 Multicomponent Polymerization of Sulfur, Diisocyanides, and Aliphatic Diamines -- 1.3 Cu(I)‐Catalyzed Multicomponent Polymerizations of Sulfonyl Azides/Hydrazides -- 1.3.1 Multicomponent Polymerization of Sulfonyl Azides, Alkynes, and Amines/Alcohols -- 1.3.2 Multicomponent Polymerization of Sulfonyl Azides, Alkynes, and Other Monomers -- 1.3.3 Multicomponent Polymerization of Sulfonyl Hydrazide, Alkynes, and Diphenyl Dichalcogen -- 1.3.4 Topological Polymers Prepared from Sulfonyl Azides and Alkyne‐Based MCPs -- 1.4 Multicomponent Polymerizations with Thiol‐Related Monomers -- 1.4.1 One‐Pot Multicomponent ; Tandem Polymerization of Alkyne, Carbonyl Chloride, and Thiol -- 1.4.2 Multicomponent Polymerizations with Cyclic Dithiocarbonate -- 1.4.3 Multicomponent Polymerizations with Cyclic Thiolactone -- 1.5 The Applications of Sulfur‐Containing Polymers Prepared from MCP -- 1.5.1 Chemosensors -- 1.5.2 Metal Ion Removal/Enrichment -- 1.5.3 Cell Imaging -- 1.6 Conclusion -- Acknowledgments -- References -- Chapter 2 Carbon Disulfide Derived Polymers -- 2.1 Introduction -- 2.2 Synthesis of Thiiranes (Episulfides) -- 2.3 Copolymerization Reactions -- 2.3.1 Copolymerization of Carbon Disulfide and Episulfides -- 2.3.2 Copolymerization of Carbon Disulfide and Epoxides.; 2.3.2.1 Scrambling Mechanism for Sulfur/Oxygen Atoms -- 2.3.2.2 NMR Scrambling Studies -- 2.3.2.3 Mixed Species Scrambling -- 2.4 Other Related CS2‐Based Polymers -- 2.5 Concluding Remarks -- Acknowledgments -- References -- Chapter 3 Carbonyl Sulfide Derived Polymers -- 3.1 Introduction -- 3.1.1 Overview of COS -- 3.1.2 Preparation of COS -- 3.1.2.1 Direct Reaction of CO and Sulfur -- 3.1.2.2 Using Carbon Disulfide (CS2) -- 3.1.2.3 Laboratory Preparation of COS -- 3.1.3 Environmental and Safety Considerations -- 3.1.4 COS Chemistry -- 3.1.4.1 Dissociation -- 3.1.4.2 Hydrolysis -- 3.1.4.3 Oxidation -- 3.1.4.4 Reduction -- 3.1.4.5 Reaction with SO2 -- 3.1.4.6 Reaction with Ammonia and Amines -- 3.1.4.7 Miscellaneous Reactions -- 3.1.4.8 The Claus Reaction -- 3.2 Metal Catalysts for COS Copolymerization -- 3.2.1 Zinc‐Cobalt(III) Double‐Metal Cyanide Complex -- 3.2.2 Catalysts Centered with Chromium (Cr) -- 3.2.3 Catalyst Centered with Iron (Fe) and Cobalt (Co) -- 3.2.4 Alkoxy Metal Salts -- 3.3 Organocatalysts for COS Copolymerization -- 3.3.1 TEB‐Organic Base Pair -- 3.3.2 Dual‐Site Lewis Pair -- 3.3.3 Thiourea‐Organic Base Pairs -- 3.3.4 Supramolecular Anion -- 3.4 Oxygen‐Sulfur Exchange Reaction -- 3.5 Utilization of O/S ER for Poly(thioether)s -- 3.5.1 COS‐Epoxides Route to Poly(thioether)s -- 3.5.2 CS2‐Epoxides Route to Poly(thioether)s -- 3.5.3 Repurposing Poly(monothiocarbonate)s to Poly(thioether)s -- 3.6 Crystalline COS‐Derived Polymers -- 3.7 COS‐Derived Block Polymers -- 3.8 Properties of COS‐Derived Polymers -- 3.8.1 Thermal Properties -- 3.8.2 Crystalline Properties -- 3.8.3 Optical Properties -- 3.8.4 Electronic Properties -- 3.9 Summary and Outlook -- References -- Chapter 4 Thiol‐Based Click Polymerizations for Sulfur‐Containing Polymers -- 4.1 Introduction -- 4.2 Thiol‐Ene Click Polymerization.; 4.2.1 Radical‐Initiated Thiol‐Ene Click Polymerization -- 4.2.2 Thiol‐Ene Michael Addition Click Polymerization -- 4.3 Thiol‐Yne Click Polymerization -- 4.3.1 Radical‐Initiated Thiol‐Yne Click Polymerization -- 4.3.2 Base‐Mediated Thiol‐Yne Click Polymerization -- 4.3.3 Metal‐Catalyzed Thiol‐Yne Click Polymerization -- 4.3.4 Spontaneous Thiol‐Yne Click Polymerization -- 4.4 Other Thiol‐Based Click Polymerizations -- 4.4.1 Thiol‐Epoxy Click Polymerization -- 4.4.2 Thiol‐Isocyanate Click Polymerization -- 4.4.3 Thiol‐Halogen Click Polymerization -- 4.5 Conclusion -- Acknowledgments -- References -- Chapter 5 Synthesis of Polythioesters -- 5.1 Introduction -- 5.2 Synthesis of Aromatic Polythioesters -- 5.3 Synthesis of Semi‐aromatic Polythioesters -- 5.4 Synthesis of Aliphatic Polythioesters -- 5.5 Summary and Concluding Remarks -- Acknowledgments -- References -- Chapter 6 Polymers with Sulfur‐Nitrogen Bonds -- 6.1 Introduction -- 6.2 Synthesis of Sulfur‐Nitrogen Containing Polymers -- 6.2.1 Poly(sulfenamide)s -- 6.2.2 Poly(diaminosulfide)s -- 6.2.3 Poly(aminodisulfide)s and Poly(diaminodisulfide)s -- 6.2.3.1 Poly(aminodisulfide)s -- 6.2.3.2 Poly(diaminodisulfide)s -- 6.2.4 Poly(oxothiazene)s -- 6.2.5 Poly(sulfonylimidate)s -- 6.2.6 Poly(sulfonylamidine)s -- 6.3 Applications of Polymers with Sulfur‐Nitrogen ; Bond -- 6.3.1 Biomedical Applications -- 6.3.2 Metal‐Ion Detection -- 6.3.3 Flame Retardant Chemicals Based on Polymers with Sulfur‐Nitrogen Bonds -- 6.3.4 Energy Storage Applications -- 6.4 Conclusion and Outlook -- References -- Chapter 7 Thioester Functional Polymers -- 7.1 Introduction -- 7.2 Thioesters: Structural Features, Reactivities, and Reactions -- 7.3 Preparation of Thioester Containing Structures -- 7.3.1 Access to Thioester Containing Polymers: Thioesters in the Side Chain.; 7.3.2 Access to Thioester Containing Polymers: Thioester in the Chain End -- 7.3.3 Access to Thioester Containing Polymers via Polymerization Process -- 7.3.4 Access to Thioester‐Bearing Structures via Post‐modification Approach -- 7.4 Post‐Polymerization Modification of Thioesters -- 7.5 Conclusion and Outlook -- References -- Chapter 8 Thiophene‐Based Polymers: Synthesis and Applications -- 8.1 Introduction -- 8.2 Development of Synthetic Methods -- 8.2.1 Oxidative Polymerization and Electrochemical Polymerization -- 8.2.2 Transmetalation Polymerization -- 8.2.2.1 Polymerization with Ni Catalysis -- 8.2.2.2 Polymerization with Pd Catalysis -- 8.2.2.3 Suzuki Coupling Method -- 8.2.2.4 Stille Coupling Method -- 8.2.2.5 Direct Arylation Method -- 8.2.3 Other Polymerization Methods -- 8.2.3.1 Photoinitiated Polymerization -- 8.2.3.2 Solid‐State Polymerization -- 8.2.3.3 Acid‐Catalyzed Polymerization -- 8.3 Applications of Polythiophene and Its Derivatives -- 8.3.1 Organic Thin‐Film Transistors -- 8.3.2 Organic Photovoltaics -- 8.3.3 Organic Light‐Emitting Diodes -- 8.3.4 Biological Applications -- 8.4 Conclusions and Future Scope -- References -- Chapter 9 High Refractive Index Sulfur‐Containing Polymers (HRISPs) -- 9.1 Introduction -- 9.2 Basics of Optics -- 9.2.1 Absorption and Refraction -- 9.2.2 Refractive Index -- 9.2.2.1 Refractive Index Determination -- 9.2.3 Dispersion -- 9.2.4 Birefringence -- 9.3 High Refractive Index Polymers (HRIPs) -- 9.3.1 General Strategies and Applications -- 9.4 Sulfur‐Containing HRIPs -- 9.4.1 Polyimides and Polyamides -- 9.4.2 Poly(meth)acrylates and Polythioacrylates -- 9.4.3 Polycarbonates and Polyesters -- 9.4.4 Thermosets -- 9.4.5 Inverse Vulcanization -- 9.5 Conclusion and Outlook -- References -- Chapter 10 Selenium‐Containing Dynamic Polymers: From Synthesis to Functions -- 10.1 Introduction.; 10.2 Synthesis of Selenium‐Containing Polymers -- 10.2.1 Step Growth Polymerization -- 10.2.2 Radical Polymerization -- 10.2.3 Ring‐Opening Polymerization -- 10.2.4 Synthesis of Dendrimer and Hyperbranched Selenium‐Containing Polymer -- 10.3 Selenium‐Containing Dynamic Covalent Chemistry -- 10.3.1 Diselenide Bond -- 10.3.2 Se S Bond -- 10.3.3 Se Te Bond -- 10.3.4 Se N Bond -- 10.4 Selenium‐Containing Dynamic Materials -- 10.4.1 Selenium‐Containing Elastomer -- 10.4.2 Selenium‐Containing Surface/Interface Materials -- 10.4.3 Selenium‐Containing Nanomaterials -- 10.5 Conclusion and Outlook -- Acknowledgments -- References -- Chapter 11 Poly(disulfide)s -- 11.1 Introduction -- 11.2 Synthesis of Poly(disulfide)s -- 11.2.1 Oxidative Polymerization of Dithiols -- 11.2.2 Ring‐Opening Polymerization (ROP) of Cyclic Disulfide -- 11.2.3 Photo‐Induced Disulfide Metathesis -- 11.2.4 Fragmentation Polymerization -- 11.2.5 Self‐Organizing Surface‐Initiated Polymerization (SOSIP) -- 11.2.6 Thiol‐Disulfide Exchange Reaction -- 11.3 Amphiphilic PDS and Drug Delivery Application -- 11.4 Cell‐Penetrating Poly(disulfide)s -- 11.5 Summary and Outlook -- References -- Chapter 12 Reduction‐Responsive Disulfide‐Containing Polymers for Biomedical Applications -- 12.1 Introduction -- 12.2 Disulfide‐Containing Topological Polymers -- 12.2.1 Systems with the Disulfide Linkages -- 12.2.2 Disulfide‐Containing Linear Polymers -- 12.2.2.1 Linear Polymers with Cleavable ; Backbones -- 12.2.2.2 Linear Polymers with Cleavable Side Chains -- 12.2.3 Disulfide‐Containing Dendritic Polymers -- 12.2.3.1 Disulfide‐Containing Hyperbranched Polymers -- 12.2.3.2 Disulfide‐Containing Dendrimers -- 12.2.4 Disulfide‐Containing Polypeptides and Proteins -- 12.2.5 Disulfide‐Containing Polymeric Nanoparticles -- 12.2.5.1 Disulfide Linker for Amphiphilic Polymers.; 12.2.5.2 Disulfide Linker for Nano‐Assemblies.