CO2 hydrogenation catalysis / / edited by Yuichiro Himeda

• Record Nr.: UNINA9910555167603321
• Pubbl/distr/stampa: Hoboken, New Jersey : , : John Wiley & Sons, Incorporated, , [2021]; ©2021
• ISBN: 3-527-82409-X; 3-527-82411-1; 3-527-82410-3
• Descrizione fisica: 1 online resource (314 pages) : illustrations
• Disciplina: 665.89
• Soggetti: Carbon dioxide; Hydrogenation; Electronic books.
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Note generali: Includes index.
• Nota di contenuto: Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 Introduction -- 1.1 Direct Use of CO2 -- 1.2 Chemicals from CO2 as a Feedstock -- 1.3 Application and Market Studies of CO2 Hydrogenation Products -- 1.3.1 Formic Acid/Formate -- 1.3.2 Methanol -- 1.3.3 Methanation -- 1.3.4 Energy Storage -- 1.4 Supply of Materials -- 1.4.1 CO2 Supply -- 1.4.2 Energy and H2 Supply -- 1.5 Political Aspect: Tax -- 1.6 Conclusion and Perspectives -- References -- Chapter 2 Homogeneously Catalyzed CO2 Hydrogenation to Formic Acid/Formate by Using Precious Metal Catalysts -- 2.1 Introduction -- 2.2 Ir Complexes -- 2.2.1 Ir Complexes with N,N-ligands -- 2.2.1.1 Tautomerizable N,N-ligands with OH Groups -- 2.2.1.2 N,N-ligands with NH Group -- 2.2.1.3 Tautomerizable N,N-ligands with OH and NH Groups -- 2.2.1.4 Tautomerizable N,N-ligands with Amide Group -- 2.2.2 Ir Complexes with C,N- and C,C-ligands -- 2.2.3 Ir Complexes with Pincer Ligands -- 2.3 Ru Complexes -- 2.3.1 Ru Complexes with Phosphorous Ligands -- 2.3.2 Ru Complexes with N,N- and N,O-ligands -- 2.3.3 Ru Complexes with Pincer Ligands -- 2.4 Rh Complexes -- 2.5 Summary and Conclusions -- References -- Chapter 3 Homogeneously Catalyzed CO2 Hydrogenation to Formic ; Acid/Formate with Non-precious Metal Catalysts -- 3.1 Introduction -- 3.2 Iron-Catalyzed CO2 Hydrogenation -- 3.2.1 Non-pincer-Type Iron Complexes -- 3.2.2 Pincer-Type Iron Complexes -- 3.3 Cobalt-Catalyzed CO2 Hydrogenation -- 3.4 Nickel-Catalyzed CO2 Hydrogenation -- 3.5 Copper-Catalyzed CO2 Hydrogenation -- 3.6 Manganese-Catalyzed CO2 Hydrogenation -- 3.7 Other Non-precious Metals for CO2 Functionalization -- 3.8 Conclusions and Perspectives -- References -- Chapter 4 Catalytic Homogeneous Hydrogenation of CO2 to Methanol -- 4.1 Carbon Recycling and Methanol in the Early Twenty-First Century.; 4.2 Heterogeneous Catalysis for CO2 to Methanol -- 4.3 Homogeneous Catalysis - An Alternative for CO2 to Methanol -- 4.3.1 Benefits of Homogeneous Catalysis -- 4.3.2 CO2 Hydrogenation to Methanol Through Different Routes -- 4.3.3 The First Homogeneous System for CO2 Reduction to Methanol -- 4.3.4 Indirect CO2 Hydrogenation -- 4.3.5 Direct CO2 Hydrogenation -- 4.3.5.1 Through Formate Esters -- 4.3.5.2 Through Oxazolidinone or Formamides -- 4.3.6 CO2 to Methanol via Formic Acid Disproportionation -- 4.4 Conclusion -- References -- Chapter 5 Theoretical Studies of Homogeneously Catalytic Hydrogenation of Carbon Dioxide and Bioinspired Computational Design of Base-Metal Catalysts -- 5.1 Introduction -- 5.2 H2 Activation and CO2 Insertion Mechanisms -- 5.2.1 Hydrogen Activation -- 5.2.2 Insertion of CO2 -- 5.3 Hydrogenation of CO2 to Formic Acid/Formate -- 5.3.1 Catalysts with Precious Metals -- 5.3.2 Catalysts with Non-noble Metals -- 5.4 Hydrogenation of CO2 to Methanol -- 5.5 Summary and Conclusions -- References -- Chapter 6 Heterogenized Catalyst for the Hydrogenation of CO2 to Formic Acid or Its Derivatives -- 6.1 Introduction -- 6.2 Molecular Catalysts Heterogenized on the Surface of Grafted Supports -- 6.3 Molecular Catalysts Heterogenized on Coordination Polymers -- 6.4 Molecular Catalysts Heterogenized on Porous Organic Polymers -- 6.5 Concluding Remarks and Future Directions -- References -- Chapter 7 Design and Architecture of Nanostructured Heterogeneous Catalysts for CO2 Hydrogenation to Formic Acid/Formate -- 7.1 Introduction -- 7.2 Unsupported Bulk Metal Catalysts -- 7.3 Unsupported Metal Nanoparticle Catalysts -- 7.3.1 Metal Nanoparticles Without Stabilizers -- 7.3.2 Metal Nanoparticles Stabilized by Ionic Liquids -- 7.3.3 Metal Nanoparticles Stabilized by Reverse Micelles -- 7.4 Supported Metal Nanoparticle Catalysts.; 7.4.1 Metal Nanoparticles Supported on Carbon-Based Materials -- 7.4.2 Metal Nanoparticles Supported on Nitrogen-Doped Carbon -- 7.4.3 Metal Nanoparticles Supported on Al2O3 -- 7.4.4 Metal Nanoparticles Supported on TiO2 -- 7.4.5 Metal Nanoparticles Supported on Surface-Functionalized Materials -- 7.5 Embedded Single-Atom Catalysts -- 7.6 Summary and Conclusions -- References -- Chapter 8 Heterogeneously Catalyzed CO2 Hydrogenation to Alcohols -- 8.1 Introduction -- 8.2 CO2 Hydrogenation to Methanol - Past to Present -- 8.2.1 Syngas to Methanol -- 8.2.2 CO2 to Methanol -- 8.2.3 Thermodynamic Consideration - Chemical and Phase Equilibria -- 8.2.4 Catalyst Developments -- 8.2.5 Active Sites and Reaction Mechanisms: The Case of Cu/ZnO Catalysts -- 8.2.6 Beyond Industrial Cu/ZnO/Al2O3 Catalysts -- 8.3 CO2 Hydrogenation to Ethanol and Higher Alcohols - Past to Present -- 8.3.1 Background -- 8.3.2 Catalysts, Active Sites, and Reaction Mechanisms -- 8.3.2.1 Modified-Methanol Synthesis Catalyst -- 8.3.2.2 Modified Fischer-Tropsch Catalysts -- 8.3.2.3 Rhodium-Based Catalysts -- 8.3.2.4 Modified Molybdenum-Based Catalysts -- 8.4 Summary -- References -- Chapter 9 Homogeneous Electrocatalytic CO2 Hydrogenation -- 9.1 ; CO2 Reduction to CH Bond-Containing Compounds: Formate or Formic Acid -- 9.1.1 Survey of Catalysts -- 9.1.1.1 Group 9 Metal Complexes -- 9.1.1.2 Group 8 Metal Complexes -- 9.1.1.3 Nickel Complexes -- 9.1.1.4 Iron and Iron/Molybdenum Clusters -- 9.1.2 Hydride Transfer Mechanisms in CO2 Reduction to Formate -- 9.1.2.1 Terminal Hydrides -- 9.1.2.2 Bridging Hydrides -- 9.1.3 Kinetic Factors in Catalyst Design -- 9.1.3.1 Roles of Metal-Ligand Cooperation -- 9.1.3.2 Roles of Multiple Metal-Metal Bonds -- 9.1.4 Thermochemical Considerations in Catalyst Design -- 9.1.4.1 Selectivity for Formate over H2 as a Function of Hydricity.; 9.1.4.2 Solvent Dependence of Hydricity -- 9.2 Prospects in Electrocatalysis: CO2 Reduction Beyond Formation of One CH Bond -- References -- Chapter 10 Recent Advances in Homogeneous Catalysts for Hydrogen Production from Formic Acid and Methanol -- 10.1 Introduction -- 10.2 Formic Acid Dehydrogenation -- 10.2.1 Organic Solvent Systems -- 10.2.1.1 Ru -- 10.2.1.2 Ir -- 10.2.1.3 Fe -- 10.2.2 Aqueous Solution Systems -- 10.2.2.1 Ru -- 10.2.2.2 Ir -- 10.3 Aqueous-phase Methanol Dehydrogenation -- 10.3.1.1 Ir -- 10.3.1.2 Non-precious Metals -- 10.4 Conclusion -- References -- Index -- EULA.

Seventh International Symposium "Monitoring of Mediterranean Coastal Areas. Problems and Measurement Techniques" : Livorno (Italy) 19-20-21 June 2018

• Record Nr.: UNINA9910571704903321
• Autore: Benincasa Fabrizio
• Pubbl/distr/stampa: Florence, : Firenze University Press, 2018
• Descrizione fisica: 1 electronic resource (688 p.)
• Collana: Proceedings e report
• Soggetti: Hydrology & the hydrosphere; Physical geography & topography
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Sommario/riassunto: The Seventh International Symposium Monitoring of Mediterranean Coastal Areas. Problems and Measurement Techniques (Livorno, Italy June 19-20-21, 2018) was organized by the CNR-IBIMET in collaboration with the City of Livorno, the LEM Foundation, the FCS Foundation and the Compagnia dei Portuali di Livorno, with the patronage by Accademia Nazionale dei Lincei, Accademia dei Georgofili, The University of Florence, the Tuscany Region and the North Tyrrhenian Sea Port System Authority. The Symposium, in which scholars from all over the Mediterranean basin participated, was an opportunity to illustrate new proposals and to promote actions to protect the Mediterranean coastal marine environment. In particular, the event was characterized by the search for technical and instrumental solutions to problems related to: energy production in the coastal area, morphology and evolution of coastlines, flora and fauna of the littoral system, management and integrated coastal protection, coastline geography, human influence on coastal landscape.

Foucault in California : [a true story--wherein the great French philosopher drops acid in the Valley of Death] / / Simeon Wade ; foreword by Heather Dundas

• Record Nr.: UNINA9910793302703321
• Autore: Wade Simeon <1940->
• Pubbl/distr/stampa: Berkeley, California : , : Heyday, , 2019
• ISBN: 1-59714-472-X
• Descrizione fisica: 1 online resource (104 pages)
• Disciplina: 194
• Soggetti: LSD (Drug)
• Lingua di pubblicazione: Inglese
• Formato: Materiale a stampa
• Livello bibliografico: Monografia